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Alkyl chloride alkylation

Iodide ion Alkyl chloride Alkyl iodide Chloride or... [Pg.329]

The reactions of thionyl chloride with organic compounds having hydroxyl groups are important. Alkyl chlorides, alkyl sulfites, or alkyl chlorosulfites form from its reaction with aUphatic alcohols, depending on reaction conditions, stoichiometry, and the alcohol stmcture ... [Pg.140]

With the bulky metallo-organic Pd(II) catalyst 98, on the other hand, selective formation of 99 was possible here functional groups are tolerated that would react with an Ag(I) catalyst (for example, terminal alkynes, alkyl chlorides, alkyl bromides and alkyl iodides) [59]. With l,n-diallenyl diketones (100), easily accessible by a bidirectional synthesis, up to 52-membered macrocycles (101) could be prepared in an end-group differentiating intramolecular reaction (Scheme 15.26) [60], For ring sizes lager than 12 only the E-diastereomer is formed overall yields of the macrocydes varied between 17 and 38%. Only with tethers shorter than 11 carbon atoms could the Z-diastereomer of the products be observed, a stereoisomer unknown from the intermolecular dimerization reactions of 96. [Pg.891]

Thionyl chloride (moles) Alkyl chloride (°/.) Alkyl chlorosulfinate (%) Sulfite (%)... [Pg.296]

M-1 s-1 alkyl phenyl selenides, aryl bromides, vinyl bromides, a-chloro esters, a-thiophenyl esters 104-102M 1 s-1 alkyl chlorides, alkyl phenyl sulfides, a-chloro and a-thiophenyl ethers. [Pg.32]

R-Cl alkyl chloride (alkyl halide) RC(=0)-C1 acyl chloride... [Pg.6]

Iodides by treatment with sodium iodide in acetone. Nal is soluble in Iodide ion Alkyl chloride Alkyl iodide Chloride or... [Pg.305]

Although the major product of an E2 dehydrohalogenation of alkyl chlorides, alkyl bromides, and alkyl iodides is normally the more substituted alkene, the major product of the E2 dehydrohalogenation of alkyl fluorides is the less substituted alkene (Table 11.2). [Pg.406]

In the first step of the reaction, a carbocation is formed from the reaction of an alkyl halide with AICI3. Alkyl fluorides, alkyl chlorides, alkyl bromides, and alkyl iodides can all be used. Vinyl halides and aryl halides cannot be used because their carbocations are too unstable to be formed (Section 10.8). [Pg.613]

We saw that in an E2 reaction of an alkyl chloride, alkyl bromide, or alkyl iodide, a hydrogen is removed from the j8-carbon bonded to the fewest hydrogens (Zaitsev s rule, Section 11.2). Now we see that in an E2 reaction of a quaternary ammonium ion, the hydrogen is removed from the j8-carbon bonded to the most hydrogens (anti-... [Pg.890]

Halophosphines are produced by reactions of phosphorus with alkyl chlorides, alkyl bromides, or aryl bromides in solution (12) and by reaction of red phosphorus in tlie presence of copper with alkyl halides in tlie vapor phase (13). Both methods require temperatures in excess of 2 )0°. The preparation of halopliosphines in solution is illustrated by the results of uncatalyzed white phosphorus reactions summarized in Table I (12). Alkyl dihalopliosphiues are the predominant products under these conditions, but appreciable yields of dialkylmonohalophos-phines are also obtained. The reaction temperature requirement de-... [Pg.7]

Iodide ion (d ) Alkyl chlorides and bromides are converted to alkyl Iodides by treatment with sodium iodide in acetone. Nal is soluble in acetone, but NaCI and NaBr are insoluble and crystallize from the reaction mixture, driving the reaction to completion. / 0 acetone y + R—X > R — + Iodide ion Alkyl chloride Alkyl iodide or bromide acetone CH3CHCH3 -h Nal > CH3CHCH3 1 1 Br 1 X Chloride or bromide ion + NaBr (solid)... [Pg.305]

Alkyl acetone Alkyl alcohol Alkyl benzene Alkyl chloride Alkyl sulfide Aluminum acetate Aluminum bromide Aluminum chlorate Aluminum chloride Aluminum ethylate Aluminum fluoride Aluminum fluorosilicate Aluminum formate Aluminum hydroxide Aluminum nitrate Aluminum oxalate Aluminum phosphate Aluminum sulfate Alum... [Pg.549]

Carboxylic acid Ketone Aldehyde Amide 1° amine 2° amine 3° amine Alkyl chloride Alkyl bromide Nitrile... [Pg.1197]

Alkyl Chlorides Alkyl Bromides, and Alkyl Iodides Preferentially Form the More Stable Product... [Pg.447]


See other pages where Alkyl chloride alkylation is mentioned: [Pg.759]    [Pg.336]    [Pg.201]    [Pg.250]    [Pg.158]    [Pg.172]    [Pg.310]   


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3- methyl chloride, alkylation

5-Alkyl-2-amino Phosphoryl-chlorid

A-Phenylethyl chloride, alkylation of sodium sodiophenylacetate with

Action of Zinc Alkyl on Acyl Chlorides in certain proportions

Alkenyl chlorides alkylation

Alkyl Chlorides to Nitriles in DMSO

Alkyl ammonium chloride

Alkyl chloride alkylation (continued

Alkyl chlorides

Alkyl chlorides

Alkyl chlorides activated

Alkyl chlorides anchimeric assistance

Alkyl chlorides elimination reactions

Alkyl chlorides formation

Alkyl chlorides from alcohols and chlorovinylamines

Alkyl chlorides halides

Alkyl chlorides heterocycles

Alkyl chlorides kinetic isotope effects

Alkyl chlorides long-chained

Alkyl chlorides mass spectrum

Alkyl chlorides pyrolysis

Alkyl chlorides reaction with saturated nitrogen

Alkyl chlorides rearrangements

Alkyl chlorides synthesis from alcohols

Alkyl chlorides, bromides and iodides

Alkyl chlorides, dehydrochlorination

Alkyl chlorides, formation from alcohols

Alkyl chlorides, formation from alcohols during

Alkyl chlorides, from alcohols, benzyl

Alkyl chlorides, preparation

Alkyl chlorides, preparation VOLUME

Alkyl chlorides, primary

Alkyl chlorides, rates

Alkyl chlorides, reaction with wood

Alkyl chlorides, reduction

Alkyl chlorides, relative rate

Alkyl chlorides, relative rate constants

Alkyl dimethyl benzyl ammonium chloride

Alkyl oxalyl chlorides, reactions

Alkyl tin chlorides

Alkyl trimethyl ammonium chloride

Alkyl trimethylammonium chloride

Alkyl-dimethyl-benzylammonium chlorid

Alkyl-dimethyl-benzylammonium chloride

Alkylation aluminum chloride

Alkylation aluminum chloride sludges

Alkylation palladium chloride

Alkylation ruthenium chloride

Alkylation using supported aluminium chloride

Alkylation with 1-butyl chloride

Alkylation with benzyloxymethyl chlorid

Alkylation with benzyloxymethyl chloride

Alkylation with isopropyl chloride

Alkylation with nitrobenzyl chloride

Alkylation zirconium chloride

Alkylation, mechanism with benzyl chloride

Alkylation, of 2-carbomethoxycyclopentanone with benzyl chloride

Alkylbenzenes aluminum chloride alkylation

Alkyls chloride exchange

Allylic chloride alkylations

Aluminum chloride Friedel-Crafts alkylations

Aluminum chloride alkyl halide reduction

Aluminum chloride alkyl halides

Aluminum chloride detergent alkylates

Aluminum chloride toluene alkylation catalyst

Aryl chlorides alkylation

Benzhydryl chloride, alkylation

Benzhydryl chloride, alkylation sodium sodiophenylacetate with

Benzhydryl chlorides, alkylation with

Benzyl chloride, Friedel-Crafts alkylation

Benzyl chloride, alkylation

Benzyl chloride, alkylation with

Benzyl chloride, alkylation with hydrolysis

Chloride, alkyl intermediate

Chloride, alkyl pyridines

Chlorides alkyl, preparation from

Chlorides, alkyl from alcohols

Chlorides, alkyl hydrolysis

Chlorides, alkyl solvolysis

Chlorides, alkyl, also

Chlorides, alkyl, synthesis

Deuterium labelling alkyl chloride

F-Alkyl chlorides

Friedel-Crafts alkylation Aluminum chloride

Friedel-Crafts alkylation zirconium chloride

Friedel-Crafts alkylations aromatic systems, aluminum chloride

Grignard reaction: alkylation with cadmium chloride

Hydrogen chloride catalyzed alkylation

Irradiation alkyl chlorides

Labelling alkyl chloride

Methoxyacetyl chloride alkylation

Neopentyl chloride, alkylation with

Nitriles from alkyl chlorides

Nucleophilic substitution alkyl chlorides

Olefines from alkyl chlorides

Piperazine, N-alkylation with benzyl chloride

Preparation of 4-Alkyl- and 4-Halobenzoyl Chlorides 4-Pentylbenzoyl Chloride

Preparation of alkyl chlorides from alcohols

Primary alkyl halides synthesis from acid chlorides

Reaction with, alkylating agents phosphorus chloride

Silicon with activated alkyl chlorides

Silicon with alkyl chlorides

Sodium Iodide Test for Alkyl Chlorides and Bromides

Solvolysis of alkyl chlorides

Sulfuryl chloride alkyl alcohols

Synthesis of Alkyl Chlorides

Tert-alkyl chloride

Thionyl chloride alcohol conversion into alkyl

Tosyl chloride, alkylations with

Triphenylmethyl chloride, amine alkylations

Tris silane with alkyl chloride

Yields from hydrogen-chloride catalyzed alkylation

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