Additives limestone

An additive assisting in fusion - e.g. CaCOj in iron-smelting - although the limestone also helps with slag formation. 

Similar to dual alkaU except Al2(S0 2 solution used in scmbber. Limestone addition regenerates reactant, precipitating CaS04-2H2 0 crystals which dewater more readily. Reduces plugging/scaliag. 

Minerals. Supplementation of macrominerals to mminants is sometimes necessary. Calcium and phosphoms are the minerals most often supplemented in mminant diets. One or both may be deficient, and the level of one affects the utilization of the other. Limestone, 36% calcium, is commonly used as a source of supplemental calcium. Dolomite, 22% calcium oyster sheUs, 35% calcium and gypsum, 29% calcium, are sources of calcium. Bone meal, 29% calcium, 14% phosphoms dicalcium phosphate, 25—28% calcium, 18—21% phosphoms and defluorinated rock phosphate, 32% calcium, 18% phosphoms, are sources of both calcium and phosphoms. Diammonium phosphate, 25% phosphoms phosphoric acid, 32% phosphoms sodium phosphate, 22% phosphoms and sodium tripolyphosphate, 31% phosphoms, are additional sources of phosphoms (5). 

Ammonia from coal gasification has been used for fertilizer production at Sasol since the beginning of operations in 1955. In 1964 a dedicated coal-based ammonia synthesis plant was brought on stream. This plant has now been deactivated, and is being replaced with a new faciUty with three times the production capacity. Nitric acid is produced by oxidation and is converted with additional ammonia into ammonium nitrate fertilizers. The products are marketed either as a Hquid or in a soHd form known as Limestone Ammonium Nitrate. Also, two types of explosives are produced from ammonium nitrate. The first is a mixture of fuel oil and porous ammonium nitrate granules. The second type is produced by emulsifying small droplets of ammonium nitrate solution in oil. 

Calcium. Calcium is the fifth most abundant element in the earth s cmst. There is no foreseeable lack of this resource as it is virtually unlimited. Primary sources of calcium are lime materials and gypsum, generally classified as soil amendments (see Calcium compounds). Among the more important calcium amendments are blast furnace slag, calcitic limestone, gypsum, hydrated lime, and precipitated lime. Fertilizers that carry calcium are calcium cyanamide, calcium nitrate, phosphate rock, and superphosphates. In addition, there are several organic carriers of calcium. Calcium is widely distributed in nature as calcium carbonate, chalk, marble, gypsum, fluorspar, phosphate rock, and other rocks and minerals. 

In addition to the principal equations discussed, several others occur which may be of importance, including calcination of calcium carbonate (limestone), which takes place in the upper shaft at 800—870°C,... 

Definitions. In addition to showing varying degrees of chemical purity, limestone assumes a number of widely divergent physical forms, including marble, travertine, chalk, calcareous mad, coral, shell, ooHtes, stalagmites, and stalactites. AH these materials are essentially carbonate rocks of the same approximate chemical composition as conventional limestone (2—4). 

The chemical and physical properties of limestone vary tremendously, owing to the nature and quantity of impurities present and the texture, ie, crystallinity and density. These same factors also exert a marked effect on the properties of the limes derived from the diverse stone types. In addition, calcination and hydration practices can profoundly influence the properties of lime. 

Mineral Feed. Mineral feed supplements for domestic animals and fowl usually contain a pure form of pulverized limestone. In fact, some state laws require the supplement to be at least 35% available calcium. Other sources of calcium are bone meal and dicalcium phosphate. Use as mineral feed has been a steadily growing market for limestone. The material is ground to 90% minus 0.15 mm (100 mesh) or 80% minus 0.9074 mm (200 mesh), is low in silica, and has strict tolerances on arsenic and fluorine (see Feeds and feed additives). 

Talc is sold for use in a wide variety of appHcations, including paper (qv), ceramics (qv), roofing, paint (qv), plastics, mbber (qv), cosmetics (qv), pharmaceuticals (qv), adhesives (qv), sealants (qv), and animal feedstuffs (see Feeds and feed additives). In all of these appHcations it is a functional ingredient with specific beneficial properties. Talc is rarely used as a filler because it is much more expensive than alternative minerals such as limestone and clay. 

In the United States the primary route for making calcium chloride is by the evaporation of underground brines (see Chemicals frombrines). Additional commercial material is available by the action of hydrochloric acid on limestone. Typically the hydrochloric acid is a by-product of some other commercial process and the conversion to calcium chloride is motivated by waste avoidance (see Hydrogen chloride). 

The sihca dux combines with iron(II) sulfide and iron(II) oxide to form slag. The duidity of the slag, in which unwanted impurities dissolve, is controlled by the addition of limestone. Reverberatory furnaces have been largely replaced by more advanced smelting furnaces, which require lower energy input, have higher capacity, and produce higher sulfur dioxide content off-gas. 

Of the removal processes that have attained commercial status, the current favorite employs a shiny of lime or limestone. The activity of the reagent is promoted by the addition of small amounts of carboxylic acids such as adipic acid. The gas and the shiny are contacted in a spray tower. The calcium salt is discarded. A process that employs aqueous sodium citrate, however, is suited for the recoveiy of elemental sulfur. The citrate solution is regenerated and recycled. (Kohl and Riesenfeld, Gas Purification, Gulf, 1985, p. 356.)... 

Lime is among a family of chemicals which are alkaline in nature and contain principally calcium, oxygen and, in some cases, magnesium. In this grouping are included quicklime, dolomitic lime, hydrated lime, dolomitic hydrated lime, limestone, and dolomite. The most commonly used additives are quicklime and hydrated lime, but the dolomitic counterparts of these chemicals (i.e., the high-magnesium forms) are also widely used in wastewater treatment and are generally similar in physical requirements. 

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