Acrylonitrile-butyl Acrylate

Brar and Sunita [188] have described a method for the analysis of acrylonitrile-butyl acrylate (A/B) copolymers of different monomer compositions. Copolymer compositions were determined by elemental analyses and comonomer reactivity ratios were determined using a non-linear least squares errors-in-variables model. Terminal and penultimate reactivity ratios were calculated using the observed monomer triad sequence distribution determined from Cj Hj-NMR spectra. The triad sequence distribution was used to calculate diad concentrations, conditional probability parameters, number-average sequence lengths and block character of the copolymers. The observed triad sequence concentrations determined Cj Hj-NMR spectra agreed well with those calculated from reactivity ratios. 

The increase in the concentration of acrylonitrile in the copolymers increases the fraction of the AAA triad while it decreases the fraction of the BAB triad. The fraction of the AAB triad first increases with the increase in concentration of acrylonitrile, passes through a maximum value and then starts decreasing. The maximum fractions of AAB and BBA triads are obtained at 0.60 and 0.55 mole fractions of the respective monomers. 

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This study was therefore undertaken to prepare and evaluate acrylonitrile—butadiene-styrene (ABS) and methyl methacrylate-butadiene-styrene (MBS) polymers under similar conditions to determine whether replacement of acrylonitrile by methyl methacrylate could improve color stability during ultraviolet light aging, without detracting seriously from the good mechanical and thermal-mechanical properties of conventional ABS plastics. For purposes of control, the study also included briefer evaluation of commercial ABS, MBS, and acrylonitrile-butyl acrylate-styrene plastics. 

The photodegradation and photo-oxidation of poly(organosiloxanes), poly(iV-vinylcarbazole), polyCalkoxyphosphazones)," thymine-containing polymers/ cellulose triacetate, cellulose acetophthalate complexes with poly(vinyl alcohol)/ acrylonitrile-butyl acrylate-vinylene chloride terpoly-... 

Recently, the chiral Pt(0) precatalyst Pt[(R, R)-Me-Duphos](tra s-stUbene) (11) has been used to prepare enantiomerically enriched chiral phosphines via hydrophosphination of acrylonitrile, butyl acrylate and related substrates. This chemistry is... 

Methyldecane Acrylonitrile-butyl acrylate Acrylonitrile-ethyl methacrylate Acrylonitrile-methyl acrylate Adipic acid... 

Studies of the particle—epoxy interface and particle composition have been helphil in understanding the mbber-particle formation in epoxy resins (306). Based on extensive dynamic mechanical studies of epoxy resin cure, a mechanism was proposed for the development of a heterophase morphology in mbber-modifted epoxy resins (307). Other functionalized mbbers, such as amine-terminated butadiene—acrylonitrile copolymers (308) and -butyl acrylate—acryhc acid copolymers (309), have been used for toughening epoxy resins. 

Following the success in blending rubbery materials into polystyrene, styrene-acrylonitrile and PVC materials to produce tough thermoplastics the concept has been used to produce high-impact PMMA-type moulding compounds. These are two-phase materials in which the glassy phase consists of poly(methyl methacrylate) and the rubbery phase an acrylate polymer, usually poly(butyl acrylate Commercial materials of the type include Diakon MX (ICI), Oroglas... 

The dimerization of functional alkenes such as acrylates and acrylonitrile represents an attractive route to obtain bifunctional compounds such as dicarboxylates and diamine, respectively. The head-to-tail dimerizahon of acrylates and vinyl ketones was catalyzed by an iridium hydride complex generated in situ from [IrCl(cod)]2 and alcohols in the presence of P(OMe)3 and Na2C03 [26]. The reaction of butyl acrylate 51 in the presence of [IrCl(cod)]2 in 1-butanol led to a head-to-tail dimer, 2-methyl-2-pentenedioic acid dibutyl ester (53%), along with butyl propionate (35%) which is formed by hydrogen transfer from 1-butanol. In order to avoid... 

Ganushchak et al. (1972, 1984) proposed to perform the Meerwein chloroarylation of ethylenic compounds using the preliminarily prepared aryldiazonium tetrachlorocuprates. They found that methyl, ethyl, butyl acrylate, methyl methacrylate, and acrylonitrile in the polar solvent reacted with tetrachlorocuprate. Chloroarylation products were obtained with better yields than when using the traditional Meerwein reaction conditions. 

Acrylan-Rubber Butyl acrylate-acrylonitrile copolymer Monomer Corp... 

A series of pyrido[2,3-rf pyrimidine-2,4-diones bearing substituents at C-5 and/or C-6 were synthesized using palladium-catalyzed coupling of uracil derivative 417 with vinyl substrates or allyl ethers to give the regioisomeric mixtures of 418/419 and 420/421, respectively. The ratio of the isomeric structures was dependent on the substituent R. In the case of the reaction with -butyl vinyl ether, only the product 419 was obtained. However, the reactions with acrylonitrile, ethyl acrylate, 2-trifluoromethylstyrene, and 3-nitrostyrene afforded only 418. Also, reaction with allyl phenyl ether gave only 420. The key intermediate 417 was prepared by the reaction of 6-amino-l-methyluracil with DMF-DMA (DMA = dimethylacetamide), followed by N-benzylation with benzyl chloride and vinyl iodination with iV-iodosuccinimide (NIS) (Scheme 15) <2001BML611>. 

Methacrylic acid Acrylic acid Di-isobutylene Acrylonitrile Allyl acrylate Allyl methacrylate n-Butyi acrylate n-Butyl methacrylate isobutyl methacrylate 2-Chloroethyl methacrylate -Ethoxyethyl methacrylate Ethyl acrylate 2-Ethylhexyl acrylate Ethyl methacrylate Lauryl methacrylate Nonyl methacrylate N-Vinyl pyrrolidone Octyl acrylate 2-Vinyl pyridine... 

Acrylonitrile Allyl acrylate Allyl methacrylate n-Butyl acrylate n-Butyl methacrylate Isobutyl methacrylate Divinyl benzene 2-Choroethyl methacrylate Ethyl acrylate /i-Ethoxyethyl methacrylate 2-Ethylhexyl methacrylate Ethyl methacrylate Methyl methacrylate Methylisopropenylketone Methyl vinyl ketone N-Vinyl pyrrolidone Styrene Vinylpyridine Acrylonitrile Allyl acrylate Allyl methacrylate... 

Acrylonitrile (inhibited) (14) Benzene (10) Butyl acetate (n-, iso- ) (13) Butyl acrylate (inhibited) (14) Butyl acrylate (inhibited) (14) Voranol CP 4100 (6) Phosphoric acid (1) Caustic soda solution (3) Methyl alcohol (6) Voranol CP 4100 (6) ... 

Various Ln amides have already been described in Sections 4.3.5 and 4.3.6 as catalysts for polymerisation of ethylene," I38,i4i i43 jjex-l-ene, isoprene,styrene, " methyl methacrylate or other polar monomers such as t-butyl acrylate or acrylonitrile, . 138,143,152,177 nng-opening polymerisation catalysts for e-caprolactone or... 

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