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Acidic environment, lead oxides

Dissolution of exposed MnS particles in this acidic environment, leading to the creation of H2S and incorporation of sulfur into the reforming oxide. [Pg.615]

After this primer is applied vinyl chloride-vinyl acetate copolymer is added in a series of thin films. The total thickness is usually 5 mils. Pigments like iron oxide, lead, or zinc chromate prevent corrosion of the metal substrate in acid environments and may also be included in the coating. The final coated metal has good resistance to water and many chemicals with about a ten-year lifetime. [Pg.353]

Unlike lead-acid and silver oxide batteries, which have historically been collected and recycled due to their economic value, collection and recycling of general purpose batteries is currently undertaken at a cost to the waste generator. All responsible manufacturers whatever the industry, recognise a need to protect the environment and promote sustainable development. However this is rarely possible at zero cost. In the late 1980 s many battery systems still contain a significant proportion of toxic elements whose environmental impact after use needed to be controlled. [Pg.178]

Preparation and characterization of PANI/NiO nanocomposite using various surfactants, e.g., polyvinyl alcohol and hydroxypropylcellulose, were reported by Aleahmad et al. [230]. PANl and NiO were electro-codeposited from aniline and NiSO through cyclic voltammetric scans at controlled acidity leading thus to the formation of PANI/NiO composite film [231]. The stability of NiO in the composite films against acidic environments was found to be enhanced in comparison with the corresponding stability of pure NiO. Electrochemical catalytic behavior of PANl/NiO composite film was demonstrated by the catalytic oxidation of methanol and ethanol. Multicolored electrochromic thin films of... [Pg.146]

Uranyl sulfate usually appears as a lemon-yellow trihydrate (UO2SO4 3H2O) with a density of 3.28 g cm" and is very soluble in 5 parts of water and 25 parts of alcohol. In geochemistry, oxidation of snlfldes would lead to formation of the sulfate, mainly in an acidic environment where carbonates are not present and cause precipitation of uranium. Uranyl sulfate plays a major role in ore processing as it is readily absorbed on anion-exchange resins and may be extracted with amines. As the uranyl sulfate is very stable, the solutions can be heated to elevated temperatures that help dissolve difficult to digest ores. [Pg.24]

A fresh lead surface slowly oxidizes into a thin, protective lead oxide (PbO) that stops further oxidation of the metal. Lead gives satisfactory resistance to corrosion in rural, marine, and industrial environments. The corrosion rate data for lead is shown as 0.5-0.7 pm/y in industrial (New York, NY), 1.2-2.2 pm/y in marine (Kure Beach, NC), and 1.05-1.85 pm/y in rural (State College, PA) [6]. Lead corrosion products in such environments, in addition to lead oxide, are sulfate, chloride, and carbonate, with lead chloride being the most soluble of all four products (see Table 1). However, lead in outdoor exposures was found to produce sulfate (PbS04) and/or carbonate (PbC03), and indoor exposures lead carboxylates. The primary atmospheric agents responsible for degradation of lead are SO2, CO2, and carboxylic acid [7]. The corrosion rate of chemical lead in Key West, Florida, and La Jolla, California is 0.58 and 0.53 pm/y (0.023 and 0.021 mpy), respectively [2]. [Pg.533]


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See also in sourсe #XX -- [ Pg.155 ]




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Environment, acid

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Lead oxidation

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