White phosphorus smoke munitions

In the military, white phosphorus is used in ammunitions such as mortar and artillery shells, and grenades. When ammunitions containing white phosphorus are fired in the field, they burn and produce smoke. The smoke contains some unbumt phosphorus, but it mainly has various burned phosphorus products. In military operations, such smoke is used to conceal troop movements and to identify targets or the locations of friendly forces. White phosphorus munitions are intended to burn or firebomb the opponents, in other words, to effectively produce widespread damage but not kill the enemy. 

Two important sources of elemental phosphorus in soil are the creation of slag piles during the production of white phosphorus, and the disposal of solid wastes containing elemental phosphorus in hazardous waste landfills (Berkowitz et al. 1981 Idler et al. 1981). The field use of WP/F and red phosphorus/butyl rubber smoke/obscurant releases elemental phosphorus into soil primarily as unburnt phosphorus in munitions (Berkowitz et al. 1981 ... 

Similarly, extensive U.S. experience with destruction of conventional and agent-like munitions (smokes, white phosphorus, CS agent) indicates that the basic CDC technology is cost effective for destroying projectiles and other types of explosive-containing munitions in a U.S. context. 

Phosphorus smokes are generated by a variety of munitions. Some of these munitions (such as the MA25 155-mm round) may, on explosion, distribute particles of incompletely oxidized white phosphorus. Contact with these particles can cause local burns, and systemic toxicity may occur if therapy is not administered. Therapy consists of topical use of a bicarbonate solution to neutralize phosphoric acids and mechanical removal and debridement of particles. A Wood s lamp in a darkened room may help to identify remaining luminescent particles. 

At the end of May, Shadle expressed his satisfaction with the chemical offensive potential and ammunition status in the North African theater. His view seems to have been overly optimistic since smoke pots, tear gas, and HC smoke grenades were the only ammunition items available in sufficient supply. All the chemical supply officers reported urgent requests for unavailable white phosphorus grenades. The Twelfth Air Force reported limited quantities of ANM50A1 4-pound incendiary bombs, a few Mja yoo-pound incendiary bomb clusters, and a considerable number of My4 loo-pound incendiary bomb clusters. There was no other chemical ammunition in the theater although the New York port had promised that 120 days supply of high explosive and smoke shell was en route for the three chemical mortar battalions which had recently arrived in the theater. Aside from a small amount of artillery shell stored by Ordnance, no toxics were available in the theater and none was scheduled to arrive until the fall of 1943. The March theater plan for gas warfare, the first such plan, was based on meeting possible enemy gas attack with this plainly inadequate supply of artillery shell. The new War Department policy for retaliation in event of enemy initiation of gas warfare called for the use of aerial munitions as the principal gas weapons. Shadle s satisfaction with the toxic supply status can be explained by the fact that he did not con-... 

A third screening smoke-type is white phosphoms [7723-14-0] (WP), P (see Phosphorus and THE phosphides), which reacts spontaneously with air and water vapor to produce a dense cloud of phosphoms pentoxide [1314-56-3]. An effective screen is obtained as the P2O5 hydrolyzes to form droplets of dilute phosphoric acid aerosol. WP produces smoke in great quantity, but it has certain disadvantages. Because WP has such a high heat of combustion, the smoke it produces from bulk-filled munitions has a tendency to rise in pillarlike mass. This behavior too often nullifies the screening effect, particularly in stiU air. Also, WP is very brittle, and the exploding munitions in which it is used break it into very small particles that bum rapidly. 

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