Viscosity, hquid

The wedge restriction has no critical surface dimensions or sharp edges and tends to retain accuracy despite visible corrosive or erosive wear. It is commonly appHed to high viscosity Hquids, slurries, and hot multiphase mixtures. A similar device is also available using a cone, positioned so that its large diameter is upstream, mounted on the meter centerline. 

Vortex-shedding flow meters typically provide 1% of flow rate accuracy over wide ranges on Hquid, gas, and steam service. Sizes are available from 25 to 200 mm. The advantages of no moving parts and linear digital output have resulted in wide usage in the measurement of steam, water, and other low viscosity Hquids. 

Many of the common properties of isoprene have been presented graphically (9). These include vapor pressure, heat of vaporization, Hquid heat capacity, vapor heat capacity, Hquid density, vapor viscosity, Hquid viscosity, surface tension, and vapor thermal conductivity. 

For blending of low viscosity Hquids to practical homogeneity, turnover of three tank volumes is normally adequate. For viscous Hquids or for a higher degree of Hquid homogeneity, a greater number of turnovers is needed. 

Commonly used heat-transfer surfaces are internal coils and external jackets. Coils are particularly suitable for low viscosity Hquids in combination with turbine impellers, but are unsuitable with process Hquids that foul. Jackets are more effective when using close-clearance impellers for high viscosity fluids. For jacketed vessels, wall baffles should be used with turbines if the fluid viscosity is less than 5 Pa-s (50 P). For vessels equipped with cods, wall baffles should be used if the clear space between turns is at least twice the outside diameter of the cod tubing and the fluid viscosity is less than 1 Pa-s (10... 

AH glass capillary viscometers should be caUbrated carefully (21). The standard method is to determine the efflux time of distilled water at 20°C. Unfortunately, because of its low viscosity, water can be used only to standardize small capillary instmments. However, a caUbrated viscometer can be used to determine the viscosity of a higher viscosity Hquid, such as a mineral oil. This oil can then be used to caUbrate a viscometer with a larger capillary. Another method is to caUbrate directly with two or more certified standard oils differing in viscosity by a factor of approximately five. Such oils are useful for cahbrating virtually all types of viscometers. Because viscosity is temperature-dependent, particularly in the case of standard oils, temperature control must be extremely good for accurate caUbration. 

Another type of experiment involves a fluid filament being drawn upward against gravity from a reservoir of the fluid (101,213,214), a phenomenon often called the tubeless siphon. The maximum height of the siphon is a measure of the spinnabiUty and extensional viscosity of the fluid. Mote quantitative measures of stress, strain, and strain rate can be determined from the pressure difference and filament diameter. A more recent filament stretching device ia which the specimen is held between two disks that move apart allows measurements ia low viscosity Hquids (215). AH of these methods are limited to spinnable fluids under small total strains and strain rates. High strain rates tend to break the column or filament. 

Viscosity. Sedimentation rate increases with decreased viscosity, )J., and viscosity is dependent on temperature. Often mineral oils, which are highly viscous at room temperature, have a viscosity that is reduced by a factor of 10 at 70—80°C. Tar, soHd at room temperature, is a low viscosity Hquid at 150—200°C and can be clarified of inorganic soHds at high flow rates. Even the viscosity of water changes significantly when the temperature changes between 10 and 35°C (10). 

Fig. 1. States of Hquid content in bonding by low viscosity Hquids (a) pendular, (b) funicular, (c) capillary, and (d) particles surrounded by Hquid droplet (8).

Casting. Because the sol is a low viscosity Hquid, it can be cast into a mold (step B, Fig. 1). The mold must be selected to avoid adhesion of the gel. The sol can be appHed as a coating on a substrate or drawn into fibers or emulsified. 

The first term is essentially the reciprocal of the Weber number and the second term is a function of the Ohnesorge number. Equation 13 may be invaHd for airblast atomizers operating at high pressures, >1 MPa (>10 atm), or with high viscosity Hquids. 

Vinyl acetate is a colorless, flammable Hquid having an initially pleasant odor which quickly becomes sharp and irritating. Table 1 Hsts the physical properties of the monomer. Information on properties, safety, and handling of vinyl acetate has been pubUshed (5—9). The vapor pressure, heat of vaporization, vapor heat capacity, Hquid heat capacity, Hquid density, vapor viscosity, Hquid viscosity, surface tension, vapor thermal conductivity, and Hquid thermal conductivity profile over temperature ranges have also been pubHshed (10). Table 2 (11) Hsts the solubiHty information for vinyl acetate. Unlike monomers such as styrene, vinyl acetate has a significant level of solubiHty in water which contributes to unique polymerization behavior. Vinyl acetate forms azeotropic mixtures (Table 3) (12). 

Wax usually refers to a substance that is a plastic solid at ambient temperature and that, on being subjected to moderately elevated temperatures, becomes a low viscosity hquid. Because it is plastic, wax usually deforms under pressure without the appHcation of heat. The chemical composition of waxes is complex all of the products have relatively wide molecular weight profiles, with the functionaUty ranging from products that contain mainly normal alkanes to those that are mixtures of hydrocarbons and reactive functional species. 

Individual particle surfaces can be lubricated by an adsorbed film that produces a smoother surface and/or decreases interparticle attraction. A plasticized binder may serve this purpose. Forming surfaces can be lubricated by coating with a film of low viscosity Hquid such as water or oil. Die surfaces can also be coated with a solution of stearic acid dissolved in a volatile Hquid that rapidly evaporates to leave a lubricating film. 

Both materials meet the processiag requirements of the industry because they are honeylike fluids at room temperature and low viscosity Hquids between approximately 70° and 90°C and thus act as reactive diluents and tougheners at the same time. 

As may be expected, turbulent flow (9,11) is more efficient for droplet formation in low viscosity Hquids. With the average amount of energy dissipated per unit time and volume equal to Z and mass density equal to p, the larger eddies are characterized by a velocity gradient equal to... 

The bisphenol A-derived epoxy resins are most frequendy cured with anhydrides, aUphatic amines, or polyamides, depending on desired end properties. Some of the outstanding properties are superior electrical properties, chemical resistance, heat resistance, and adhesion. Conventional epoxy resins range from low viscosity Hquids to soHd resins. 

Subsequent epoxidation with epichl orohydrin yields the highly functional epoxy novolak. The product can range from a high viscosity Hquid of n = 0.2 to a soHd of n value greater than 3. 

An important appHcation is for filament-wound glass-reinforced pipe used in oil fields, chemical plants, water distribution, and as electrical conduits. Low viscosity Hquid systems having good mechanical properties (elongation at break) when cured are preferred. These are usually cured with Hquid anhydride or aromatic-amine hardeners. Similar systems are used for filament-win ding pressure botdes and rocket motor casings. 

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