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Variation of integral

The saturation behavior of a spectrum - the variation of integrated intensity with microwave power - is related to the spin-lattice relaxation time, a measure of the rate of energy transfer between the electron spin and its surroundings. Saturation often depends on the same structural and dynamic properties as line widths. [Pg.18]

Figure 6 Comparison of experimental (...) variation of integral W value for water vapor [50] with... Figure 6 Comparison of experimental (...) variation of integral W value for water vapor [50] with...
Figure 5. Variation of integral molar energy of sorption with coverage for (x) methane and ( ) Kr on 5A zeolite (EU data of Rolniak for CHt (--------) theo-... Figure 5. Variation of integral molar energy of sorption with coverage for (x) methane and ( ) Kr on 5A zeolite (EU data of Rolniak for CHt (--------) theo-...
Figure 13.5 Temperature-dependent PL spectra of (a) bare ZnO and (b) metal-capped ZnO obtained from 10 to 300 K. (c) The variation of integrated band edge emission intensity of bare (square) and c ped (circle) ZnO as a function of temperature, (d) The dependence of emission enhancement on temperature [14]. Figure 13.5 Temperature-dependent PL spectra of (a) bare ZnO and (b) metal-capped ZnO obtained from 10 to 300 K. (c) The variation of integrated band edge emission intensity of bare (square) and c ped (circle) ZnO as a function of temperature, (d) The dependence of emission enhancement on temperature [14].
For the electro-oxidation of an adsorbed monolayer of CO, however, synergistic effects between Pt and Ru are obvious from the time dependence of the IR spectra, i.e., there is a coupling of the reaction on the composite surface. Figure 14(a) shows the temporal variation of integrated band densities after a potential step from 90 mV to 450 mV. At 450 mV no CO is oxidized on Pt(lll), and one would expect an uneven concentration of CO on Ru or Pt, reflected in the IR-CO stretching band. [Pg.580]

Figure 5.7. Diagram illustrating typical autosampler precision vs. peak signal/noise ratio (keeping injection volume constant at 10 pL). Note that the peak area precision worsens (increasing RSD) because precision was limited by the statistical variation of integration of noise peak when the signal-to-noise ratios (S/N) are less than 100. Reprinted with permission from reference 12. See the same reference for additional experimental details. Figure 5.7. Diagram illustrating typical autosampler precision vs. peak signal/noise ratio (keeping injection volume constant at 10 pL). Note that the peak area precision worsens (increasing RSD) because precision was limited by the statistical variation of integration of noise peak when the signal-to-noise ratios (S/N) are less than 100. Reprinted with permission from reference 12. See the same reference for additional experimental details.
Obviously, a sharp viscosity growth during polymerization may also lead to a reduction of P(Q) due to variation of integral viscosity with the flow rate... [Pg.124]

The variations of integral objective functionals can be further simplified at their optima by integrating by parts the terms involving derivative functions such as 6x and Srh in Equation (2.29). As a matter of fact, this simplification is an important step in deriving the optimality conditions. Therefore, it is very important to familiarize oneself with the following formula of integration by parts ... [Pg.49]

Variation of integrated P(H) with milling time for the high field component (33.0T), low field component (14.0T), and paramagnetic component in the hyperfine field distribution of the Mossbauer spectra. (Reprinted with permission from Ref. 39. Copyright (2007) by Elsevier.)... [Pg.444]

Fig. 7.37 Variation of integrated intensities with reaction temperature. In (a) the totai intensity of the magnetite pattern (decreasing) and of the iron pattern (increasing) are composed. The straight lines indicate the discrepancy of the sum of the total diffracted intensity from the expected constant value. In (b) the evolutions of the iron (110) and (211) intensities are composed. The expectation value for the (211) reflection is calculated from the suitable scanned structure factor normalised to the (110) intensity 0 ... Fig. 7.37 Variation of integrated intensities with reaction temperature. In (a) the totai intensity of the magnetite pattern (decreasing) and of the iron pattern (increasing) are composed. The straight lines indicate the discrepancy of the sum of the total diffracted intensity from the expected constant value. In (b) the evolutions of the iron (110) and (211) intensities are composed. The expectation value for the (211) reflection is calculated from the suitable scanned structure factor normalised to the (110) intensity 0 ...
Fig. V-12. Variation of the integral capacity of the double layer with potential for 1 N sodium sulfate , from differential capacity measurements 0, from the electrocapillary curves O, from direct measurements. (From Ref. 113.)... Fig. V-12. Variation of the integral capacity of the double layer with potential for 1 N sodium sulfate , from differential capacity measurements 0, from the electrocapillary curves O, from direct measurements. (From Ref. 113.)...
The variation of the integral capacity with E is illustrated in Fig. V-12, as determined both by surface tension and by direct capacitance measurements the agreement confrrms the general correctness of the thermodynamic relationships. The differential capacity C shows a general decrease as E is made more negative but may include maxima and minima the case of nonelectrolytes is mentioned in the next subsection. [Pg.200]

There are cases where the variation of the electtonic ttansition moment with nuclear configuration caimot be neglected. Then it is necessary to work with equation (B 1.1.6) keeping the dependence of on Q and integrating it over the vibrational wavefiinctions. In most such cases it is adequate to use only the tenns up to first-order in equation (B 1.1.7). This results in modified Franck-Condon factors for the vibrational intensities [12]. [Pg.1129]

The enthalpy of fomiation is obtained from enthalpies of combustion, usually made at 298.15 K while the standard entropy at 298.15 K is derived by integration of the heat capacity as a function of temperature from T = 0 K to 298.15 K according to equation (B 1.27.16). The Gibbs-FIehiiholtz relation gives the variation of the Gibbs energy with temperature... [Pg.1904]

For greater precision the variation of j. with composition should be taken into account on integrating along the capillary. This leads to equations more complicated than (6.5) and (6.6), of course. [Pg.58]

Two-dimensional models can be used to provide effective approximations in the modelling of polymer processes if the flow field variations in the remaining (third) direction are small. In particular, in axisymraetric domains it may be possible to ignore the circumferential variations of the field unlaiowns and analytically integrate the flow equations in that direction to reduce the numerical model to a two-dimensional form. [Pg.17]

This is not E, i , of course you must find the minimum energy by systematic variation of ot. Alternatively, a QBASIC or TBASIC program can be written to integrate Eq. (6-28) by Simpson s rule. [Pg.182]

Flooding and Pseudo-First-Order Conditions For an example, consider a reaction that is independent of product concentrations and has three reagents. If a large excess of [BJ and [CJ are used, and the disappearance of a lesser amount of A is measured, such flooding of the system with all components butM permits the rate law to be integrated with the assumption that all concentrations are constant except A. Consequentiy, simple expressions are derived for the time variation of A. Under flooding conditions and using equation 8, if x happens to be 1, the time-dependent concentration... [Pg.508]

Piezoresistive Sensors. The distinction between strain-gauge sensors and pie2oresistive (integrated-circuit) sensors is minor. Both function by measuring the strain on an elastic element as it is subjected to pressure. A pie2oresistive transducer is a variation of the strain gauge that uses bonded... [Pg.24]

Petroleum asphalts, compared to native asphalts, are organic with only trace amounts of inorganic materials. They derive their characteristics from the nature of their cmde origins with some variation possible by choice of manufacturing process. Although there are a number of refineries or refinery units whose prime function is to produce asphalt, petroleum asphalt is primarily a product of integrated refineries (Fig. 1). Cmdes may be selected for these refineries for a variety of other product requirements and the asphalt (or residuum) produced may vary somewhat in characteristics from one refinery-cmde system to another and even by cut-point (Table 2) and asphalt content (Fig. 2) (5,6). The approximate asphalt yields (%) from various cmde oils are as follows ... [Pg.360]

Method of Variation of Parameters This method is apphcable to any linear equation. The technique is developed for a second-order equation but immediately extends to higher order. Let the equation be y" + a x)y + h x)y = R x) and let the solution of the homogeneous equation, found by some method, he y = c f x) + Cofoix). It is now assumed that a particular integral of the differential equation is of the form P x) = uf + vfo where u, v are functions of x to be determined by two equations. One equation results from the requirement that uf + vfo satisfy the differential equation, and the other is a degree of freedom open to the analyst. The best choice proves to be... [Pg.455]

This equation applies to any incompressible or compressible static fluid. For an incompressible hquid, pressure varies linearly with depth. For compressible gases, p is obtained by integration accounting for the variation of p with z. [Pg.634]


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See also in sourсe #XX -- [ Pg.568 , Pg.569 , Pg.573 ]




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