United States acid rain

In the eastern United States, acid rain consists of 65% sulfuric acid, 30% nitric acid, and 5% other acids. In the West, windblown alkaline dusts buffer the acidity in rains occurring over many rural areas, whereas in urban areas 80% of the acidity is due to nitric acid (28). Average pH in rainfall over the eastern United States for the period April 1979-March 1980 was less than 5.0, with some areas less than pH 4.2 (29). The lowest annual pH recorded was 3.78 at De Bilt, The Netherlands, in 1967, and the lowest in an individual rainfall was 2.4 at Pitlochry, Scotland, on April li) 1974 (30). 

Selection of pollution control methods is generally based on the need to control ambient air quaUty in order to achieve compliance with standards for critetia pollutants, or, in the case of nonregulated contaminants, to protect human health and vegetation. There are three elements to a pollution problem a source, a receptor affected by the pollutants, and the transport of pollutants from source to receptor. Modification or elimination of any one of these elements can change the nature of a pollution problem. For instance, tall stacks which disperse effluent modify the transport of pollutants and can thus reduce nearby SO2 deposition from sulfur-containing fossil fuel combustion. Although better dispersion aloft can solve a local problem, if done from numerous sources it can unfortunately cause a regional one, such as the acid rain now evident in the northeastern United States and Canada (see Atmospheric models). References 3—15 discuss atmospheric dilution as a control measure. The better approach, however, is to control emissions at the source. 

Even rain is not pure water. Reports from the U.S. Geological Survey show that it contains 2.3—4.6 ppm of soflds, or a yearly precipitation of 2.5—5 t/km. Recently (ca 1997), work conducted ia the United States and Europe has underscored the rather dangerous results of iacreased use of fossil fuels, where the SO and NO emissions that end up ia the rain lower its pH from 5.6 (slightly acidic) for uncontaminated rain, to acid rains. Such acid rain has serious effects on surface waters (1). About 40 x 10 t of SO and 25 x 10 t of NO were emitted ia the United States ia 1980. There are, however, encouragiag trends the 1970 Clean Air Act has led to a gradual reduction ia these emissions, bringing the SO emissions down from the previous levels cited by 10% by 1990, and the NO emissions down by 6%, with a consequent slight decrease ia rain acidity. A part of the Clean Air Act is also iatended to cap SO emissions from major poiat sources at 13.5 x 10 t (2). Between 1994 and 1995, total SO emissions ia the U.S. decreased remarkably by 13% and total NO emissions by 8%. 

The usage pattern in Europe and Japan is more dependent upon the automotive industry. However, with the recent concern about acid rain, the European and U.S. markets should show increased interest in fluorocarbon elastomers for pollution control appHcations. On the other hand, the Japanese market has a sizable outlet in electrical and general machinery manufacturing (eg, copiers). Petroleum appHcations are of Htfle interest outside the United States. 

In a relatively small continental area such as Europe, there is not much difference between what would be considered the regional scale and the continental scale. However, on most other continents there would be a difference between what is considered regional and what continental. Perhaps of greatest concern on the continental scale is that the air pollution policies of a nation are likely to create impacts on neighboring nations. Acid rain in Scandanavia has been considered to have had impacts from Great Britain and Western Europe. Japan has considered that part of their air pollution problem, especially in the western part of the country, has origins in China and Korea. Cooperation in the examination of the North American acid rain problem has existed for a long time between Canada and the United States. 

Acid rain is the popular term for a very complex environmental problem. Over the past 25 years, evidence has accumulated on changes in aquatic life and soil pH in Scandinavia, Canada, and the northeastern United States. Many believe that these changes are caused by acidic deposition traceable to pollutant acid precursors that result from the burning of fossil fuels. Acid rain is only one component of acidic deposition, a more appropriate description of this phenomenon. Acidic deposition is the combined total of wet and dry deposition, with wet acidic deposition being commonly referred to as acid rain. 

An overview of acid rain monitoring activities in North America shows several national and regional programs in operation in the United States,... 

Acid deposition occurs when sulfur dioxide and nitrogen oxide emissions are transformed in the atmosphere and return to the earth in rain, fog or snow. Approximately 20 million tons of SOj are emitted annually in the United States, mostly from the burning of fossil fuels by electric utilities. Acid rain damages lakes, harms forests and buildings, contributes to reduced visibility, and is suspected of damaging health. 

In the United States the passage of the CAAAs of 1990, and their implementation starting in 1995, was an attempt to solve the acid rain problem mainly by reducing SO, emissions from electric power plants. While significant reductions in SO, emissions have occurred, and there already has been... 

Atmospheric emissions of sulphur dioxide are either measured or estimated at their source and are thus calculated on a provincial or state basis for both Canada and the United States (Figure 2). While much research and debate continues, computer-based simulation models can use this emission information to provide reasonable estimates of how sulphur dioxide and sulphate (the final oxidized form of sulphur dioxide) are transported, transformed, and deposited via atmospheric air masses to selected regions. Such "source-receptor" models are of varying complexity but all are evaluated on their ability to reproduce the measured pattern of sulphate deposition over a network of acid rain monitoring stations across United States and Canada. In a joint effort of the U.S. Environmental Protection Agency and the Canadian Atmospheric Environment Service, eleven linear-chemistry atmospheric models of sulphur deposition were evaluated using data from 1980. It was found that on an annual basis, all but three models were able to simulate the observed deposition patterns within the uncertainty limits of the observations (22). 

Acid rain is actually a catchall phrase for any kind of acidic precipitation, including snow, sleet, mist, and fog. Acid rain begins when water comes into contact with sulfur and nitrogen oxides in the atmosphere. These oxides can come from natural sources such as volcanic emissions or decaying plants. But there are man-made sources as well, such as power plant and automobile emissions. In the United States, two-thirds of all the sulfur dioxide and one-fourth of the nitrogen oxides in the atmosphere are produced by coal-burning power plants. 

Environmental Effects of Acid Rain. Acid Rain Program, United States Environmental Protection Agency, http //www.epa.gov/airmarkets/acidrain/index.html... 

The Eastern Canadian Acid Rain Program was highly successful at reducing SO2 emissions and sulfate wet deposition in eastern Canada (see Figure 10). Sulfur emissions actually declined more than the desired 50% by 1994, and have continued to decline modestly in the present. These SO2 emissions in the United States have also reduced dramatically, particularly since the implementation of the Canada-United States Air Quality Accord in 1991. This has been especially important to the aquatic and terrestrial ecosystems in eastern Canada, since US emissions are responsible for a large proportion of the acid deposition received in eastern Canada due to transboundary transport. 

Briefly, lakes in some areas of the world are now registering a low pH (acidic) reading because of excess acidity in rain. This was first noticed in Scandinavia and is now prevalent in eastern Canada and the northeastern United States. Normal rainfall has a pH of 5.6, and thus slight acidity (neutral water has a pH equal to 7.0), because the carbon dioxide (CO2) in the air combines with water to form carbonic acid (H2CO3) ... 

In the United States and other parts of the world, both low-sulfur diesel fuel and high-sulfur diesel fuel are being refined. Because fuel sulfur level has been identified as the primary component of fuel emission particulates and acid rain, sulfur reduction has been mandated and implemented. 

Acid rain in North America is most severe in the east, downwind of many coal-fired power plants. In the 3-year period 1995-1997, after S02 emissions were limited by a new law, concentrations of SOj and H in precipitation decreased by 10-25% in the eastern United States.18... 

The two photographs in (a) show the same obelisk before and after the effects of acid rain, (b) Many forests downwind from heavily industrialized areas, such as in the northeastern United States and in Europe, have been noticeably hard-hit by acid rain. 

The environmental impact of acid rain depends on local geology, as Figure 10.15 illustrates. In certain regions, such as the midwestern United States, the ground contains significant quantities of the alkaline compound calcium carbonate (limestone), deposited when these lands were submerged under oceans... 

---