Underground process

These data show that the areas of underground oil pollution sometimes can exceed the areas of surface pollution, and underground processes of self-purification go slowly due to restricted chemical and microbiological destruction of oil components. 

Underground process sewers to off-plant treatment facilities. 

Both the type and location of service urinals and stools for both men and women employees require prime consideration. It is important that the sanitary service be somewhat removed from the plant processing in order to simplify fittings underground. Process equipment service may interfere with sanitary service in drainage, since equipment drainage may overtax the system at periodic intervals. Therefore, each piece of equipment should drain directly into the main laterals. 

The following procedure may prove to be one of the largest advances in the field of MDMA chemistry since the perfection and dissemination of the Wacker oxidation procedure for producing MDP2P. This reaction is based on a published process that somehow has escaped discovery by underground chemistry until... 

Reinforced furan resias have been used for many years in process piping and in underground sewer or waste-disposal systems. With a wide range in pH acceptability and good solvent resistance, furan piping has been a logical choice for many services. 

Lubricants, Fuels, and Petroleum. The adipate and azelate diesters of through alcohols, as weU as those of tridecyl alcohol, are used as synthetic lubricants, hydrauHc fluids, and brake fluids. Phosphate esters are utilized as industrial and aviation functional fluids and to a smaH extent as additives in other lubricants. A number of alcohols, particularly the Cg materials, are employed to produce zinc dialkyldithiophosphates as lubricant antiwear additives. A smaH amount is used to make viscosity index improvers for lubricating oils. 2-Ethylhexyl nitrate [24247-96-7] serves as a cetane improver for diesel fuels and hexanol is used as an additive to fuel oil or other fuels (57). Various enhanced oil recovery processes utilize formulations containing hexanol or heptanol to displace oil from underground reservoirs (58) the alcohols and derivatives are also used as defoamers in oil production. 

Synthetic Processes. Traditional Solvay plants produce large volumes of aqueous, chloride-containing waste which must be discharged. This fact, in addition to a noncompetitive cost position, is largely responsible for the demise of U.S. synthetic plants. In countries other than the United States, waste is sent to the ocean, rivers, or deep underground wells. The AC and NA coproduct processes produce less aqueous waste than the traditional Solvay and NA mono processes. Related environmental concerns are added whenever a plant complex includes lime quarries and ammonia-producing equipment. 

Mining. Underground mining procedures are used for deep fluorspar deposits, and open-pit mines are used for shallow deposits or where conditions do not support underground mining techniques (see Mineral RECOVERY AND PROCESSING). 

Limestone Production. Because more than 99% of U.S. limestone is sold or used as cmshed and broken stone, rather than dimension-stone, most of the description of limestone s extraction and processing herein focuses on the former (Fig. 4). Most stone is obtained by open-pit quarrying methods. Underground mining is pursued by some important operations, but the toimage quarried exceeds that mined by nearly 20-fold. There is, however, a slight trend toward increased mining which should continue. 

In Situ Leaching. Copper and uranium ores are sometimes leached ia place by circulatiag acidified mine water through the underground deposit. This process is known as solution mining. 

In designing faciUties for handling and processing nitromethane, it is recommended that nitromethane not be processed in high pressure equipment. AH vessels for nitromethane service should be protected to prevent adiabatic compression. Detonation traps should be installed at each end of transfer lines and in every 61 m (200 feet) of continuous line. Nitromethane lines should be located underground or in channels wherever possible. Pressure rehef devices (rated - 690 kPa = 100 psig) should be installed between closed valves (81). 

Nuclear wastes are classified according to the level of radioactivity. Low level wastes (LLW) from reactors arise primarily from the cooling water, either because of leakage from fuel or activation of impurities by neutron absorption. Most LLW will be disposed of in near-surface faciHties at various locations around the United States. Mixed wastes are those having both a ha2ardous and a radioactive component. Transuranic (TRU) waste containing plutonium comes from chemical processes related to nuclear weapons production. These are to be placed in underground salt deposits in New Mexico (see... 

Chemical processing or reprocessing (39) of the fuel to extract the plutonium and uranium left a residue of radioactive waste, which was stored in underground tanks. By 1945, the reactors had produced enough plutonium for two nuclear weapons. One was tested at Alamogordo, New Mexico, in July 1945 the other was dropped at Nagasaki in August 1945. 

Consumption of natural gas, as of the mid-1990s, was about 2000 x 10 /yr. Using seismic detection equipment, exploration firms search for gas reserves buried deep underground and beneath the sea floor. Advanced computer systems process the seismic data to pinpoint the most likely locations for reserves. These advanced systems have both cut the time required for data analysis, by 80%, and gready improved the success rate for new drill rigs. 

In kaolin (clay) processing, sulfur dioxide reduces colored impurities, eg, iron compounds. In the bromine industry, sulfur dioxide is used as an antioxidant in spent brine to be reinjected underground. In agriculture, especially in California, sulfur dioxide is used to increase water penetration and the avadabiHty of soil nutrients by virtue of its abiHty to acidulate saline—alkaH soils (327). It is also usefiil for cleaning ferric and manganese oxide deposits from tile drains (328). 

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