1,1,1-Trimethylolpropane trimethacrylate

EPM/EPDM compounding pLASTOTffiRS, SYNTHETIC - ETHYLENE-PROPYLENE-DIENE RUBBER] (Vol 8) Trimethylolpropane trimethacrylate [3290-92-4]... 

The polymers were prepared using MAA as functional monomer and EDMA as crosslinking monomer if not otherwise noted. VPY= 2- or 4-vinylpyridine TRIM = trimethylolpropane trimethacrylate DPGE = (R)-N,0-dimethacryloylphenylglycinol PYAA = 3-(4-pyridinyl)acrylic acid. 

FIGURE 13.8 Co-agents used. From left to right m-phenylenedimaleitnide (PDMI), m-phenylenedi(maleamic acid) (PDMA), l,6-hexamethylenedi(maleamic acid) (HMDMA), and trimethylolpropane trimethacrylate (TMPTMA). 

A different approach, although stdl working with essentially non-fiinctional polymers has been exemplified [114,115], in which, a 100% solid (solvent free) hot melt has been irradiated to produce pressure-sensitive adhesives with substantially improved adhesive properties. Acrylic polymers, vinyl acetate copolymers with small amounts of A,A -dimethylaminoethyl methacrylate, diacetone acrylamide, A-vinyl pyrrohdone (NVP) or A A have been used in this study. Polyfunctional acrylates, such as trimethylolpropane trimethacrylate (TMPTMA) and thermal stabilizers can also be used. 

FIGURE 31.2 Plots of crystalline melting point, heat of fusion and percent crystallinity of ethylene-vinyl acetate (EVA) samples versus (a) radiation dose (b) trimethylolpropane trimethacrylate (TMPTMA) level from differential scanning calorimetry (DSC) studies. (From Datta, S.K., Bhowmick, A.K., Chaki, T.K., Majali, A.B., and Deshpande, R.S., Polymer, 37, 45, 1996. With permission.)... 

It was found, when an attempt was made to conduct ship trials that the paint applier would be required to wear long sleeves, gloves, safety glasses, and a protective face shield. It is also a requirement that an eyewash fountain be nearby. These requirements were imposed because acrylates are skin, eye and respiratory tract irritants, but the problem lies mostly with the acrylated reactive diluent rather than with the acrylated resin (2,3). To avoid these problems, tests have been performed with use of trimethylolpropane trimethacrylate (TMPTMA) as a replacement for TMPTA. TMPTMA has been shown to be much less of an irritant than TMPTA, and is used in dental restorations. 

Trimethylolpropane, el 83 Trimethylolpropane triacrylate, el 14 Trimethylolpropane trimethacrylate, el 85 l,3,3-Trimethyl-2-oxabicyclo[2.2.2]octane, c277... 

Fig. 21. Molecular imprinting of (R)-propranolol using methacrylic acid (MAA) as the functional monomer and trimethylolpropane trimethacrylate (TRIM) as the crosslinking monomer. (Reprinted with permission from [126], Copyright 1998 Elsevier). The enantiose-lectivity of a given polymer is predetermined by the configuration of the ligand, R-propranolol present during its preparation. Since the imprinted enantiomer possesses a higher affinity for the polymer, the separation is obtained with a predictable elution order of the enantiomers...

The influence of adding polyfunctional monomers having different structures and functionality into a dicumyl peroxide-based crosslinking system for LDPE was investigated. Monomers employed were diallyl phthalate, trimethylolpropane trimethacrylate and triallyl cyanurate. The effects of formulation on matrix gel content and on foam density at similar gel content were examined and the dependence of foam density on melt modulus assessed. The applicability of swell ratio for estimating foam density was evaluated and the suitability of triallyl cyanurate as a crosslinking promoter for LDPE foam demonstrated. 20 refs. 

Figure 15.1 Examples of common cioss-liiikers used in the preparation of molecular imprinted polymers ethylene glycol dimethylcrylate (EGDMA) divinyl benzene (DVB), trimethylolpropane trimethacrylate (TRIM), VA -methylenebisacrylamide (MBA), and V,0-bismethacryloyl ethanolamine (NOBE).

Glad M, Reinholdsson P, Mosbach K. Molecularly imprinted composite polymers based on trimethylolpropane trimethacrylate (TRIM) particles for efficient enantiomeric separations. React Polym 1995 25 47-54. 

The most effective prorads for PVC are acrylic and allylic esters, such as triallyl cyanurate (TAC), trimethylolpropane trimethacrylate (TMPTMA), and trimethylolpropane triacrylate. The triacrylate is more reactive than the trimethacrylate, but it is more toxic and, for that reason, is used only seldom. The amounts of these additives are 1 to 5% of the formulation weight. ... 

Note phr = parts per hundred parts of rubber, ENB = ethylene norbornene (curing site in the elastomer), TMPT = trimethylolpropane trimethacrylate (prorads). 

Hydrated aluminum oxide is a preferred flame refardanf fhaf liberates its water of hydrafion when exposed to flames, in contrast to chlorinated materials, which give off toxic gases as by-products. The paraffin oil is a processing aid that enhances the ability to extrude such materials. The silane is a coupling agent that improves the interaction between the polymers and the aluminum trihydrate. Trimethylolpropane trimethacrylate (TMPT) enhances the radiation response. 

TOP Tobacco peroxidase, HRP Horseradish peroxidase, APB A 3-Aminophenylboronic acid monohydrate, TBA 3-Thiopheneboronic acid, VYP 4-vinylpyridine, TRIM Trimethylolpropane trimethacrylate... 

MIP films, applied to a QCM transducer, have been employed for chiral recognition of the R- and 5-propranolol enantiomers [107]. MIP films were prepared for that purpose by surface grafted photo-radical polymerization. First, a monolayer of 11-mercaptoundecanoic acid was self-assembled on a gold electrode of the quartz resonator. Then, a 2,2 -azobis(2-amidinopropane) hydrochloride initiator (AAPH), was attached to this monolayer. Subsequently, this surface-modified resonator was immersed in an ACN solution containing the MAA functional monomer, enantiomer template and trimethylolpropane trimethacrylate (TRIM) cross-linker. Next, the solution was irradiated with UV light for photopolymerization. The resulting MIP-coated resonator was used for enantioselective determination of the propranolol enantiomers under the batch [107] conditions and the FIA [107] conditions with an aqueous-ACN mixed solvent solution as the carrier. The MIP-QCM chemosensor was enantioselective to 5-propranolol at concentrations exceeding 0.38 mM [107]. 

Fatty acid esters Ethyl acetate, methyl methacrylate, trimethylolpropane trimethacrylate, decyl methacrylate, 2-hydroxyethyl methacrylate, ethoxy ethyl acetate, methyl palmitate, ethyl palmitate, isopropyl palmitate, butyl palmitate, isobutyl palmitate, methyl margarate, butyl margarate, methyl stearate, ethyl stearate, butyl stearate, isobutyl stearate, methyl oleate, bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) sebacate, methyl linoleate, methyl laurate, octyl laurate, methyl myristate, isobutyl myristate, butyl myristate, dihydroisopimaric add methyl ester... 

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