Transport equation joint scalar dissipation rate

A spectral model similar to (3.82) can be derived from (3.75) for the joint scalar dissipation rate eap defined by (3.139), p. 90. We will use these models in Section 3.4 to understand the importance of spectral transport in determining differential-diffusion effects. As we shall see in the next section, the spectral interpretation of scalar energy transport has important ramifications on the transport equations for one-point scalar statistics for inhomogeneous turbulent mixing. 

The first factor occurs even in homogeneous flows with two inert scalars, and is discussed in Section 3.4. The second factor is present in nearly all turbulent reacting flows with moderately fast chemistry. As discussed in Chapter 4, modeling the joint scalar dissipation rate is challenging due to the need to include all important physical processes. One starting point is its transport equation, which we derive below. 

The transport equation for the joint scalar dissipation rate can be derived following the same steps used to derive (3.110). We begin by defining the fluctuating scalar gradients as... 

On the other hand, on the bounding hypersurfaces the normal diffusive flux must be null. However, this condition will result naturally from the fact that the conditional joint scalar dissipation rate must be zero-flux in the normal direction on the bounding hypersurfaces in order to satisfy the transport equation for the mixture-fraction PDF.122... 

The SR model introduced in Section 4.6 describes length-scale effects and contains an explicit dependence on Sc. In this section, we extend the SR model to describe differential diffusion (Fox 1999). The key extension is the inclusion of a model for the scalar covariance l(p a(p p) and the joint scalar dissipation rate sap. In homogeneous turbulence, the covariance transport equation is given by (3.179), p. 97. Consistent with the cospectrum transport equation ((3.75), p. 78), we will define the molecular diffusivity of the covariance as... 

The description is based on the previously defined single-particle (Lagrangian) or one-point (Eulerian) joint velocity-composition (micro-)PDF, /(r,yr). As mentioned in Section 12.4.1, in the one-point description no information on the local velocity and scalar (species concentrations, temperature,. ..) gradients and on the frequency or length scale of the fluctuations is included and the related terms require closure models. The scalar dissipation rate model has to relate the micro-mixing time to the turbulence field (see (12.2-3)), either directly or via a transport equation for the turbulence dissipation rate e. A major advantage is that the reaction rate is a point value and its behavior and mean are described exactly by a one-point PDF, even for arbitrarily complex and nonlinear reaction kinetics. 

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