Titanium extraction

The cake produced by the digestion is extracted with cold water and possibly with some diluted acids from the subsequent processes. During the cake dissolution it is necessary to maintain the temperature close to 65°C, the temperature of iron sulfate maximum solubiUty. To prevent the reoxidation of the Fe " ions during processing, a small amount of Ti " is prepared in the system by the Ti reduction. The titanium extract, a solution of titanium oxo-sulfate, iron sulfate, and sulfuric acid, is filtered off. Coagulation agents are usually added to the extract to faciUtate the separation of insoluble sludge. 

Krishnaswamy R. 1984. Study of availability and composition of metal bearing wastes (generated in titanium extraction and fabrication, aluminum smelters, chromite bearing refractory and foundry sands and mercury battery industries). Report to US Bureau of Mines, Washington, DC, by NH Parker, PE and Associates, La Crescenta, CA. NTIS No. PB84-207091. 

The apparatus for the chlorination of titanium raw stock in a fluidised layer is a cylindrical shaft lined with thick silica brick. There are several shelves with gas distribution grates located one above another for better chlorine consumption and titanium extraction. The parent mixture is loaded onto the top shelf where it is partially chlorinated with unreacted chlorine coming from below and is sent onto the next shelf through a pipe. The most intensive chlorination occurs on the lower shelf. 

Sun K. Metallurgical Physical Chemistry of Titanium Extraction, (Beijing Metallurgical Industry Press, 2001 24)... 

Th, Bl, Mo, Zn, and Cr by O.IM TOPO from aqueous solutions Is given as a function of nitric acid concentration In figure 46j as a function of hydrochloric acid concentration In figure Iron and titanium extraction curves are... 

Beryllium is added to copper to produce an alloy with greatly increased wear resistance it is used for current-carrying springs and non-sparking safety tools. It is also used as a neutron moderator and reflector in nuclear reactors. Much magnesium is used to prepare light nieial allo>s. other uses include the extraction of titanium (p. 370) and in the removal of oxygen and sulphur from steels calcium finds a similar use. 

Chlorine is also used in the manufacture of hydrochloric acid, the extraction of titanium, and the removing of tin from old tinplate ( de-tinning ). 

The extraction of titanium is still relatively costly first the dioxide Ti02 is converted to the tetrachloride TiCl4 by heating with carbon in a stream of chlorine the tetrachloride is a volatile liquid which can be rendered pure by fractional distillation. The next stage is costly the reduction of the tetrachloride to the metal, with magnesium. must be carried out in a molybdenum-coated iron crucible in an atmospheric of argon at about 1100 K ... 

Chlorination. In some instances, the extraction of a pure metal is more easily achieved from the chloride than from the oxide. Oxide ores and concentrates react at high temperature with chlorine gas to produce volatile chlorides of the metal. This reaction can be used for common nonferrous metals, but it is particularly useful for refractory metals like titanium (see Titanium and titanium alloys) and 2irconium (see Zirconium and zirconium compounds), and for reactive metals like aluminum. 

Selective solution of the aluminum from the ahoy using a volatile metal, such as mercury, lead, bismuth, cadmium, magnesium, or zinc, has been investigated. After extracting the aluminum from the original ahoy into the volatile metal, the volatile metal is distilled, leaving pure aluminum. Neither electrolysis nor volatile metal extraction can extract aluminum from iron aluniinide [12004-62-3J, EeAl, titanium aluniinide [12004-78-3] TiAl, or Al C. ... 

In energy extraction, titanium alloys are being used in deep-water hydrocarbon and geothermal weUs for risers. Corrosion resistance, high strength, low modulus (flexible), and low density can result in risers one-fourth the weight and three times the flexibiHty of steel. 

The U.S. titanium market distribution is shown in Table 18. Before 1970, more than 90% of the titanium produced was used for aerospace, which feU to ca 70—80% by 1982. Mihtary use has continually decreased from nearly 100% in the early 1950s to 20% in the 1990s. In contrast to the United States, aerospace uses in Western Europe and Japan account for only 40—50% of the demand (58). The CIS s consumption of titanium metal prior to the breakup was about one-half of the world consumption. In the 1980s, considerable amounts were used for submarine constmction. Since the breakup of the former Soviet Union, the internal consumption of titanium in the CIS is beheved to be a modest fraction of its former capacity, thus leaving a large capacity available for export. The world production faciUties for titanium metal and extraction are given in Table 19. 

Arsonium salts have found considerable use in analytical chemistry. One such use involves the extraction of a metal complex in aqueous solution with tetraphenyiarsonium chloride in an organic solvent. Titanium(IV) thiocyanate [35787-79-2] (157) and copper(II) thiocyanate [15192-76-4] (158) in hydrochloric acid solution have been extracted using tetraphenyiarsonium chloride in chloroform solution in this manner, and the Ti(IV) and Cu(II) thiocyanates deterrnined spectrophotometricaHy. Cobalt, palladium, tungsten, niobium, and molybdenum have been deterrnined in a similar manner. In addition to their use for the deterrnination of metals, anions such as perchlorate and perrhenate have been deterrnined as arsonium salts. Tetraphenyiarsonium permanganate is the only known insoluble salt of this anion. 

Extraction of Bertrandite. Bertrandite-containing tuff from the Spor Mountain deposits is wet milled to provide a thixotropic, pumpable slurry of below 840 p.m (—20 mesh) particles. This slurry is leached with sulfuric acid at temperatures near the boiling point. The resulting beryUium sulfate [13510-49-1] solution is separated from unreacted soflds by countercurrent decantation thickener operations. The solution contains 0.4—0.7 g/L Be, 4.7 g/L Al, 3—5 g/L Mg, and 1.5 g/L Fe, plus minor impurities including uranium [7440-61-1/, rare earths, zirconium [7440-67-7] titanium [7440-32-6] and zinc [7440-66-6]. Water conservation practices are essential in semiarid Utah, so the wash water introduced in the countercurrent decantation separation of beryUium solutions from soflds is utilized in the wet milling operation. 

Erom 1955—1975, the Ziegler-Natta catalyst (91), which is titanium trichloride used in combination with diethylaluminum chloride, was the catalyst system for propylene polymerization. However, its low activity, which is less than 1000 g polymer/g catalyst in most cases, and low selectivity (ca 90% to isotactic polymer) required polypropylene manufacturers to purify the reactor product by washing out spent catalyst residues and removing unwanted atactic polymer by solvent extraction. These operations added significantly to the cost of pre-1980 polypropylene. 

Solutions in contact with polyvinyl chloride can become contaminated with trace amounts of lead, titanium, tin, zinc, iron, magnesium or cadmium from additives used in the manufacture and moulding of PVC. V-Phenyl-2-naphthylamine is a contaminant of solvents and biological materials that have been in contact with black rubber or neoprene (in which it is used as an antioxidant). Although it was only an artefact of the separation procedure it has been isolated as an apparent component of vitamin K preparations, extracts of plant lipids, algae, livers, butter, eye tissue and kidney tissue [Brown Chem Br 3 524 1967]. 

Figure 4 Plot of time-resolved decomposition of titanium-enriched slags as extracted from neutron diffraction data collected at 1000° C.

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