Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Thiol group replacement with hydrogen

On the other hand, conjugated nitroalkenes are very useful electron-poor alkenes, prone to act as nucleophilic acceptor, mainly in the Michael reaction (Berestovitaskaya et al., 1994) or in the Diels-Alder cycloaddition (Denmark and Thorarensen, 1996). Moreover, the nitro group can be easily turned into a respectable array of functional groups such as its reduction to a primary amine, replacement with hydrogen (Ballini et al., 1983 Ono, 2001), conversion into a carbonyl (Nef reaction) (Ballini and Petrini, 2004), and transformation into other important functionalities such as nitrile, nitrile oxide, oximes, hydroxylamines, and thiols (Colvin et al., 1979). [Pg.55]

The action of aniline on 3-phenyl-5-mercapto-l,2,4-thiadiazole under restrained conditions is reported to remove the mercapto group as hydrogen sulfide, with formation of the corresponding 5-anilino compound.75,200 This replacement, normally difficult in aromatic systems, may be due to the unusual reactivity of the thiol grouping in this particular structural environment. [Pg.189]

Thioles of type 44 (X = S) are of synthetic utility, since the SH-group can be replaced by hydrogen. This transformation is accomplished by oxidation of the thiol with H2O2 to a sulfinic acid moiety, which thermally eliminates SO2 (oxidative dethionation), for example ... [Pg.225]

HFBA). Alkylation is used to replace reactive hydrogens associated with carboxylic acids, hydroxyls, thiols, phenols, and both primary and secondary amines with alkyl groups by using alkyl halide reagents. Esterification of acids by using a simple alcohol and acidic catalyst is a well-known example of this derivatization procedure. [Pg.374]

If one or more of the hydrogen atoms of a non-metal hydride are replaced formally with another group, R—e.g., alkyl residues—then derived compounds of the type R-XHn-i, R-XHn-2-R, etc., are obtained. In this way, alcohols (R-OH) and ethers (R-O-R) are derived from water (H2O) primary amines (R-NH2), secondary amines (R-NH-R) and tertiary amines (R-N-R R") amines are obtained from ammonia (NH3) and thiols (R-SH) and thioethers (R-S-R ) arise from hydrogen sulfide (H2S). Polar groups such as -OH and -NH2 are found as substituents in many organic compounds. As such groups are much more reactive than the hydrocarbon structures to which they are attached, they are referred to as functional groups. [Pg.10]


See other pages where Thiol group replacement with hydrogen is mentioned: [Pg.301]    [Pg.10]    [Pg.301]    [Pg.301]    [Pg.195]    [Pg.379]    [Pg.281]    [Pg.416]    [Pg.393]    [Pg.114]    [Pg.619]    [Pg.723]    [Pg.619]    [Pg.1683]    [Pg.35]    [Pg.2]    [Pg.498]    [Pg.461]    [Pg.344]    [Pg.45]    [Pg.723]    [Pg.619]    [Pg.368]    [Pg.251]    [Pg.25]    [Pg.311]    [Pg.450]    [Pg.645]    [Pg.1135]    [Pg.398]    [Pg.223]    [Pg.290]    [Pg.433]    [Pg.818]    [Pg.210]    [Pg.24]    [Pg.373]    [Pg.413]    [Pg.257]    [Pg.125]    [Pg.131]    [Pg.233]    [Pg.241]    [Pg.442]    [Pg.205]    [Pg.196]   
See also in sourсe #XX -- [ Pg.252 ]




SEARCH



Group, replacement

Hydrogen groups

Hydrogen replacement

Hydrogenation group

Replacement with

Thiol groups

Thiols groups

Thiols/thiol groups

© 2024 chempedia.info