The Optical Transparency of Solids

THE OPTICAL TRANSPARENCY OF SOLIDS EXAMPLE 4.4 The absorption edge of Ge. 

Point defects can have a profound effect upon the optical properties of solids. The most important of these in everyday life is color,3 and the transformation of transparent ionic solids into richly colored materials by F centers, described below, provided one of the first demonstrations of the existence of point defects in solids. 

A wealth of information about photolumescent materials, their properties and conditions for their optimum preparation is found in [257]. In combination with glass substrates coated with transparent electrodes, the electro-optical properties of liquid crystal films, which themselves emit no light, offer some interesting possibilities [258, 259]. Liquid crystals have the mobility of liquids and the optical properties of solids. The molecular structure lies between the liquid and solid state. Liquid crystals are organic compounds of relatively long molecules compared with their diameter, and often contain polar groups and multiple bonds. 

Active enzymes were encapsulated into a sol-gel matrix for the first time in 1990 719 About 60 different types of hybrid bioceramic materials with inotganic matrices made from silicon, titanium, and zirconium oxides Ti02-cellulose composites etc. were described. Recentiy, bioceramic sensors, solid electrolytes, electrochemical biosensors, etc. have been surveyed in a review. The moderate temperatures and mild hydrolytic and polymerization conditions in sol-gel reactions of alkoxides make it possible to trap proteins during matrix formation. This prevent proteins denaturation. The high stability of the trapped biomolecules, the inertness, the large specific surface, the porosity, and the optical transparency of the matrix facilitate use of sol-gel immobilization. The principal approaches ate considered below. 

Another way to achieve uniform illumination is to lower the optical density of the sample by increasing the effective molar volume. Solid solution of an absorbing guest in a transparent host in either a normal crystal or a molecular inclusion compound can achieve this end so can using a pure crystal of a much larger molecule which includes the chromophore of interest [27]. While it is harder to reach high dilution with the latter approach, it has the virtue that the initial compound is a pure crystal and thus better suited for definitive X-ray investigation. 

Polarimeter Instrument that measures the optical rotation of a transparent liquid or solid. 

These coefficients have the dimension of reciprocal length (Mills, 1988), in this context, cm Kubelka and Munk (1931) described the optical properties of pigments by employing the parameters a and r. The Kubelka-Munk theory is the basis of diffuse reflection spectroscopy (Sec. 6.4). We have extended the Kubelka-Munk approach in order to describe the Raman scattering of crystal powders (Schrader and Bergmann, 1967). The results can also be applied to liquids and transparent solids. The procedure is as follows ... 

A diamond-anvil-cell (DAG) is a small high pressure cell most suitable for the spectroscopic measurement of molecular or atomic diffusion. The DAG is used for various kinds of spectroscopic investigations on liquids and solids at pressures up to several tens of GPa [19-22]. The optically transparent nature of diamond over a wide wavelength span allows in situ optical measurements in combination with conventional equipment such as visible light or infrared spectrometers. The protonic diffusion in ice is measured by a traditional diffusion-couple method, in the present case, with an H2O/D2O ice bilayer. The mutual diffusion of hydrogen (H) and deuteron (D) in the ice bUayer is monitored by measuring the infrared vibrational spectra. The experimental details are described in the following sections. 

The technique of laser heating in a DAC is based on three main features optical transparency of diamond anvils the samples can be heated via the optical absorption of intense laser radiation, and the temperature can be determined from the thermal radiation spectrum of the heated sample using the Planck formula [10]. Laser radiation for heating of a sample in a DAC was first implemented by Ming and Bassett [11], who used a pulsed ruby laser, and a continuous-wave Nd-YAG (yttrium-aluminum-garnet) laser to heat samples in a DAC above 3300 K, and up to 2300 K, respectively. Today two types of continuous wave infrared (IR) lasers are extensively used in laser heating experiments Solid state lasers (Nd-doped YAG, or YLF (yttrium-lithium-fluorite) crystals with the most intense line at... 

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