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Terpenoids diterpenes

The effects of GB are attributed to several chemical constituents of the whole plant rather than to any one individual component. These chemicals include many flavonoids (also called flavonol, flavone, or flavonoid glycosides, ginkgo flavone glycosides, dimeric bioflavones), and the terpene lactones (also called terpenoids, diterpenes, terpenes), including the ginkgolides and bilobalide (2,5-7). [Pg.42]

Alkaloids can be divided into different t q3es according their pure chemical structures pointing first at the alkaloid base, a basic chemical nucleus. The following are basic types of alkaloids acridones, aromatics, carbo-lines, ephedras, ergots, imidazoles, indoles, bisindoles, indolizidines, manza-mines, oxindoles, quinolines, quinozolines. quinolizidines, phenylisoquinolines, phenylethylamines, piperidines, purines, pyrolidines, pyrrolizidines, pyrro-loindoles, pyrydines, sesquiterpenes, simple tetrahydroisoquinolines, stereoids, tropanes, terpenoids, diterpenes, and triterpenes. [Pg.8]

Terpenoid (diterpene) Aconine Aconitum napellus Ranunculaceae... [Pg.416]

Briareum sp. Terpenoids (diterpene) Stecholide L Cytotoxic activity [34] ... [Pg.320]

Lophogorgia violacea Terpenoid (diterpenes) Lophotoxin deoxylophotoxin 13-acetoxy-11 p,12p- epoxypukalide 7-acetoxy-8-hydroxylophotoxin 3-methoxy-8-hydroxylophotoxin Chemical deterrence against generalist fish [68]... [Pg.323]

Phyllogorgia dilatata Terpenoid (diterpene) 11 P,12P-Epoxypukalide crude extract Chemical deterrence against generalist fish [69]... [Pg.323]

Xenia eiongata Terpenoids (diterpene) Deoxyxeniolide m Ichthyotoxic activity against Japanese killifish Oryzia latipes [72]... [Pg.323]

Xenia macrospiculata Terpenoids (diterpenes) Crude extract and desoxyhavannahine Antimicrobial activity against Arthrobacter sp. [76]... [Pg.324]

Briareum polyanthes Terpenoids (diterpenes) Eu nicel 1 i n-type asbesti nane-type briarane-type Activity against pathogenic microbes of human infectious diseases [77]... [Pg.324]

Since GAs as diterpenes share many intermediates in the biosynthetic steps leading to other terpenoids, eg, cytokinins, ABA, sterols, and carotenoids, inhibitors of the mevalonate (MVA) pathway of terpene synthesis also inhibit GA synthesis (57). Biosynthesis of GAs progresses in three stages, ie, formation of / Akaurene from MVA, oxidation of /-kaurene to GA 2" hyde, and further oxidation of the GA22-aldehyde to form the different GAs more than 70 different GAs have been identified. [Pg.47]

Wood is the raw material of the naval stores iadustry (77). Naval stores, so named because of their importance to the wooden ships of past centuries, consist of rosin (diterpene resin acids), turpentine (monoterpene hydrocarbons), and associated chemicals derived from pine (see Terpenoids). These were obtained by wounding the tree to yield pine gum, but the high labor costs have substantially reduced this production in the United States. Another source of rosin and turpentine is through extraction of old pine stumps, but this is a nonrenewable resource and this iadustry is in decline. The most important source of naval stores is spent sulfate pulpiag Hquors from kraft pulpiag of pine. In 1995, U.S. production of rosin from all sources was estimated at under 300,000 metric tons and of turpentine at 70,000 metric tons. Distillation of tall oil provides, in addition to rosin, nearly 128,000 metric tons of tall oil fatty acids annually (78). [Pg.331]

Terpenes (and terpenoids) are further classified according to the number of 5-carbon units they contain. Thus, monoterpenes are 10-carbon substances biosynthesized from two isoprene units, sesquiterpenes are 15-carbon molecules from three isoprene units, diterpenes are 20-carbon substances from four isoprene units, and so on. Monoterpenes and sesquiterpenes are found primarily in plants, but the higher terpenoids occur in both plants and animals, and many have important biological roles. The triterpenoid lanosterol, for example, is the precursor from which all steroid hormones are made. [Pg.203]

Ulubelen, A. Oksiiz, S. Kolak, U. Birman, H. Voelter, W. Cardioactive terpenoids and a new rearranged diterpene from Salvia syriaca. Planta Med. 2000, 66, 627-629. [Pg.290]

That terpenoid metabolites can also be up-regulated in response to herbivory was demonstrated with the brown alga Dictyota menstrualis. The generalist amphipod Amphithoe longimana induced increased concentrations of the defensive diterpenes 65-67 in this alga, making it less palatable (Scheme 18). [Pg.207]

A recent example demonstrates that corals rely on induced biosynthesis of terpenes as a dynamic defense strategy as well. The induction of terpenoid secondary metabolites was observed in the sea whip Pseudopterogorgia elisabethae [162]. Levels of pseudopterosins 89-92, a group of diterpene glycosides with anti-inflammatory and analgesic properties (Scheme 23) [163-165], are increased in response predation by the mollusk Cyphoma gibbosum. First bioassays indicate that these natural products are involved in the chemical defense. [Pg.216]

Essential oils may comprise volatile compounds of terpenoid or non-terpe-noid origin. All of them are hydrocarbons and their oxygenated derivatives. Some may also contain nitrogen or sulphur derivatives. They may exist in the form of alcohols, acids, esters, epoxides, aldehydes, ketones, amines, sulphides, etc. Monoterpenes, sesquiterpenes and even diterpenes constitute the composition of many essential oils. In addition, phenylpropanoids, fatty acids and their esters, or their decomposition products are also encountered as volatiles [1-16, 21-33, 36-38]. [Pg.43]

Gershenzon, J. and Croteau, R. (1993). Terpenoid biosynthesis the basic pathway and formation of monoterpenes, sesquiterpenes and diterpenes. In Lipid Metabolism in Plants, ed. T. S. Moore Jr, pp. 339-388. Boca Raton, FL CRC Press. [Pg.170]

The diverse, widespread and exceedingly numerous class of natural products that are derived from a common biosynthetic pathway based on mevalonate as parent, are synonymously named terpenoids, terpenes or isoprenoids, with the important subgroup of steroids, sometimes singled out as a class in its own right. Monoterpenes, sesquiterpenes, diterpenes and triterpenes are ubiquitous in terrestrial organisms and play an essential role in life, as we know it. Although the study of terrestrial terpenes dates back to the last century, marine terpenes were not discovered until 1955. [Pg.687]

The terpenoids form a large and structurally diverse family of natural products derived from C5 isoprene units (Figure 5.1) joined in a head-to-tail fashion. Typical structures contain carbon skeletons represented by (Cs) , and are classified as hemiterpenes (C5), monoterpenes (C10), sesquiterpenes (C15), diterpenes (C2o), sesterterpenes (C25), triterpenes (C30) and tetraterpenes (C40) (Figure 5.2). Higher polymers are encountered in materials such as rubber. Isoprene itself (Figure 5.1) had been characterized as a decomposition product from various natural cyclic hydrocarbons, and was suggested as the fundamental building block for these compounds, also referred to as isoprenoids . Isoprene is produced naturally but is not involved in the formation of... [Pg.167]


See other pages where Terpenoids diterpenes is mentioned: [Pg.298]    [Pg.190]    [Pg.269]    [Pg.288]    [Pg.357]    [Pg.40]    [Pg.9]    [Pg.82]    [Pg.309]    [Pg.45]    [Pg.45]    [Pg.455]    [Pg.376]    [Pg.392]    [Pg.407]    [Pg.426]    [Pg.464]    [Pg.375]    [Pg.130]    [Pg.235]    [Pg.237]    [Pg.689]    [Pg.691]    [Pg.1052]    [Pg.167]    [Pg.203]   
See also in sourсe #XX -- [ Pg.20 , Pg.706 ]

See also in sourсe #XX -- [ Pg.39 ]




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