Temperature lignocellulose steam

Forest products industries know that temperature increases in piles of sawdust and bark. In pulp and paper mills, self-heating develops in amassed tree chips. Paper rolls stacked hot tend to self-heat, as occasionally do stored bales of waste paper. The wood-base panel products particleboard, hardboard, and fiberboard self-heat after being stacked too hot in the factory. Where in structures the framing lumber, wood-base panels, and lignocellulosic insulation is heated by items such as steam pipes, temperatures tend to rise above that of the heat source. 

Because the hemicellulose fraction of biomass materials can be separated from lignin and cellulose by dilute acid treatment, cellulose becomes more reactive towards cellulase. Hemicellulose hydrolysis rates vary with acid concentration, temperature, and solid-to-liquid ratio. With most lignocellulosic materials, complete hemicellulose hydrolysis can be achieved in 5-10 min at 160°C or 30-60 min at 140 °C. Dilute acid hydrolysis forms the basis of many pretreatment processes for example, autohydrolysis and steam explosion are based on high-temperature dilute acid catalyzed hydrolysis of biomass. 

In cellulosic ethanol production processes, a pretreatment procedure is needed to disrupt the recalcitrant structure of the lignocellulosic materials so that the cellulose can be more efficiently hydrolyzed by cellulase enzymes [2], These pretreatments include physical, biological, and chemical ways, such as uncatalyzed steam explosion, liquid hot water, dilute acid, flow-through acid pretreatment, lime, ammonium fiber/freeze explosion, and ammonium recycle percolation [3, 4], Most of these methods involve a high temperature requirement, which is usually achieved through convection- or conduction-based heating. 

Carbon dioxide explosion is a pre-treatment process that uses supercritical carbon dioxide to break down the biomass structure. In aqueous solution, carbon dioxide forms carbonic acid which depolymerizes lignocellulosic materials. As a small molecule, carbon dioxide can penetrate into the pores of the biomass better than ammonia. When carbon dioxide explodes due to the change of pressure, it breaks the cellulosic structure. This process is usually operated under high pressure but low temperature to prevent monosaccharide degradation. But in comparison to steam explosion and ammonia explosion processes, the sugar recovery yield from this process is... 

In industry, activated carbons are essentially produced by carbonization (pyrolysis at temperatures up to 900°C under neutral atmosphere) of various precursors (lignocellulosic, polymers, anthracites,. ..), followed by physical and chemical activation [1], Physical activation is generally realized around 900°C through partial gasification of carbon, using CO2 or steam, according to Eqs. 12.1 and 12.2 ... 

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