Tailored compensation

Inevitably, there will be a residual effect after applying structural compensation techniques for which it cannot cater, and this residual effect will vary between nominally identical sensors. Further techniques of minor adjustment are thus needed to minimise the residue. The term tailored compensation refers to trimming techniques that require action determined by the individual sensor and not the overall design, a major cost item in the traditional industry. 

Extrinsic Defects Extrinsic defects occur when an impurity atom or ion is incorporated into the lattice either by substitution onto the normal lattice site or by insertion into interstitial positions. Where the impurity is aliovalent with the host sublattice, a compensating charge must be found within the lattice to pre-serve elec-troneutality. For example, inclusion of Ca in the NaCl crystal lattice results in the creation of an equal number of cation vacancies. These defects therefore alter the composition of the solid. In many systems the concentration of the dopant ion can vary enormously and can be used to tailor specific properties. These systems are termed solid solutions and are discussed in more detail in Section 25.1.2. 

Some of the major questions that semiconductor characterization techniques aim to address are the concentration and mobility of carriers and their level of compensation, the chemical nature and local structure of electrically-active dopants and their energy separations from the VB or CB, the existence of polytypes, the overall crystalline quality or perfection, the existence of stacking faults or dislocations, and the effects of annealing upon activation of electrically-active dopants. For semiconductor alloys, that are extensively used to tailor optoelectronic properties such as the wavelength of light emission, the question of whether the solid-solutions are ideal or exhibit preferential clustering of component atoms is important. The next... 

Good financial planning is a combination of analysis and application tailored to your specific needs and circumstances. It is not a sales approach for marketing investment products. Therefore, you need to sort out the method of compensation that best suits your situation. 

Fortunately, they are several species of low-loss dielectric ceramics with tailored temperature coefficient of dielectric constant, which can be made lower than 1 ppm/K for a certain temperature window around room temperature. Physically, this can be accomplished either by intrinsic compensation of the temperature dependence of thermal volume expansion V(T) and lattice polarizability a(T) via the Clausius-Mossotti relation ... 

Allocation to the power sector only could be tailored to compensate losses... 

NMR analysis of a paramagnetic biomolecule may require modifications to the standard experiments. In some cases, this is to compensate for deleterious line broadening caused by unpaired electrons, which interferes with detection of resonances and NOEs. In other cases, modifications are made to take advantage of the effects of unpaired electrons to selectively observe nuclei in the vicinity of the paramagnetic metal. The effects of the metal on the NMR spectrum depend largely on the Xs value, which determines amount of linebroadening (equations 16 and 17). For systems with relatively short tg, few, if any, modifications need to be made, whereas study of systems with long tg require specially tailored experiments to obtain any information on nuclei in the vicinity of the metal site. ... 

Zeolitic materials have been widely used in the last decades in the chemical and petrochemical industries. This increasing interest on these materials is based in their unique properties a uniform intra-crystalline microporosity that provides aceess to a large and well-defined surface, the molecular sieve effect, and the electrostatic field centered at zeolite cations. Furthermore, some properties of zeolites can be tailored by changing the nature of the compensating cation located in the inner part of the cavities by means of their ion-exchange capability. In this way, the pore accessibility of some zeolites used in gas separation processes, as well as the adsorbent-adsorbate interactions, can be tailored by the introduction of cations with different size and chemical nature. Similarly, different cations can be used to introduce new chemical properties (acid-base, redox, etc.), which are needed for a given application in catalytic processes. 

In this chapter multiple-pulse sequences for homonudear Hartmann-Hahn transfer are discussed. After a summary of broadband Hartmann-Hahn mixing sequences for total correlation spectroscopy (TOCSY), variants of these experiments that are compensated for crossrelaxation (clean TOCSY) are reviewed. Then, selective and semiselective homonudear Hartmann-Hahn sequences for tailored correlation spectroscopy (TACSY) are discussed. In contrast to TOCSY experiments, where Hartmann-Hahn transfer is allowed between all spins that are part of a coupling network, coherence transfer in TACSY experiments is restricted to selected subsets of spins. Finally, exclusive TACSY (E.TACSY) mixing sequences that not only restrict coherence transfer to a subset of spins, but also leave the polarization state of a second subset of spins untouched, are reviewed. 

Challenges in real-time process optimization mainly arise from the inability to build and adapt accurate models for complex physico-chemical processes. This paper surveys different ways of using measurements to compensate for model uncertainty in the context of process optimization. A distinction is made between model-adaptation methods that use the measurements to update the parameters of the process model before repeating the optimization, modifier-adaptation methods that adapt constraint and gradient modifiers, and direct-input-adaptation methods that convert the optimization problem into a feedback control problem. This paper argues in favor of modifier-adaptation methods, since it uses a model parameterization, measurements, and an update criterion that are tailored to the tracking of the necessary conditions of optimality. 

To take away the mystery from the word supercritical, it should be recognized that a supercritical fluid can be used like any other solvent for maceration and percolation processes. The only restriction is that it must be handled under high pressure, a fact that requires a special and expensive design of the extraction apparatus. This obvious disadvantage however is compensated by many benefits as demonstrated below. Supercritical C02-extraction of botanical materials is today a well-developed and reliable procedure applied on an industrial scale for about 20 years. The equipment is available turn-key from various suppliers in multi-purpose design or tailor made for special applications. 

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