System pressure, effect

What Is the Point of Measuring System Pressure Effects A... 

High pressure systems Pressure effects Cooking, etc. 3... 

Trickle bed reaction of diol (12) using amine solvents (41) has been found effective for producing PDCHA, and heavy hydrocarbon codistiUation may be used to enhance diamine purification from contaminant monoamines (42). Continuous flow amination of the cycloaUphatic diol in a Hquid ammonia mixed feed gives >90% yields of cycloaUphatic diamine over reduced Co /Ni/Cu catalyst on phosphoric acid-treated alumina at 220°C with to yield a system pressure of 30 MPa (4350 psi) (43). 

The absolute pressure may have a significant effect on the vapor—Hquid equiHbrium. Generally, the lower the absolute pressure the more favorable the equiHbrium. This effect has been discussed for the styrene—ethylbenzene system (30). In a given column, increasing the pressure can increase the column capacity by increasing the capacity parameter (see eqs. 42 and 43). Selection of the economic pressure can be faciHtated by guidelines (89) that take into consideration the pressure effects on capacity and relative volatiHty. Low pressures are required for distillation involving heat-sensitive material. 

Effects of Total Pressure on Uq and The influence of total system pressure on the rate of mass transfer from a gas to a licniid or to a solid has been shown to be the same as would be predicted from stagnant-film theory as defined in Eq. (5-285), where... 

For the liquid-phase mass-transfer coefficient /cl, the effects of total system pressure can be ignored for all practical purposes. Thus, when using Kq and /cl for the design of gas absorbers or strippers, the primary pressure effects to consider will be those which affect the equilibrium curves and the values of m. If the pressure changes affect the hydrodynamics, then Icq, and a can all change significantly. 

Use of Psychrometric Charts at Pressures Other Than Atmospheric The psychrometric charts shown as Figs. 12-1 through 12-4 and the data of Table 12-1 are based on a system pressure of 1 atm (29.92 inHg). For other system pressures, these data must be corrected for the effect of pressure. Additive corrections to be apphed to the atmospheric values of absolute humidity and enthalpy are given in Table 12-2. 

The ambiguity of the total pressure effect can be seen by a comparison of the gas-phase- and liquid-phase-controlled cases when the gas phase controls, the liquid-phase resistance is negligible and Kg( = K npf is independent of the total pressure. For this case the coefficient K g< is inversely proportional to the total system pressure as shown in Eq. (14-66). On the other hand, when the liquid phase controls, the correct equation is... 

DEA is prefened when system pressure is above 500psi. The 0.25 grains/100 scf is more difficult to produce with DEA. COS and CS2 have few detrimental effects on DEA. This, and high solution loadings, provide advantages over MEA. DEA will typically be used for refinery and manufactured gas streams that have COS and 082. ... 

Testing should address the maximum operating temperature and pressure normally seen at the arrester location. This does not include certain pressure upsets (such as emergency shutdown) that produce unusually high system pressures. In many cases it may not be possible to design an arrester that will function effectively during upset conditions, and other protective measures should be considered (e.g., venting, suppression). 

As previously discussed, the charts of K values are available, but do apply primarily to hydrocarbon systems. Reference 79 presents important other data on K value relationships. See Figures 8 4A and 8-4B for charts with pressure effects included (not ideal, but practical charts). 

Because water will be present in this system, and is assumed immiscible with the other components, it will exert its own vapor pressure. This situation is similar to many systems where the liquid to be flashed enters below its dew point, and hence requires the use of steam to heat (sensible + latent) as well as steam for the partial pressure effect... 

Figure 11-19. Lithium bromide hermetic absorption refrigeration system, double effect, liquid chiller/heater. As shown in chilling mode, water is the refrigerant under low absolute pressure (boiling at 40°F) (Used by permission Cat. 521-606, form 16DF-1 PD, 1994. Carrier Corporation, a United Technologies Company.)...

Since the pressure generated by most fans is far in excess of pressure differences due to buoyancy and wind, the performance of a powered ventilation system is effectively independent of these, and flow rates and directions can be confidently predicted and will be constant regardless of conditions. The high-pressure generation also allows resistive components such as heater batteries, filters and attenuators to be used within the system. 

Pressure drops on the high-pressure side will be small enough to have little effect on the performance of the complete system. Pressure losses in the suction pipe and its fittings, especially if this is long, should be checked, and a correction made for the actual compressor suction pressure. For low-temperature applications, pipe sizes may have to be increased to avoid excessive frictional losses at these low pressures. 

Dr. Blum As a further comment on pressure optimization, and as it relates to our system, I think the response of the slurry methanation system to pressure is somewhat different from that of dry methanation. It relates to the ability of the catalyst to methanate a given amount of gas. In our system, the effective pressure is the total pressure minus the vapor pressure of the liquid phase. This doesn t hold for the standard methanation catalyst in the dry system. There is a different pressure relationship so the optimum just might not work quite the same way. 

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