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Synthesis of Poly e-caprolactone

Bailey WJ, Ni Z, Wu S-R (1982) Synthesis of poly-e-caprolactone via a free radical mechanism. Free radical ring opening polymerization of 2-methylene-l,3-dioxepane. J Polym Sci A Polym Chem 20 3021-3030... [Pg.208]

Fig. 63 Controlled synthesis of poly(e-caprolactone) grafted onto dextran via partially silylated dextran... Fig. 63 Controlled synthesis of poly(e-caprolactone) grafted onto dextran via partially silylated dextran...
Wyatt, M.F., Duxbury, C.J., Thurecht, K.J., and Howdle, S.M. (2006) One-Step Chemoenzymatic synthesis of poly(e-caprolactone-block-methyl methacrylate) in supercritical C02. Macromolecules, 39 (16), 5352-5358. [Pg.346]

Among these reactions, the Cu(l)-catalyzed azide-alkyne cycloaddition (CuAAC) is the most widely used. This reaction has been implemented for the preparation of segmented block copolymers from polymerizable monomers by different mechanisms. For example, Opsteen and van Hest [22] successfully prepared poly(ethylene oxide)-b-poly(methyl methacrylate) (PEO-b-PMMA) and PEO-b-PSt by using azide and alkyne end-functionalized homopolymers as the click reaction components (Scheme 11.2). Here, PEO, PSt, and PMMA homopolymers were obtained via living anionic ring-opening polymerization (AROP), atom transfer radical polymerization (ATRP), and postmodification reactions. Several research groups have demonstrated the combination of different polymerization techniques via CuAAC click chemistry, in the synthesis of poly(e-caprolactone)-b-poly(vinyl alcohol) (PCL-b-PVA)... [Pg.317]

Washington, DC, ACS, Div.of Polymer Chemistry, 2003,p.936-7, 28CM, 012 MICROWAVE-ASSISTED SYNTHESIS OF POLY(E-CAPROLACTONE) WITH ACID AS INITIATOR AND A NOVEL METHOD IN PREPARATION OF DRUG RELEASE SYSTEMS Song Y Liu L J Yu X C Zhuo R X Wuhan,University (ACS,Div.of Polymer Chemistry)... [Pg.51]

Rong, G., Deng, M., Deng, C. et al. (2003) Synthesis of poly(E-caprolactone)-b-Poly(Y-benzyl-l-glutamic acid) block copolymer using amino organic calcium catalyst. Biomacromolecules, 4,1800-1804. [Pg.644]

Scheme 11.2 Synthesis of poly-e-caprolactone by ROP. Terminal -H and -OH have been added. Scheme 11.2 Synthesis of poly-e-caprolactone by ROP. Terminal -H and -OH have been added.
Ydens I, Rutot D, Degee P, Six J-L, Dellacherie E, Dubois P. Controlled synthesis of poly(e-caprolactone)-grafted dextran copoly mers as potential environmentally friendly surfactants. Macromolecules 2000 33(18) 6713-21. [Pg.276]

Nottelet B, Coudane J, Vert M (2006) Synthesis of an X-ray opaque biodegradable copolyester by chemical modiflcation of poly(E-caprolactone). Biomaterials 27 4948 954... [Pg.213]

The ease of synthesis of oxepan-2-one (e-caprolactone 78) on a commercial scale has led to its use as a monomer in the production of poly-e-caprolactone. The latter polymer has been widely used as an additive and plasticizer. Over the last decade a large number... [Pg.589]

Martinez-Richa, A. Barrera-Rivera, K. A. Flores-Carreon, A. Synthesis and characterization of poly(e-caprolactone) obtained by enzymatic polymerization with Yarrowia lipolytica lipase ACS Polymer Preprints, 2006, 47(2), 277. [Pg.15]

Messersmith, P. B., Giannelis, E. R, Synthesis and barrier properties of poly(e-caprolactone)-layered silicate nanocomposites. loumal of Polymer Science Part A Polymer Chemistry. 7, 1047-1057 (1995), DOI 10.1002/pola.l995.080330707. [Pg.924]

Dubois, P., J6rdme, R., and Teyssi6, P., 1991, Macromolecular Engineering of Polylactones and Polylactides. 3. Synthesis, Characterizaion, and Application of Poly(e-caprolactone) Macromonomers. Macromolecules, 24 977... [Pg.192]

Synthesis scheme of poly(e-caprolactone-co-trimethylene carbonate-co-p-dioxanone) triblock copolymers. [Pg.308]

M. loubert, C. Delaite, E. Bourgeat-Lami, P. Dumas, Synthesis of poly(epsilon-caprolactone)-silica nanocomposites from hairy colloids to core-shell nanoparticles. New J. Chem. 2005, 29,1601-1609. [Pg.149]

Lorenzo AT, Muller AJ, Priftis D, Pitsikalis M, Hadjichristidis N. Synthesis and morphological characterization of miktoarm star copolymers (PCLijfPS) of poly(e-caprolactone) and polystyrene. J Polym Sci A Polym Chem 2007 45(23) 5387-739. [Pg.307]

Huet J M and MarSchal E (1974) S5mthesis and study of the polycondensate sequences comprising a sequence of poly(e-caprolactone) II. Synthesis and study of copolycondensate sequences comprising a poly(e-caprolactone) sequence and polyamide or polycarbonate sequences. An attempt to S5mthesize of copolycondensate sequences of poly(ethanediol terephthalate) and poly(e-caprolactone), Eur Polym J 10 771-782 (in French). [Pg.258]

See also PBT degradation structure and properties of, 44-46 synthesis of, 106, 191 Polycaprolactam (PCA), 530, 541 Poly(e-caprolactone) (CAPA, PCL), 28, 42, 86. See also PCL degradation OH-terminated, 98-99 Polycaprolactones, 213 Poly(carbo[dimethyl]silane)s, 450, 451 Polycarbonate glycols, 207 Polycarbonate-polysulfone block copolymer, 360 Polycarbonates, 213 chemical structure of, 5 Polycarbosilanes, 450-456 Poly(chlorocarbosilanes), 454 Polycondensations, 57, 100 Poly(l,4-cyclohexylenedimethylene terephthalate) (PCT), 25 Polydimethyl siloxanes, 4 Poly(dioxanone) (PDO), 27 Poly (4,4 -dipheny lpheny lpho sphine oxide) (PAPO), 347 Polydispersity, 57 Polydispersity index, 444 Poly(D-lactic acid) (PDLA), 41 Poly(DL-lactic acid) (PDLLA), 42 Polyester amides, 18 Polyester-based networks, 58-60 Polyester carbonates, 18 Polyester-ether block copolymers, 20 Polyester-ethers, 26... [Pg.595]

Ekin A, Webster DC (2006) Library synthesis and characterization of 3-aminopropyl-terminated poly(dimethylsiloxane)s and poly(e-caprolactone)-b-poly(dimethylsiloxane)s. J Polym Sci Part A Polym Chem 44 4880-4894... [Pg.14]

Ekin A, Webster DC. (2006) Synthesis and characterization of novel hydroxyalkyl carbamate and dihydroxyalkyl carbamate terminated poly(dimethylsiloxane) oligomers and their block copolymers with poly(e-caprolactone). Macromolecules 39 8659-8668... [Pg.14]

Guillaume SM, Schappacher M, Soum A (2003) Polymerization of e-caprolactone by Nd (BH4)3(THF)3 synthesis of hydroxytelechelic poly(e-caprolactone). Macromolecules 36 54-60... [Pg.210]

Li H, Riva R, Kricheldorf FIR, Jerome R, Lecomte P (2008) Synthesis of eight and starshaped poly(e-caprolactone)s and their amphiphilic derivatives. Chem Eur J 14 358-368... [Pg.216]

Hiskins JN, Grayson JM (2009) Synthesis and degradation behavior of cyclic poly(E-caprolactone). Macromolecules 42 6406—6413... [Pg.218]

Turunen MPK, Korhonen H, Tuominen J, Seppala JV (2001) Synthesis, characterization and crosslinking of functional star-shaped poly(E-caprolactone). Polym Int 51 92-100... [Pg.218]

Theiler S, Teske M, Keul H, Sternberg K, Moller M (2010) Synthesis, characterization and in vitro degradation of 3D-microstmctured poly(E-caprolactone) resins. Polym Chem 1 1215-1225... [Pg.218]

See other pages where Synthesis of Poly e-caprolactone is mentioned: [Pg.277]    [Pg.661]    [Pg.785]    [Pg.42]    [Pg.324]    [Pg.231]    [Pg.277]    [Pg.661]    [Pg.785]    [Pg.42]    [Pg.324]    [Pg.231]    [Pg.271]    [Pg.76]    [Pg.228]    [Pg.372]    [Pg.4]    [Pg.406]    [Pg.104]    [Pg.725]   


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Caprolactone

Caprolactones

E-Caprolactone

Of e-caprolactone

Poly-3-caprolactone

Poly-e-caprolactone

Synthesis!—es)

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