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Symmetry, cylindrical

Homogeneous liquid in a uniform spherical domain. The spherical displacement front associated with a point source is useful in studying invasion at the bit. The flow that would idealize Figure 17-3 possesses spherically symmetry. Cylindrical radial invasion away from the bit (around the drill pipe) is controlled by mudcake buildup. But at the bit, cake does not form, since it is... [Pg.309]

Let us consider the scheme showed in Fig. I to calculate the field scattered by a rough cylindrical surface (i.e. a wire). The wire is illuminated by a monochromatic, linearly polarized plane wave at an angle of incidence a with its axis of symmetry. The surface is described, in a system fixed to the wire, by p = h (cylindrical coordinates. We shall denote the incident wave vector lying on the x-z plane as kj and the emergent wave vector simply as k. [Pg.663]

Similar to the case without consideration of the GP effect, the nuclear probability densities of Ai and A2 symmetries have threefold symmetry, while each component of E symmetry has twofold symmetry with respect to the line defined by (3 = 0. However, the nuclear probability density for the lowest E state has a higher symmetry, being cylindrical with an empty core. This is easyly understand since there is no potential barrier for pseudorotation in the upper sheet. Thus, the nuclear wave function can move freely all the way around the conical intersection. Note that the nuclear probability density vanishes at the conical intersection in the single-surface calculations as first noted by Mead [76] and generally proved by Varandas and Xu [77]. The nuclear probability density of the lowest state of Aj (A2) locates at regions where the lower sheet of the potential energy surface has A2 (Ai) symmetry in 5s. Note also that the Ai levels are raised up, and the A2 levels lowered down, while the order of the E levels has been altered by consideration of the GP effect. Such behavior is similar to that encountered for the trough states [11]. [Pg.598]

In an axisymmetric flow regime all of the field variables remain constant in the circumferential direction around an axis of symmetry. Therefore the governing flow equations in axisymmetric systems can be analytically integrated with respect to this direction to reduce the model to a two-dimensional form. In order to illustrate this procedure we consider the three-dimensional continuity equation for an incompressible fluid written in a cylindrical (r, 9, 2) coordinate system as... [Pg.113]

Cone-Roof Tanks. Cone-roof tanks are cylindrical shells having a vertical axis of symmetry. The bottom is usually flat and the top made ia the form of a shallow cone. These are the most widely used tanks for storage of relatively large quantities of fluid because they are economic to build and the market supports a number of contractors capable of building them. They can be shop-fabricated ia small sizes but are most often field-erected. Cone-roof tanks typically have roof rafters and support columns except ia very small-diameter tanks when they are self-supporting (see Fig. 4b and c Table 3). [Pg.312]

Note that 0" < A< 60". The invariants A , and form a cylindrical coordinate system relative to the principal coordinates, with axial coordinate / A equally inclined to the principal coordinate axes, with radial coordinate /3t, and with angular coordinate The plane A" = 0 is called the II plane. Because the principal values can be ordered arbitrarily, the representation of A through its invariants in n plane coordinates has six-fold symmetry. [Pg.183]

Boundary conditions are special treatments used for internal and external boundaries. For example, the center line in cylindrical geometry is an internal boundary that is modeled as a plane of symmetry. External boundaries model the world outside the mesh. The outermost row of elements is often used to implement the boundary condition as shown in Fig. 9.13. The mass, stress, velocity, etc., of the boundary elements are defined by the boundary conditions rather than the governing equations. External boundary conditions are typically prescribed through user input. [Pg.336]

Of particular importance to carbon nanotube physics are the many possible symmetries or geometries that can be realized on a cylindrical surface in carbon nanotubes without the introduction of strain. For ID systems on a cylindrical surface, translational symmetry with a screw axis could affect the electronic structure and related properties. The exotic electronic properties of ID carbon nanotubes are seen to arise predominately from intralayer interactions, rather than from interlayer interactions between multilayers within a single carbon nanotube or between two different nanotubes. Since the symmetry of a single nanotube is essential for understanding the basic physics of carbon nanotubes, most of this article focuses on the symmetry properties of single layer nanotubes, with a brief discussion also provided for two-layer nanotubes and an ordered array of similar nanotubes. [Pg.27]

It is known that a metallic ID system is unstable against lattice distortion and turns into an insulator. In CNTs instabilities associated two kinds of distortions are possible, in-plane and out-of-plane distortions as shown in Fig. 8. The inplane or Kekuld distortion has the form that the hexagon network has alternating short and long bonds (-u and 2u, respectively) like in the classical benzene molecule [8,9,10]. Due to the distortion the first Brillouin zone reduees to one-third of the original one and both K and K points are folded onto the F point in a new Brillouin zone. For an out-of-plane distortion the sites A and B are displaced up and down ( 2) with respect to the cylindrical surface [11]. Because of a finite curvature of a CNT the mirror symmetry about its surface are broken and thus the energy of sites A and B shift in the opposite direction. [Pg.69]

The synthesis of molecular carbon structures in the form of C q and other fullerenes stimulated an intense interest in mesoscopic carbon structures. In this respect, the discovery of carbon nanotubes (CNTs) [1] in the deposit of an arc discharge was a major break through. In the early days, many theoretical efforts have focused on the electronic properties of these novel quasi-one-dimensional structures [2-5]. Like graphite, these mesoscopic systems are essentially sp2 bonded. However, the curvature and the cylindrical symmetry cause important modifications compared with planar graphite. [Pg.89]

The vessel under gas pressure bursts into equal fragments. If there are only two fragments and the vessel is cylindrical with hemispherical end-caps, the vessel bursts perpendicular to the axis of symmetry. If there are more than two fragments and the vessel is cylindrical, strip fragments are formed and expand radially about the axis of symmetry. (The end caps are ignored in this case.)... [Pg.228]

Fragments are equal in size and shape. For two fragments only, the cylindrical vessel bursts perpendicularly to the axis of symmetry. For more than two fragments, the cylindrical vessel bursts into strip fragments which expand radially about the axis of symmetry, and end caps are neglected. [Pg.318]

Figure 1.7 The cylindrical symmetry of the H-H ct bond in an H2 molecule. The intersection of a plane cutting through the (T bond is a circle. Figure 1.7 The cylindrical symmetry of the H-H ct bond in an H2 molecule. The intersection of a plane cutting through the (T bond is a circle.
We know from Section 1.5 that cr bonds are cylindrically symmetrical. In other words, the intersection of a plane cutting through a carbon-carbon singlebond orbital looks like a circle. Because of this cjdindrical symmetry rotation is possible around carbon-carbon bonds in open-chain molecules. In ethane, for instance, rotation around the C-C bond occurs freely, constantly changing the spatial relationships between the hydrogens on one carbon and those on the other (Figure 3.5),... [Pg.93]

The procedure for determining the six localized orbitals of a CII3 group (Fig. 9), is similar to that for determining the four localized orbitals of a CH2 group. This time the basic valence orbitals can be divided into three sets a orbitals with either cylindrical or pseudo-cylindrical symmetry about the x axis a ttv orbitals, which... [Pg.8]

The nAChR is cylindrical with a mean diameter of about 6.5 nm (Fig. 1). All five rod-shaped subunits span the membrane. The receptor protrades by <6 nm on the synaptic side of the membrane and by <2 nm on the cytosolic side [2]. The pore of the channel is along its symmetry axis and includes an extracellular entrance domain, a transmembrane domain and a cytosolic entrance domain. The diameter of the extracellular entrance domain is <2.5 nm and it becomes narrower at the transmembrane domain. The... [Pg.870]

Daoud and Cotton [10] pioneered this geometrical analysis of tethered layers with spherical symmetry, which was later extended by Zhulina et al. [36] and Wang et al. [37] to cylindrical layers. The subsequent analysis is purely geometrical and requires no free energy minimization. The tethered layer consists of a stratified array of blobs such that all blobs in a given sublayer are of equal size, E , but blobs in different layers differ in size. This corresponds to the uniform stretching assumption of the Alexander model. [Pg.41]

FIGURE 3.8 When electrons with opposite spins (depicted as t and 1) in two hydrogen 1s-orbitals pair and thes-orbitals overlap, they lorm a boundary surface of the electron cloud. The cloud has cylindrical symmetry around the internuclear axis and spreads over both nuclei. In the illustrations in this book, cr-bonds are usually colored blue... [Pg.230]

In the early discussions of hybrid orbitals4,5 it was pointed out that the maximum strength (the maximum value in the bond direction) of a bond orbital formed from completed subshells of orbitals is associated with cylindrical symmetry of the orbital. In order to simplify the analysis of spd hybridization Hultgren5 decided to discuss only orbitals with cylindrical symmetry. He pointed out that no more than three d orbitals with cylindrical symmetry can be formed in a set of five d orbitals, and that each of these three is equivalent to the function d2 (see Table 1), except in orientation. [Pg.239]

It is seen that the maximum bond strength for set I (Powell s second set) is greater than that for set II (Powell s first set), and also that there is for each of the two kinds of functions great deviation from cylindrical symmetry. The values of the functions in the planes of symmetry are shown in Figures 2 and 3. Comparison with the corresponding cross sections for d2 and d,2-.2 shows that the functions I are qualitatively similar to d 2, and the functions II are more similar to dx2-t2. The values for the two functions are indicated in Figure 1. [Pg.240]

At that time I was handicapped by my remembering a misinterpretation that I had made of some results obtained in 1932 by one of my students, Ralph Hultgren (6). He had begun to make a thorough study of sets of equivalent spd hybrid bond orbitals, and soon found that he could not handle the computational problem in those precomputer days. I pointed out that the best hybrid orbitals have cylindrical symmetry about... [Pg.397]


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See also in sourсe #XX -- [ Pg.299 ]

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