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Surface pretreatments affected

In summary, the removal of organic matter and Fe oxides significantly changes the physicochemical and surface chemical properties of soils. Thus, this pretreatment affects the overall reactivity of heavy metals in soils. The removal of organic matter and Fe oxides may either increase or decrease heavy metal adsorption. The mechanisms responsible for the changes in metal adsorption in soils with the removal of organic matter and Fe oxides include increases in pH, surface area, CEC and electrostatic attraction, decreases in the ZPC, shifts of positive zeta potentials toward... [Pg.144]

As indicated above, Mason et al. [13] found that the pretreatment affected the surface acidity of Ti-6,4. They found that surfaces treated with a basic etchant had an isoelectric point between 7.3 and 9.2. A phosphate-fluoride etch left the surface acidic with an isoelectric point between 5.4 and 7.3. As noted above, Finlayson and Shah [12] also found that the pretreatment affected the acidity of oxidized aluminum surfaces. [Pg.260]

In a great variety of solid supports, the number and nature of the surface reactive groups drastically affect the distribution and local organization of the adsorbates. The adsorbent pretreatment and handling, or the solvent used for probe deposition, strongly influence the surface and, as a consequence, the molecule s adsorption. Therefore, their photochemistry and/or photophysics vary according to the surface pretreatment. [Pg.294]

With plasma treatment, surface wettability can be readily induced on a variety of normally non-wettable materials as shown in Table P. 5. Certain polymeric surfaces, such as the polyolefins, become crosslinked during plasma treatment. The surface skin of polyethylene, for example, will become crosslinked so that if the polymer were placed on a hot plate of sufficient heat, the interior would turn to a molten liquid while the crosslinked outer skin held a solid shape. Other polymers have their critical surface energy affected in different ways. Plasma-treated polymers usually form adhesive bonds that are two to four times the strength of nontreated polymers. Table P.5 presents bond strength of various plastic adherends pretreated with activated gas and bonded with an epoxy or urethane adhesives. [Pg.405]

Zhang, Z., Ma, H., Hausner, D.B., Chilkoti, A., Beebe, J.T.P. (2005) Pretreatment of amphiphihc comb polymer surfaces dramatically affects protein adsorption. Biomacromolecules, 6, 3388-3396. [Pg.1011]

In recent years, efforts have been directed to develop surface pretreatment methods on PHAs for the introduction of polar groups without affecting their bulk properties. Among them, ozone, plasma, and alkali treatments are often used to modify the PHA surfaces. [Pg.152]

For the investigation of the effect of surface pretreatment, two different mild steel samples were prepared, and their O Is and Fe 2p3/2 XPS spectra were measured prior to the inhibitor adsorption procedure. The dependence of the adsorption procedure on sample pretreatment, i.e., how the chemical state (the oxide content) of the iron surface affects the adsorption of the inhibitor can be followed in Figs. 9-37 to 9-40. [Pg.521]

A. J. Kinloch (JiivuJ>i/iy 0 VQ. Q.n62, U. K.) It has been suggested that the type of oxide on the titanium alloy surface, for example whether it is rutile or anatase, can affect the water resistance of the subsequently made joint. Did you conduct any experiments, for example x-ray diffraction analysis, to identify the structural type of titanium oxide formed by your Pasa-Jell surface pretreatment ... [Pg.436]

To demonstrate the T-stress effect and to understand other factors affecting crack path selection, the authors and their coworkers [13,25,31,32] carried out a series of experimental studies with adhesively bonded joints to determine the effects of T-stress, specimen geometry, external loading conditions, surface pretreatment. [Pg.396]

Thus, in many applications, which may involve some of the most critical uses of adhesives technology, the bonded joints are exposed to an environment which also happens to be one of the most potentially damaging. Indeed, the aspect of the durability of adhesive joints to aqueous environments is undoubtedly one of the most important challenges that the adhesives community faces. In particular, there are two main challenges to develop (a) adhesive systems (i.e. combinations of an adhesive/primer/surface pretreatment/substrate type, all of which may interact to affect the joint durability) which possess excellent long-term durability, and which are environmentally friendly and cost effective and (b) test methods and models to accurately rank and predict the service-life from short-term experiments, and thereby convince the potential user that an adequate durability will be realised. Clearly, these two aims are strongly inter-linked. [Pg.661]

Absorbed moisture in certain substrates, e.g. fibre composites, may also adversely affect the performance of the adhesive joint, but these aspects are best considered in Section 4.2.5 when surface pretreatments for such materials are reviewed. [Pg.50]

Cmde products from organic-based processes contain organic impurities which affect color, odor, surface tension, and stabiUty, and ate normally pretreated to reduce the carbon content before final purification and concentration by various distillation methods. [Pg.478]

Zinc phosphate is now probably the most important pigment in anticorrosive paints. The selection of the correct binder for use with these pigments is very important and can dramatically affect their performance. Red lead is likely to accelerate the corrosion of non-ferrous metals, but calcium plumbate is unique in providing adhesion to newly galvanised surfaces in the absence of pretreatment, and is claimed to behave similarly on other metals in this group. [Pg.586]

The pretreated metalwork to be coated is heated in an oven to a temperature of between 260 and 360°C, depending on the metal thicknesses and the coating to be applied. It is then withdrawn from the oven and dipped into the fluidised powder. Here the fine powder particles are blown onto the hot metal where they melt. After a few seconds (5-lOs is normal), the item is removed from the powder and the unfused outer particles are allowed to fuse. Then either the item is allowed to air cool or it is water quenched. The cooling method can affect crystal structure and hence surface finish and... [Pg.747]

The effect of oxidation pretreatment and oxidative reaction on the graphitic structure of all CNF or CNF based catalysts has been studied by XRD and HRTEM. From the diffraction patterns as shown in Fig. 2(a), it can be observed the subsequent treatment do not affect the integrity of graphite-like structure. TEM examination on the tested K(0.5)-Fe(5)/CNF catalysts as presented in Fig.2(b), also indicates that the graphitic structure of CNF is still intact. The XRD and TEM results are in agreement with TGA profiles of fi-esh and tested catalyst there is no obviously different stability in the carbon dioxide atmosphere (profiles are not shown). Moreover, TEM image as shown in Fig. 2(b) indicates that the iron oxide particle deposited on the surface of carbon nanofibcr are mostly less than less than 10 nm. [Pg.743]


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