Surface chemical properties of oxides

Hohl, H., L. Sigg, and W. Stumm (1980), "Characterization of Surface Chemical Properties of Oxides in Natural Waters The Role of Specific Adsorption Determining the Specific Charge," in M. C. Kavanaugh and J. O. Leckie, Eds., Particulates in Water, Advances in Chemistry Series, ACS 189, 1-31. 

Characterization of Surface Chemical Properties of Oxides in Natural Waters... 

Traditional adsorbents such as sihca [7631 -86-9] Si02 activated alumina [1318-23-6] AI2O2 and activated carbon [7440-44-0], C, exhibit large surface areas and micropore volumes. The surface chemical properties of these adsorbents make them potentially useful for separations by molecular class. However, the micropore size distribution is fairly broad for these materials (45). This characteristic makes them unsuitable for use in separations in which steric hindrance can potentially be exploited (see Aluminum compounds, aluminum oxide (ALUMINA) Silicon compounds, synthetic inorganic silicates). 

The chemical properties of oxide surfaces have been studied by several methods, including oxygen exchange. This method has been used to investigate the mechanisms of heterogeneous reactions for which oxides are active catalysts [36]. The dimerization step does not necessarily precede desorption and Malinin and Tolmachev [634], in one of the few reviews of decomposition kinetics of solid metal oxides, use this criterion to distinguish two alternative reaction mechanisms, examples being... 

In addition, the removal of organic matter and Fe oxides from soils and sediments is common practice as a pretreatment for soils prior to physical, chemical and biological analyses. The effects of the removal of these components on physicochemical and surface chemical properties of soils will be discussed as well. 

In summary, the removal of organic matter and Fe oxides significantly changes the physicochemical and surface chemical properties of soils. Thus, this pretreatment affects the overall reactivity of heavy metals in soils. The removal of organic matter and Fe oxides may either increase or decrease heavy metal adsorption. The mechanisms responsible for the changes in metal adsorption in soils with the removal of organic matter and Fe oxides include increases in pH, surface area, CEC and electrostatic attraction, decreases in the ZPC, shifts of positive zeta potentials toward... 

Simple Models. The surface chemical properties of clay minerals may often be interpreted in terms of the surface chemistry of the structural components, that is, sheets of tetrahedral silica, octahedral aluminum oxide (gibbsite) or magnesium hydroxide (brucite). In the discrete site model, the cation exchange framework, held together by lattice or interlayer attraction forces, exposes fixed charges as anionic sites. 

Baun, W. L., et al. Pitting Corrosion and Surface Chemical Properties of a Thin Oxide Layer on Anodized Aluminum, in Air Force Materials Laboratory Technical Report 78-128, September... 

Reduction-oxidation episodes in soils cause appreciable redistribution of elements as some minerals dissolve and new minerals precipitate. It is unlikely that the surface chemical properties of the soil are preserved through the reduction and oxidation processes. In particular, freshly precipitated Fe and Mn oxides seem to provide recently reoxidized soils with new reactive surfaces for heavy metal and oiganic sorption. 

Using pitch-based ACFs, Mochida et al. [132] reported 87% conversion at room temperatnre in dry air. Lower conversions were obtained in the presence of water vapor. The anthors found that heat treatment at 1123 K enhanced the activity of the fibers. Such treatment removes oxygen functional groups from the surface of the ACFs the vacant sites created as a result of this treatment were thought to be the active sites for the reaction. On the other hand, the hydrophobic surface obtained after the heat treatment helps to decrease the amount of water adsorbed, which decreases NO conversion in humid air. An interesting point noted by Mochida et al. [131] is that PAN- and pitch-based ACFs exhibited the reverse order of activity for the oxidation of SO2 and NO. Thus, pitch fibers were best for NO oxidation, while PAN fibers were found to be more active for SO2 oxidation. No explanation was provided by the authors for this finding, which certainly reflects the different surface chemical properties of the two fiber types. A detailed kinetic study of this process was presented in a subsequent paper [133], while Guo et al. [134] compared the performances of different carbon fibers (PAN, pitch) and activated carbons. 

The surface chemical properties of the oxide surface are sensitive to the composition of the aqueous phase because adsorption or binding of solutes to the surface may increase, decrease, or reverse the effective surface charge on the solid (IS). One speaks of specific chemical interactions if binding mechanisms other than electrostatic interactions are significantly involved in the adsorption process. 

Surface Chemical Properties of the Higher Rare Earth Oxides... 

All three effects strongly depend on the oxide surface structure, in particular on the type and density of surface defects. Data on the structural and chemical properties of oxide-liquid interfaces are considerably less detailed and usually are obtained on oxides without defined surface structure. In aqueous solutions, the oxide surface is usually terminated by hydroxyl groups... 

The corrosion behavior of tantalum is weU-documented (46). Technically, the excellent corrosion resistance of the metal reflects the chemical properties of the thermal oxide always present on the surface of the metal. This very adherent oxide layer makes tantalum one of the most corrosion-resistant metals to many chemicals at temperatures below 150°C. Tantalum is not attacked by most mineral acids, including aqua regia, perchloric acid, nitric acid, and concentrated sulfuric acid below 175°C. Tantalum is inert to most organic compounds organic acids, alcohols, ketones, esters, and phenols do not attack tantalum. 

---