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Structural characteristics for

Sodium reduction development directions, 336 diluted melts, 331-332 of K-Salt, 327-328 principals, 326 Solid-phase interaction mechanism, 34-37 niobium oxyfluorides, 26-31 tantalum oxyfluorides, 32-34 Solubility diagrams (NH4)5Nb3OF18, 22 K2NbF7 in HF solutions, 14 K2TaF7 in HF solutions, 14 RbsNbjOF,, 22-23 Solubility of peroxides, 307 Specific conductivity, 153, 164 Spontaneous polarization, 223 Structural characteristics for X Me=8, 61,... [Pg.388]

This task represents a continuation of efforts to maximize the hydrophobicity of acrylic, epoxy, and other polymeric systems for resistance to water penetration and environmental degradation, and to minimize the dielectric constant and improve the processability for adhesives and coatings, without compromising the necessary structural characteristics for materials used for, e.g., structural elements, liners, paints, and microelectronic devices. [Pg.182]

The X-ray powder diffraction patterns of the parent materials showed the hexagonal structure characteristic for MCM-41 and SBA-15, and the cubic structure for MCM-48, respectively. All the patterns matched well with the reported patterns, confirming the successful synthesis of the mesoporous molecular sieves. The intensity of the reflection did not change essentially upon loading the carrier with the organometallic complexes, nor after a catalytic cycle, showing that the mesoporous structures were not affected by incorporation of the catalyst. [Pg.280]

The second group involves polymers with three-dimensional ordering of side branches (e.g., those forming Mj-phaseXTable 5). On X-ray patterns of these polymers 3-4 narrow reflexes at wide angles are observed. As a rule, the authors define this type of structure as crystalline, or ascribe a smectic type of structure, characteristic for ordered smectics in SE or SH phases. The heats of transition from anisotropic state to isotropic melt are usually small and do not exceed the heats of transition smectic liquid crystal — isotropic melt . The similarity of structural parameters of three-dimensionally ordered smectics and that of crystalline polymers of the type here considered, make their correct identification quite a difficult task. [Pg.196]

Table 1 Summary of structural characteristics for materials of the oxomolybdate-phosphonate-Cu(II)-organoimine family. [Pg.267]

A quantitative measurement of the depth of penetration of the diffracted electrons has been made previously by the author (1) by depositing silver vapor onto a gold crystal surface, using a calibrated silver source. Since the lattice structures are the same and the lattice constants differ by less than 0.4%, the silver was found to deposit as a thin crystal on the gold surface. Because of the different indices of refraction and certain fine-structure characteristics for the two metals, the diffraction beams from silver and gold were readily distinguished. [Pg.23]

Structural characteristics for a series of hydroxides are shown in Table 2.3 [15]. [Pg.19]

LiVMoOe was successfully synthesized using the conventional solid-state reaction method, and its chemical and physical properties were examined by several analytical methods. We have shown that LiVMoOe does not possess good structural characteristics for a lithium half cell (Li/LiVMoOe) as a cathode in non-aqueous electrolyte environment. Furthermore, we suggest that LiVMoOe may instead be considered as an anode material of choice for developing rechargeable lithium-ion battery technology. [Pg.84]

As mentioned above, the three-dimensional structure of a considerable number of these compounds has been established mainly by X-ray crystallography. The main structural characteristics for sepulchrate and sarcophaginate complexes as well as for free ligands are listed in Tables 2 and 3. [Pg.139]

The use of primary fragment ions is not enough to allow for extensive structural characterization. Careful examination, however, of the secondary fragmentation pathways provides a more precise means to identify some, but not all, of the structural characteristics for the substance under study. Aspinall (82MI7) reviewed a useful example in which the permethylated alditols from the milk oligosaccharides lacto-N-tetraose [Gai- (1 3)-Glc- l 3)-Gal-... [Pg.349]

Surface induced spinodal decomposition leads, for properly controlled surface fields, to a two layer structure characteristic for coexisting phases. Hence it may be used to determine the coexisting conditions in a more convenient way that with the interfacial relaxation method as the initial bilayer geometry may be avoided. In practical terms the overall composition of the whole thin film may be much better controlled in experiments involving spinodal decomposition. Therefore in experiments studying the equilibrium composition vs depth pro-... [Pg.21]

As observed with receptors, enzymatic systems can be snbdivided into enzyme families, and each enzymatic type presents several isoforms. Thns, for pharmacological and therapeutic purposes, it may be of interest to combine in a same molecule structural characteristics for inhibition of two different isoenzymes, two enzymes belonging to the same family, or two enzymes for which inhibitors are showing pharmacophore similarities. [Pg.394]

Sato, T., Gariepy, J., Lane, A., Frayman, F., Wilbur, D., Robien, W., Schoolnik, G. K., and Jardetzky, O. Structural characteristics for biological activity of heat-stable enterotoxin ST I, Biochemistry, 25, 7854,1986. [Pg.37]

Seebach et al. reported the synthesis of fi- and y-peptides with stable secondary structures [58] and, independently, Hanessian et al. reported the synthesis of y-pep-tides that adopt helical structures in solution [59]. These combined studies showed important structural characteristics for fi- and y-peptides in contrast with a-peptides. For example, a-peptides adopt helical conformations stabilized by a 13-membered hydrogen bond between the carbonyl of the amino terminus and the amide NH of the fomth residue toward the C-terminus (3.6 residues per turn). )8-Peptides formed... [Pg.519]

It is interesting to compare the dependence of the strength of interfacial layer on its structural characteristics for the polymer-polymer and polymer-high-modulus filler. For the first type of systems with increasing Ij there is observed the growth of adhesion [17]. [Pg.362]

We carried out comparative studies of the effect of the porous structure of carbon materials on electrochemical electrode characteristics using various carbide carbons (CCs). Main structural characteristics for CCs based on silicon carbide are presented in Table 27.3 and those for titanium carbide are in Table 27.4. Specific surface areas were calculated on the basis of the nitrogen adsorption data with calculation using the DFT technique. This method is used to measure micropores and mesopores, but not macropores. [Pg.291]

TABLE 27.3. Main Structural Characteristics for CCs Based on Silicon Carbide... [Pg.291]

Now it is possible to calculate value using the reaction rate constants k, obtained according to the described above experimental methods as function of t or Q. The calculation has shown the principal distinction of behavior D, which is the microgels structure characteristic, for the systems 2DPP+HCE/DDM and EPS-4/DDM. For the first from the indicated systems the value D. does not depend on t at the initial part of the curve but is the function of Tcur. So, at T = 353 and 373 KD, 1.5, atT = 393 D. 1.7andatT = 513 KD, 2.3. It means... [Pg.234]

Figure 8.4 Chain penetration structure, characteristic for lipids with large polar head-groups such as psychosine hydrochloride (Abrahamsson etal., 1972). [Pg.322]

Define an appropriate and consistent set of structural characteristics for operational best practice (process choice). [Pg.170]

In this section, the structural model for paper-type GDLs is compared with real 3D data gained by means of synchrotron tomography [23, 24]. This comparison is based on the above-described structural characteristics for porous media and can be seen as a model validation. In particular, characteristics are applied which are related to transport properties of the pore phase, since the investigation of transport processes is the main area of application of the multi-layer model see also the results and discussions in Thiedmann et al. [5]. [Pg.696]

The constant compositions of ternary compounds and the absence of solid solutions on the basis of binary compounds are other characteristic features of scandiiun systems (with the exception of the systems Sc-M-Ga with M = rare earth or 4A element). However, in some systems solid solutions of phases with narrow homogeneity regions occur. Sometimes a substitution of Sc and M atoms occurs and sometimes the M and the X atoms are mutually substituted. There is no doubt that the atomic size factor has a dominating influence on the formation of solid solutions and their nature (solid solutions of substitution, of inclusion or of subtraction of atoms). Examples of solid solutions of substitution are presented in table 31. It is interesting to note that all ternary compounds which form such solid solutions crystallize in structures characteristic for binary compoimds. [Pg.479]


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