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Stabilizer various

Indeed, these reactions proceed at 25 °C in ethanol-aqueous media in the absence of transition metal catalysts. The ease with which P-H bonds in primary phosphines can be converted to P-C bonds, as shown in Schemes 9 and 10, demonstrates the importance of primary phosphines in the design and development of novel organophosphorus compounds. In particular, functionalized hydroxymethyl phosphines have become ubiquitous in the development of water-soluble transition metal/organometallic compounds for potential applications in biphasic aqueous-organic catalysis and also in transition metal based pharmaceutical development [53-62]. Extensive investigations on the coordination chemistry of hydroxymethyl phosphines have demonstrated unique stereospe-cific and kinetic propensity of this class of water-soluble phosphines [53-62]. Representative examples outlined in Fig. 4, depict bidentate and multidentate coordination modes and the unique kinetic propensity to stabilize various oxidation states of metal centers, such as Re( V), Rh(III), Pt(II) and Au(I), in aqueous media [53 - 62]. Therefore, the importance of functionalized primary phosphines in the development of multidentate water-soluble phosphines cannot be overemphasized. [Pg.133]

In the following we shall briefly review some of the recent applications of computational quantum chemistry to zeolites, in particular, some studies on the quantum chemical origin of Loewenstein s aluminum avoidance rule, and on the role of counter ions in stabilizing various structural units in zeolite lattices. These calculations are often extremely time consuming, nevertheless, the scope of their application is continuously expanding. [Pg.147]

The ferrous complex of octaethyl porphyrin in SDS micelles has been characterized as four coordinated (S = 1) ferrous heme species and is similar to that observed for the ferrous protoheme complex in CTAB. It is noted that ferrous complexes of natural porphyrins cannot be stabilized in aqueous SDS micelles, and much larger aqueous micelles like CTAB were needed to stabilize various ferrous protohemes. This indicates that the environment around the octaethyl porphyrin complex in aqueous SDS is more hydrophobic than that of the analogous natural heme species, suggesting that the OEP moiety is embedded much deeper inside the micellar hydrophobic cavity than the protoporphyrin analogue. [Pg.136]

Various amino acids are also used as stabilizing agents for some biopharmaceutical products (Table 3.24). Glycine is most often employed and it (as well as other amino acids) has been found to help stabilize various interferon preparations, as well as erythropoietin, factor VIII,... [Pg.151]

Alcohol oxidase could be immobilized onto DEAE-sepharose (Pharmacia) and had very high stability even when dried and rehydrated. We therefore tried to stabilize alcohol oxidize on a solid surface and as free enzyme using DEAE dextran. However this was not successful (Fig. 5). We also knew that lactitol had been used in stabilizing various antibodies during the manufacture of antibody based tests, however lactitol also had poor stabilizing properties when dried with alcohol oxidase (Fig 5). Unexpectedly, however, we found that a combination of DEAE dextran and lactitol gave excellent stabilization of die enzyme (Fig 5.). Further experiments showed that the combination of stabilizers was generic and would be used to stabilize broad selection of enzymes (Table 1 and see ref. 17). [Pg.52]

PRINCIPLES OF METEOROLOGICAL ANALYSIS, Walter J. Saucier. Highly respected, abundantly illustrated classic reviews atmospheric variables, hydrostatics, static stability, various analyses (scalar, cross-section, isobaric, isentropic, more). For intermediate meteorology students. 454pp. 6X 9X. 65979-8 Pa. 12.95... [Pg.116]

The Biodiesel Stability (BIOSTAB) project, supported by the European Commission, was initiated in 2001 to establish clear criteria and analytical methods for the monitoring biodiesel fuel stability (Various, 2003 Prankl, 2002). The resulting unified method, EN 14112 (Anon., 2003c) established a means for measuring oxidative stability utilizing the Rancimat or oxidation stability instruments. This test method was essentially developed from standards employed in the fats and oils industry to measure isothermally the induction period for oxidation of fatty derivatives. At present, both biodiesel fuel standards ASTM D 6751 (Anon., 2007a) and EN 14214 (Anon., 2003b) include an oxidative stability specification based on measurement by method EN 14112. [Pg.29]

Table 2 Some of the buffer systems used to stabilize various parenteral products... Table 2 Some of the buffer systems used to stabilize various parenteral products...
Stability Various Perform preliminary tests on parent drug substance and on appropriate salts... [Pg.756]

Table 8 Critical cation environments to anion radius ratios for stability various coordination... Table 8 Critical cation environments to anion radius ratios for stability various coordination...
RNA molecules regulate their own metabolism. A number of structural features of RNA are known to influence stability, various processing events, subcellular distribution, and transport. It is likely that, as RNA intermediary metabolism is better understood, many other regulatory features and mechanisms will be identified. [Pg.125]

CIrown ethers and their relatives have proved so interesting to the chemical community in part because of their ability to complex and stabilize various cations. In the process, these compounds may alter the properties of associated anions. Nowhere has this anion effect been more exploited than in phase-transfer catalysis (1-3). [Pg.430]

Let us now give examples illustrating the use of surfactants for the purpose of stabilizing various disperse systems of complex nature, namely let us discuss detergency [75] andmicroencapsulation[76] (preparation of protective coating at the surface of various substances). [Pg.636]

Other modifications in color compounds lead to intensification and stabilization. Various polymerized pigments are formed and the balance shifts... [Pg.400]


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See also in sourсe #XX -- [ Pg.157 , Pg.161 ]




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Relative Stabilities of the Various Forms

Summary of Carbocation Stabilization in Various Reactions

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