Stability carbides

Vanadium is added to steel for high resistance to oxidation and to stabilize carbide. Vanadium foil is used for cladding titanium to steel. Vanadium-gallium alloy is used in making superconductive magnets. An important compound of vanadium is pentoxide which has many commercial uses (See Vanadium Pentoxide). 

Chromium is a refractory metal having a melting point of 3375°F (1857°C). Neither chromium metal nor chromium-based alloys are widely in the hydrocarbon or chemical industries. Chromium plating is useful for aesthetic purposes, and hard chromium plating finds some use in hardface applications. It is extensively used as an alloy addition to low-alloy steels (usually for the purpose of stabilizing carbides) and in cast irons (to produce wear-resistant products) and nickel alloys (for increased corrosion resistance). Chromium is the main alloying addition in the 400-series stainless steels and is used extensively in the 200- and 300-series stainless steels. 

Knife-line attack, immediately adjacent to the weld metal, is a special form of sensitization in stabilized austenitic stainless steels. Stabilizing elements (notably Ti and Nb) are added to stainless steels to prevent intergranular corrosion by restricting the formation of Cr-rich grain boundary precipitates. Basically, these elements form carbides in preference to Cr in the austenitic alloys. However, at the high temperatures experienced immediately adjacent to the weld fusion zone, the stabilizer carbides dissolve and remain in solution during the subsequent rapid... 

Silicon. Silicon is typically present only in minor amounts in most nickel-base alloys. In alloys containing significant amounts of iron, cobalt, molybdenum, tungsten, or other refractory elements, the level of silicon must be carefully controlled because it can stabilize carbides and harmful intermetallic phases. However, the use of silicon as a major alloying element has been found to greatly improve the... 

Vanadium is used in producing rust resistant and high speed tools steels. It is an important carbide stabilizer in making steels. 

Carbon content is usually about 0.15% but may be higher in bolting steels and hot-work die steels. Molybdenum content is usually between 0.5 and 1.5% it increases creep—mpture strength and prevents temper embrittlement at the higher chromium contents. In the modified steels, siUcon is added to improve oxidation resistance, titanium and vanadium to stabilize the carbides to higher temperatures, and nickel to reduce notch sensitivity. Most of the chromium—molybdenum steels are used in the aimealed or in the normalized and tempered condition some of the modified grades have better properties in the quench and tempered condition. 

AISI 321 and 347 are stainless steels that contain titanium and niobium iu order to stabilize the carbides (qv). These metals prevent iatergranular precipitation of carbides during service above 480°C, which can otherwise render the stainless steels susceptible to iatergranular corrosion. Grades such as AISI 316 and 317 contain 2—4% of molybdenum, which iacreases their creep—mpture strength appreciably. In the AISI 200 series, chromium—manganese austenitic stainless steels the nickel content is reduced iu comparison to the AISI 300 series. 

HTS catalyst consists mainly of magnetite crystals stabilized using chromium oxide. Phosphoms, arsenic, and sulfur are poisons to the catalyst. Low reformer steam to carbon ratios give rise to conditions favoring the formation of iron carbides which catalyze the synthesis of hydrocarbons by the Fisher-Tropsch reaction. Modified iron and iron-free HTS catalysts have been developed to avoid these problems (49,50) and allow operation at steam to carbon ratios as low as 2.7. Kinetic and equiUbrium data for the water gas shift reaction are available in reference 51. 

Antimony may be added to copper-base alloys such as naval brass. Admiralty Metal, and leaded Muntz metal in amounts of 0.02—0.10% to prevent dezincification. Additions of antimony to ductile iron in an amount of 50 ppm, preferably with some cerium, can make the graphite fliUy nodular to the center of thick castings and when added to gray cast iron in the amount of 0.05%, antimony acts as a powerflil carbide stabilizer with an improvement in both the wear resistance and thermal cycling properties (26) (see Carbides). 

Ceramics (qv) such as those in Table 12 find high temperature use to over 800°C (32). Advanced ceramics finding interest include alumina, partially stabilized zitconia, siUcon nitride, boron nitride, siUcon carbide, boron carbide, titanium diboride, titanium carbide, and sialon (Si—Al—O—N) (33) (see... 

Specify stabilized grades of stainless steel. An alternative method to prevent chromium carbide formation is to charge the alloy with substances whose affinity for carbon is greater than that of chromium. These substances will react preferentially with the carbon, preventing chromium carbide formation and thereby leaving the chromium uniformly distributed in the metal. The carbon content of the alloy does not have to be reduced if sufficient quantities of these stabilizing elements are present. Titanium is used to produce one stabilized alloy (321) and niobium is used to provide another (347). Note the cautions below. 

Figure 3.2 Chemical potential diagrams for the transport of silicon carbide by chlorine, showing that the much greater stability of SiCU than CCI4 makes this process very inefficient, while the use of HCl as the transporting gas can be operated under optimum conditions...

The expected oxidation mechanisms of carbides and silicides can be analysed from a thermodynamic viewpoint by a comparison of the relative stabilities... 

The first observation of sensitivity-stability was reported by Liljenroth (1918) in connection with the autothermal operation of ammonia oxidation reactors. Papers of Damkdhler (1937) and Wagner (1945) went unnoticed. At Union Carbide Corp. Perkins (1938) used zero order kinetics to define a safe range for ethylene oxidation in an unpublished report. His result,... 

Poor Weldability a. Underbead cracking, high hardness in heat-affected zone. b. Sensitization of nonstabilized austenitic stainless steels. a. Any welded structure. b. Same a. Steel with high carbon equivalents (3), sufficiently high alloy contents. b. Nonstabilized austenitic steels are subject to sensitization. a. High carbon equivalents (3), alloy contents, segregations of carbon and alloys. b. Precipitation of chromium carbides in grain boundaries and depletion of Cr in adjacent areas. a. Use steels with acceptable carbon equivalents (3) preheat and postheat when necessary stress relieve the unit b. Use stabilized austenitic or ELC stainless steels. 

Carbide 800/1600°F Low impact vaiues Pipe and piping Austenitic stainless Precipitation of Use stabilized or... 

The heavier alkaline earth metals Ca, Sr, Ba (and Ra) react even more readily with non-metals, and again the direct formation of nitrides M3N2 is notable. Other products are similar though the hydrides are more stable (p. 65) and the carbides less stable than for Be and Mg. There is also a tendency, previously noted for the alkali metals (p. 84), to form peroxides MO2 of increasing stability in addition to the normal oxides MO. Calcium, Sr and Ba dissolve in liquid NH3 to give deep blue-black solutions from which lustrous, coppery, ammoniates M(NH3)g can be recovered on evaporation these ammoniates gradually decompose to the corresponding amides, especially in the presence of catalysts ... 

The C-C distance in CaC2 is close to that in ethyne (120.5 pm) and it has been suggested that the observed increase in the lanthanoid and actin-oid carbides results from a partial localization of the supernumerary electron in the antibonding orbital of the ethynide ion [C=C] (see p. 932). The effect is noticeably less in the sesquicarbides than in the dicarbides. The compounds EuC2 and YbC2 differ in their lattice parameters and hydrolysis behaviour from the other LnC2 and this may be related to the relative stability of Eu and Yb (p. 1237). 

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