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Some other alcohols

There are many other commercial alcohols besides methanol. This chapter treats the ones traded in the largest volumes ethyl alcohol, isopropyl alcohol (IPA), normal butyl alcohol (NBA), 2-ethyl hexanol (2-EH) and li4-butanediol (BDO). [Pg.191]

By the way, when there is more than one hydroxyl group per molecule, it is still an alcohol. Ethylene glycol [Pg.192]

Like Caesars Gaul, most petrochemical processes used for manufacturing alcohols today est divida in tres partes. [Pg.193]

Oxo reaction. Reacting an olefin with synthesis gas (CO and H2) to produce an aldehyde (called hydroformylation) followed by hydrogenation (addition of hydrogen), producing an alcohol containing one more carbon than the original olefin. [Pg.193]

A1(C2H5)3 + CH7 = CH2 Trialkyl aluminum Triethyl aluminum Ethylene (A polymer chain) [Pg.193]


The Oxo process, a.k.a. the hydroformylation reaction, is the same as that described in Chapter l4, Some Other Alcohols, in the section on NBA. This process can also be applied to higher alcohols by just substituting feeds of longer chain length. [Pg.219]

Schaffarzick RW, Brown BJ The anticonvulsant activity and toxicity of methyl parafynol (Vormison) and some other alcohols. Science 116 663-665, 1952... [Pg.103]

These oxidations take place with most small primary alcohols. Unfortunately, the oxidation products of some other alcohols are more toxic than acetic acid. Methanol is oxidized first to formaldehyde and then to formic acid. Both of these compounds are more toxic than methanol itself. [Pg.475]

Isolation of water soluble materials from an aqueous solution is very costly and much problematic in an industrial scale. The isolation of ethanol from an aqueous solution obtained by the fermentation of biomass is one of the most important problems relating to a cheap energy source which may take the place of oU in future. If the crystal inclusion method can be appHed to such an isolation process cheap ethanol is available which might cause a revolution in the utilization of energy. This Section deals with the isolation of ethanol and some other alcohols from aqueous solution. [Pg.57]

The oxidation products of some other alcohols are toxic. In the case of methanol, oxidation catalyzed by LADH gives methanal (formaldehyde) and then methanoic acid (formic acid). [Pg.503]

In addition to alcohols, some other nucleophiles such as amines and carbon nucleophiles can be used to trap the acylpalladium intermediates. The o-viny-lidene-/j-lactam 30 is prepared by the carbonylation of the 4-benzylamino-2-alkynyl methyl carbonate derivative 29[16]. The reaction proceeds using TMPP, a cyclic phosphite, as a ligand. When the amino group is protected as the p-toluenesulfonamide, the reaction proceeds in the presence of potassium carbonate, and the f>-alkynyl-/J-lactam 31 is obtained by the isomerization of the allenyl (vinylidene) group to the less strained alkyne. [Pg.457]

Many of the most interesting and useful reactions of aldehydes and ketones involve trans formation of the initial product of nucleophilic addition to some other substance under the reaction conditions An example is the reaction of aldehydes with alcohols under con ditions of acid catalysis The expected product of nucleophilic addition of the alcohol to the carbonyl group is called a hemiacetal The product actually isolated however cor responds to reaction of one mole of the aldehyde with two moles of alcohol to give gem mal diethers known as acetals... [Pg.720]

In addition to the solvent soluble toners, alkah water-soluble toners have been produced. These types include WST produced by Day-Glo and Aquabest produced by Radiant Color. These toners are dissolved ia water which contains a portion of ammonia and, if necessary, some isopropyl alcohol. These toners can be used as binders or additional binders and other additives can be added to give the ink the desired properties. These toners are condensation-type polymers other than the formaldehyde types. [Pg.302]

Sahcyl alcohol [90-01-7] (saligenin, o-hydroxybenzyl alcohol) crystallizes from water in the form of needles or white rhombic crystals. It occurs in nature as the bitter glycoside, saUcin [138-52-3] which is isolated from the bark of Salix helix S. pentandra S. praecos some other species of willow trees, and the bark of a number of species of poplar trees such as Folpulus balsamifera P. candicans and P. nigra. [Pg.293]

Most flavors that are designed for beverage alcohol products use ethanol as the primary solvent for the flavor. Glycerol [56-81-5] propylene glycol [57-55-6] and water are other common solvents in Hquid flavors. Some beverage alcohol concepts require the addition of an emulsified flavor, either as a vehicle to solubilize the oils in the beverage or as a deflberate attempt to cloud the product. This can best be accompHshed at lower proofs with the alcohol breaking the emulsion. [Pg.90]

Povidone—iodine is a brown, water-soluble powder containing approximately 10% iodine. However, the amount of free iodine, which is responsible for the antimicrobial activity, is low in a concentrated solution, but is released as the solution is diluted (41). Concentrated solutions have actually been contaminated with bacteria (42). For use as an antiseptic, povidine—iodine is diluted with water or alcohol to a concentration of 1% iodine. Detergents are added if it is used as a surgical scmb. lodophors are important as broad-spectmm antiseptics for the skin, although they do not have the persistent action of some other antiseptics. They are also used as disinfectants for clinical thermometers that have been used by tuberculous patients, for surface disinfection of tables, etc, and for clean equipment in hospitals, food plants, and dairies, much as chlorine disinfectants are used. [Pg.123]

Transparent (Invisible) Flames Some materials have nearly nonluminous flames, which may not be visible, especially in the daytime. For example, hydrogen has a nearly nonvisible flame in the daytime. A person may walk unaware into a hydrogen leak flame. Some other materials, including some alcohols such as methanol, also have nearly nonluminous flames and may be unusually hazardous because the flames cannot be seen in the daytime. [Pg.2314]

Adsorption of lA of POMs with CV and Malachite Green (MG) on the polyurethane foams (PF) and some other adsorbents is investigated. While lA is fully adsorbed on the PF in wide pH range (0,4 M H SO - pH 4) extent of dye adsoi ption does not exceed 0,4%. lA are adsorbed faster then POMs. Extent of sorption of lA is 60-70% at 5 minutes and is complete after 15 minutes. lA can be eluted from PF most effectively by methylbutylketone, acetone or alcohols can be used too. [Pg.285]

Yields of the primary alkyl acrylates vary somewhat, owing to occasional losses through formation of polymer, but are usually in the range of 85-99%. Some secondary alcohols react very slowly, others readily. The method has been applied to more than fifty alcohols, some of which (with percentage yields) are listed below ethyl, 99% isopropyl, 37% -amyl, 87% isoamyl, 95% -hexyl, 99% 4-methyl-2-pentyl, 95% 2-ethylhexyl, 95% capryl, 80% lauryl, 92% myristyl, 90% allyl, 70% fur-furyl, 86% citronellyl, 91% cyclohexyl, 93% benzyl, 81% (3-ethoxyethyl, 99% /S-(/3-phenoxyethoxy) ethyl (from diethylene glycol monophenyl ether), 88%. [Pg.20]

Table 4.11 lists the Y values for some alcohol-water mixtures and for some other solvents. The Y value reflects primarily the ionization power of the solvent. It is largest for polar... [Pg.238]


See other pages where Some other alcohols is mentioned: [Pg.191]    [Pg.193]    [Pg.195]    [Pg.197]    [Pg.199]    [Pg.201]    [Pg.203]    [Pg.205]    [Pg.207]    [Pg.209]    [Pg.211]    [Pg.170]    [Pg.1065]    [Pg.1065]    [Pg.204]    [Pg.58]    [Pg.523]    [Pg.427]    [Pg.191]    [Pg.193]    [Pg.195]    [Pg.197]    [Pg.199]    [Pg.201]    [Pg.203]    [Pg.205]    [Pg.207]    [Pg.209]    [Pg.211]    [Pg.170]    [Pg.1065]    [Pg.1065]    [Pg.204]    [Pg.58]    [Pg.523]    [Pg.427]    [Pg.164]    [Pg.259]    [Pg.877]    [Pg.158]    [Pg.164]    [Pg.374]    [Pg.93]    [Pg.365]    [Pg.202]    [Pg.233]    [Pg.407]    [Pg.455]    [Pg.205]    [Pg.6]    [Pg.257]    [Pg.739]   


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Other Alcohols

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