Solubility diagram interpretation

Kumok, V. 14., Batyreva, V. A., Interpretation of the solubility diagrams of selenate systems at 25 C, Russ. J. Inorg. Chem., 35, (1990), 1514-1517. From a citation in this Bibliography... 

Herriott (1957) has reviewed the use of the solubility diagram as a tool for detecting the presence of impurities in soluble substances, particularly proteins. In these days of advanced types of instrumentation and sophisticated methods, it is worth recalling the use of a method that depends on solubility principles and is not difficult to apply. The method is based on application of the phase rule, but one need not apply the phase rule or even understand it to determine whether a preparation contains one or more components. Herriott has discussed the general procedure, the interpretation of results, the quantitative limitations of the method, the conditions and details of technique, and the separation of protein components by methods based on the solubility diagram. 

In a typical acid—base titration, the analyte is a solution of a base and the titrant is a solution of an acid or vice versa. An indicator a water-soluble dye (Section J), helps us detect the stoichiometric point, the stage at which the volume of titrant added is exactly that required by the stoichiometric relation between titrant and analyte. For example, if we titrate hydrochloric acid containing a few drops of the indicator phenolphthalein, the solution is initially colorless. After the stoichiometric point, when excess base is present, the solution in the flask is basic and the indicator is pink. The indicator color change is sudden, so it is easy to detect the stoichiometric point (Fig. L.3). Toolbox L.2 shows how to interpret a titration the procedure is summarized in diagram (3), where A is the solute in the titrant and B is the solute in the analyte. 

The application of the GLO Step Rule and, for that matter, the interpretation of activity-ratio diagrams in general are influenced by the existence of varying degrees of crystallinity or of particle size in soil minerals, with a corresponding variation in their solubility.15 For example, in the case of Fig. 3.5, very poorly crystallized forms of gibbsite and kaolinite, alluded to above, would require... 

The temperatures of thermal arrests are plotted as a function of composition in Figure 1. The lines have been drawn to suggest the location of equilibrium phase boundaries, and the best interpretation of the thermal analysis data. The resulting diagram is characteristic of a system exhibiting solid solubility with a minimum melting point and a solid-miscibility gap. 

Type B diagrams are observed when complexes of limited solubility are formed. In Fig. 5, the segment xy in curve Bg shows the formation of a complex that increases the total solubility of the compound. This is similar to a Type A diagram. At point y, however, the solubility of the complex is reached and as additional compound goes into solution, some solid complex precipitates. At point z, all of the excess solid compound added to the vials has been consumed by this process. Further addition of complexing agent beyond point z results in depletion of the compound from solution by complex formation. Curve Bj is interpreted in a similar manner except that the complex formed is so insoluble that no increase in solubility is observed. 

The mutual solubility of ozone and oxygen at —183° and —195.5° C. has been determined by measuring the magnetic susceptibility and vapor pressure (4) of solutions, and a critical solution temperature of —180° C is indicated. The vapor pressure-composition data, combined with vapor pressure data for liquid ozone (1), were used to interpret the phase diagram of the system ( ). Measurements of the density and viscosity of solutions and the surface tension of liquid ozone are reported. 

Solid-fluid phase diagrams of binary hard sphere mixtures have been studied quite extensively using MC simulations. Kranendonk and Frenkel [202-205] and Kofke [206] have studied the solid-fluid equilibrium for binary hard sphere mixtures for the case of substitutionally disordered solid solutions. Several interesting features emerge from these studies. Azeotropy and solid-solid immiscibility appear very quickly in the phase diagram as the size ratio is changed from unity. This is primarily a consequence of the nonideality in the solid phase. Another aspect of these results concerns the empirical Hume-Rothery rule, developed in the context of metal alloy phase equilibrium, that mixtures of spherical molecules with diameter ratios below about 0.85 should exhibit only limited solubility in the solid phase [207]. The simulation results for hard sphere tend to be consistent with this rule. However, it should be noted that the Hume-Rothery rule was formulated in terms of the ratio of nearest neighbor distances in the pure metals rather than hard sphere diameters. Thus, this observation should be interpreted as an indication that molecular size effects are important in metal alloy equilibria rather than as a quantitative confirmation of the Hume-Rothery rule. 

Notice that, in contrast to the analysis for cupola-shaped separation diagram of bulk alloys, one needs to interpret the size-dependent separation diagram for small particle differently. This is clear from the following reasons. Indeed, the usual cupola-shaped equilibrium diagram determines the solubility as well as equibbrium compositions as a result of separation by one line AVPBNF. For a small particle, the equilibrium diagram becomes doubled (and shifted and size dependent). So, instead of one line, one needs to deal with two lines, namely, line MQZNL of solubility CJ and line DENL of separation results C and Ci. It appears from depletion effect (splitting, CJ Cy ). We define the critical supersaturation ... 

Liquidus is the solubility curve for liquid particle. So in our Interpretation, the Hquidus curve is in a temperature-concentration diagram, the line connecting the temperatures at which freezing is just started for various compositions of a starting Hquid phase. ... 

Using the well-known tables by Pltzer, it Is easily possible to construct a generalized solubility parameter diagram as shown in Figure 25. In this particular case the acentric factor 0.075 is close to that of ethylene because when this chart was prepared over ten years ago, application was directed at interpreting solubility data for naphthalene in ethylene at high pressure. Just to orient ourselves, when the temperature is around 20 C and the pressure is... 

As the amount of solvent is increased, point M representing the overall plant balance moves toward S on Fig. 10.19 and point A j moves farther to the left. At an amount of solvent such that lines and SRf/ are parallel, point Aj will be at an infinite distance. Greater amounts of solvent will cause these lines to intersect on the right-hand side of the diagram rather than as shown, with point A nearer B for increasing solvent quantities. The interpretation of the difference point is, however, still the same a line from Ajj intersects the two branches of the solubility curve at points representing extract and raffinate from adjacent stages. 

Interpreting the Phases and Compositions in a Binary Phase Diagram as Described by the Lever Rule Alloy Compositions in a Solid Solution with Limited Solubility Determine the composition, relative amonnts, and phases present at point B on Figure 23.7. Alloy Compositions in a Solid Solution with Limited Solubility Determine the composition, relative amonnts, and phases present at point C on Figure 23.7. 

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