Temperature softening

Because cellulose triacetate has a high softening temperature, it must be processed in solution. A mixture of dichloromethane and methanol is a common solvent. 

When -xylene is used as the monomer feed in a plasma polymer process, PX may play an important role in the formation of the plasma polymer. The plasma polymer from -xylene closely resembles the Gorham process polymer in the infrared, although its spectmm contains evidence for minor amounts of nonlinear, branched, and cross-linked chains as well. Furthermore, its solubiUty and low softening temperature suggest a material of very low molecular weight (15). 

Polymer T,°C TJC Softening temperature,°C Thermal degradation temperature,°C... 

Dimensional Stability. The wet heat resistance of PVA fiber is indicated by the wet softening temperature (WTS) at which the fiber shrinks to a specified ratio. At one time, the WTS was not more than 95°C for nonacetalized PVA fiber, but improvement of WTS has been achieved by improvement in heat-drawing and -treating techniques other methods proposed include suppression of polymerization temperature of vinyl acetate (36) and employment of alkafi spinning (37). 

In commercial practice, packaging is produced from continuous web on intermittent-motion thermoforming/die-cut machines. The web edge is clamped and conveyed into a heating box. If a plastic with a narrow softening temperature is used, heating is carefully controUed from top and bottom. 

The tailoring of PE properties in commercial processes is achieved mostiy by controlling the density, molecular weight, MWD, or by cross-linking. Successful control of all reaction parameters enables the manufacture of a large family of PE products with considerable differences in physical properties, such as the softening temperatures, stiffness, hardness, clarity, impact, and tear strength. 

ISO 306, Plastics Thermoplastic Materials-Determination of Vicat Softening Temperature, ISO, Geneva, Swit2eiiand, 1987. 

MSTM D1525, Test Methodfor Hicat Softening Temperature of Plastics, Vol. 8.01, ASTM, Philadelphia, Pa., 1991. 

Refractoriness. Refractoriaess is determined by several methods. The pyrometric cone equivalent (PCE) test (ASTM C24) measures the softening temperature of refractory materials. Inclined trigonal pyramids (cones) are formed from finely ground materials, set on a base, and heated at a specific rate. The time and temperature (heat treatment) requited to cause the cone to bend over and touch the base is compared to that for standard cones. 

Ash Fusibility. A molded cone of ash is heated in a mildly reducing atmosphere and observed using an optical pyrometer during heating. The initial deformation temperature is reached when the cone tip becomes rounded the softening temperature is evidenced when the height of the cone is equal to twice its width the hemispherical temperature occurs when the cone becomes a hemispherical lump and the fluid temperature is reached when no lump remains (D1857) (18). 

Figure 17.1 and Table 17.1 give melting points for metals and ceramics and softening temperatures for polymers. Most metals and ceramics have high melting points and, because of this, they start to creep only at temperatures well above room temperature... 

From what we have said so far it should be obvious that the first requirement that we should look for in choosing materials that are resistant to creep is that they should have high melting (or softening) temperatures. If the material can then be used at less than 0.3 of its melting temperature creep will not be a problem. If it has to be used above this temperature, various alloying procedures can be used to increase creep resistance. To... 

These requirements severely limit our choice of creep-resistant materials. For example, ceramics, with their high softening temperatures and low densities, are ruled out for aero-engines because they are far too brittle (they are under evaluation for use in land-based turbines, where the risks and consequences of sudden failure are less severe - see below). Cermets offer no great advantage because their metallic matrices soften at much too low a temperature. The materials which best fill present needs are the nickel-based super-alloys. 

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