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Single-crystal electrodes

Soriaga M P 1992 Ultra-high vacuum techniques in the study of single-crystal electrode surfaces Prog. Surf. Sc/. 39 325... [Pg.320]

A single crystal electrode is exemplified by the lanthanum fluoride electrode in which a crystal of lanthanum fluoride is sealed into the bottom of a plastic container to produce a fluoride ion electrode. The container is charged with a... [Pg.559]

The surface electrochemistry of Pt single-crystal electrodes has been exhaustively studied using cyclic voltammetry.100 186 188 197 209 412 753-756,771,-773,779-788,794-796 qq g technique has been proved to be highly... [Pg.130]

Figure 40. PMC peak measured with a ZnO single-crystal electrode in a microwave resonator near the onset of the anodic photocurrent.5... Figure 40. PMC peak measured with a ZnO single-crystal electrode in a microwave resonator near the onset of the anodic photocurrent.5...
Hamelin, A. Double-Layer Properties at sp and sd Metal Single-Crystal Electrodes 16... [Pg.604]

Reaction Kinetics and Mechanism on Metal Single Crystal Electrode Surfaces AdiiC, R. 21... [Pg.621]

FeUu JM, Gomez R, Llorca MS, Aldaz A (1993) Electrochemical behavior of irreversibly adsorbed selenium dosed from solution on Pt(h,k,l) single crystal electrodes in sulphuric and perchloric acid media. Surf Sci 289 152-162... [Pg.202]

Fan and Bard [140] employed capacitance and voltammetric measurements to investigate the photoelectrochemical behavior of n-WSe2, p-WSe2, and n-MoSe2 single-crystal electrodes in aqueous solutions containing various redox couples, namely Br /Br2, I /I, Fe(CN)6" /Fe(CN)6 , Fe /Fe, and... [Pg.244]

Fujishima A, Sugiyama E, Honda K (1971) Photosensitized electrolytic oxidation of iodide ions on cadmium sulfide single crystal electrode. Bull Chem Soc Japan 44 304 Inoue T, Watanabe T, Fujishima A, Honda K, Kohayakawa K (1977) Suppression of surface dissolution of CdS photoanode by reducing agents. J Electrochem Soc 124 719-722 Elhs AB, Kaiser SW, Wrighton MS (1976) Visible light to electrical energy conversion. Stable cadmium sulfide and cadmium selenide photoelectrodes in aqueous electrolytes. J Am Chem Soc 98 1635-1637... [Pg.294]

Salvador P, Chaparro AM, Mir A (1996) Digital imaging of the effect of photoetching on the photoresponse of n-type tungsten diselenide and molybdenum diselenide single crystal electrodes. J Phys Chem 100 760-768... [Pg.299]

Chaparro AM, Salvador P, Mir A (1996) The scanning microscope for semiconductor characterization (SMSC) Study of the influence of surface morphology on the photoelectrochemical behavior of an n-MoSe2 single crystal electrode by photocurrent and electrolyte electroreflectance imaging. J Electroanal Chem 418 175-183... [Pg.299]

Uosaki K, Kaneko S, Kita H, Chevy A (1986) Electrochemical behavior of p-type indium selenide single crystal electrodes in dark and under illumination. Bull Chem Soc Jpn 59 599-605... [Pg.300]

Since oxidation of methanol is an electrocatalytic reaction with different adsorption steps, interactions of the adsorbed species with the metallic surface are important. Using platinum single-crystal electrodes, it has been proven that the electrooxidation of methanol is a surface-sensitive reaction. The initial activity of the Pt(llO) plane is much higher than that of the other low-index planes, but the poisoning phenomenon is so rapid that it causes a fast decrease in the current densities. The... [Pg.83]

Reaction Kinetics and Mechanisms on Metal Single Crystal Electrode Surfaces Recent Developments in Faradaic Rectification Studies... [Pg.247]

Protsailo, L.V., Fawcett, W.R., Russell, D. and Meyer, R.L. (2002) Electrochemical Characterization of the Alkaneselenol-Based SAMs on Au(lll) Single Crystal Electrode. Langmuir, 18, 9342-9349. [Pg.355]

SHG has been used to study electrode surface symmetry and order using an approach known as SH rotational anisotropy. A single-crystal electrode is rotated about its surface normal and the modulation of the SH intensity is measured as the angle (9) between the plane of incidence and a given crystal axis or direction. Figure 27.34 shows in situ SHG results for an Au(ll 1) electrode in 0.1 M NaC104 + 0.002 M NaBr, using a p-polarized beam. The results indicate the presence of two distinct onefold... [Pg.501]

Many studies at single-crystal electrodes of xp-metals were directed at the special features of double-layer stracture and the potential of zero charge at the various single-crystal faces. It was shown that rather large differences could exist between the potentials of zero charge of different faces (see Table 10.1). [Pg.531]

Taylor CD, Kelly RG, Neurock M. 2007c. Theoretical analysis of the nature of hydrogen at the electrochemical interface between water and a Ni(lll) single-crystal electrode. J Electrochem Soc 154 F55-F64. [Pg.128]

This general scheme for the oxidation reaction is very sensitive to the surface stmcture. The first studies with single-crystal electrodes revealed that the voltammetric profiles for the three basal planes, Pt(lll), Pt(lOO), and Pt(llO), were completely different (Fig. 6.13) [Clavilier et ah, 1981 Lamy et al., 1983 Adzic et ah, 1982]. The lowest currents are obtained for the Pt(l 11) electrode, which in mm has a very low poisoning rate, as suggested by the small hysteresis. In fact, the reaction on this... [Pg.178]

Housmans and Koper [2003] have carried out a detailed analysis of the chronoam-perometric transients on a series of stepped single-crystal electrodes using reaction models very similar to those used in Franaszczuk et al. [1992] and Jarvi and Stuve [1998]. The expression that they used to model the current transient was... [Pg.190]

Angelucci CA, Nart FC, Heirero E, Feliu JM. 2007a. Anion re-adsorption and displacement at platinum single crystal electrodes in CO-containing solutions. Electrochem Commun 9 1113-1119. [Pg.199]

Clavilier J. 1987. Pulsed linear sweep voltammetry with pulses of constant level in a potential scale, a polarization demanding condition in the study of platinum single crystal electrodes. J Electroanal Chem 236 87-94. [Pg.200]

Clavilier J, Sun SG. 1986. Electrochemical study of the chemisorbed species formed from formic acid dissociation at platinum single crystal electrodes. J Electroanal Chem 199 ... [Pg.200]

Garcia G, Koper MTM. 2008. Stripping voltammetry of carbon monoxide oxidation on stepped platinum single-crystal electrodes in alkaline solution. Phys Chem Chem Phys 10 3802-3811. [Pg.201]

Hoshi N, Kida K, Nakamura M, Nakada M, Osada K. 2006. Structural effects of electrochemical oxidation of formic acid on single crystal electrodes of palladium. J Phys Chem B 110 12480-12484. [Pg.202]

See other pages where Single-crystal electrodes is mentioned: [Pg.109]    [Pg.73]    [Pg.92]    [Pg.109]    [Pg.599]    [Pg.217]    [Pg.218]    [Pg.242]    [Pg.246]    [Pg.256]    [Pg.559]    [Pg.252]    [Pg.531]    [Pg.531]    [Pg.531]    [Pg.161]    [Pg.166]    [Pg.176]    [Pg.192]    [Pg.194]    [Pg.194]    [Pg.196]   
See also in sourсe #XX -- [ Pg.531 ]

See also in sourсe #XX -- [ Pg.232 , Pg.336 , Pg.358 ]

See also in sourсe #XX -- [ Pg.150 ]



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