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Silicates isolation

Orthosilicates or neso-silicates Isolated [Si04] tetrahedra Olivine, (Mg, Fe, Mn)(Si04) Zircon, Zr(Si04)... [Pg.203]

Titanium Silicates. A number of titanium siUcate minerals are known (160) examples are Hsted in Table 19. In most cases, it is convenient to classify these on the basis of the connectivity of the SiO building blocks, eg, isolated tetrahedra, chains, and rings, that are typical of siUcates in general. In some cases, the SiO units may be replaced, even if only to a limited extent by TiO. For example, up to 6% of the SiO in the garnet schorlomite can be replaced by TiO. In general, replacement of SiO by TiO bull ding blocks increases the refractive indices of these minerals. Ti has also replaced Si in the framework of various zeofltes. In addition, the catalytic activity of both titanium-substituted ZSM-5 (TS-1) and ZSM-11 (TS-2) has received attention (161), eg, the selective oxidation of phenol, with hydrogen peroxide, to hydroquinone and catechol over TS-1 has been operated at the 10,000 t/yr scale in Italy (162). [Pg.132]

Figure 5. Infrared spectrum of pyrethrin II Fraction isolated from silicic acidr-acetonitrile-hexane partition column... Figure 5. Infrared spectrum of pyrethrin II Fraction isolated from silicic acidr-acetonitrile-hexane partition column...
Figure 7. Infrared spectrum of pyrethrin I Isolated after dual partition chromatography First partition column. Celite-acetonitrile-hexane Second partition column. Silicic acid-nitromethane-hexane (with 5% acetone). Corresponds to peak 3 of gas chromatographic separation of pyrethrum mixture... Figure 7. Infrared spectrum of pyrethrin I Isolated after dual partition chromatography First partition column. Celite-acetonitrile-hexane Second partition column. Silicic acid-nitromethane-hexane (with 5% acetone). Corresponds to peak 3 of gas chromatographic separation of pyrethrum mixture...
Figure 8. Infrared spectrum of a cinerin I type Fraction isolated from Celite-acetonitrile-hexane partition column and rechromatographed on a silicic acid-nitrome-thane-hexane (with 5% acetone) partition column. Figure 8. Infrared spectrum of a cinerin I type Fraction isolated from Celite-acetonitrile-hexane partition column and rechromatographed on a silicic acid-nitrome-thane-hexane (with 5% acetone) partition column.
Some metals that are chemically combined with oxygen (metal oxides) also dissolve in sodium hydroxide. For example, aluminum ore (known as bauxite) is treated with sodium hydroxide to isolate pure aluminum oxide, from which pure aluminum is obtained. Sand (silicon dioxide) will also dissolve in sodium hydroxide to form a chemical known as sodium silicate or water glass. [Pg.29]

A solution of sodium methoxide (80 mmol) in methanol (40 mL) is added to silica gel (2.7 g, 45 mmol) followed by a solution of catechol (13.2 g, 120 mmol) in methanol (40 mL). The resulting mixture is stirred and heated under reflux for 18 h. The methanol is then evaporated and the solid residue washed with ether. The black sohd is dissolved in THF (400 mL) and the resulting solution is heated for 1 h in the presence of charcoal. After filtration and evaporation of the solvent the sodium tris(benzene-l,2-diolato)silicate 80 is isolated as a white powder (12.53 g, 70% Scheme 2.20) [93]. [Pg.26]

Six elements are metalloids B, Si, Ge, As, Sb, and Te. Of these, silicon is by far the most abundant, making up over 27% of the Earth s crust, more than any other element except oxygen, hi fact, S1O2 and silicate minerals account for 80% of the atoms near the Earth s surface. Despite its great abundance, silicon was not discovered until 1824, probably because the strong bonds it forms with oxygen makes silicon difficult to isolate. Two much rarer metalloids, antimony (known to the ancients) and arsenic (discovered ca. 1250 ad) were isolated and identified long before silicon. [Pg.1521]

Silicon w is first isolated and described as an element in 1824 by Jdns Jacob Berzelius, a Swedish chemist. Silicon does not occur uncombined in nature, i.e.- as an element. It is found in practically aU rocks as well as in sand, clays, and soils, combined either with oxygen as silica (Si02= silicon dioxide) or with oxygen plus other elements (e.g., aliuninum, mcignesium, calcium, sodium, potassium, or iron) as silicates. Its compounds also occur in all natural waters, in the atmosphere (as siliceous dust), in many plants, and in the skeletons, tissues, and body fluids of some animals. [Pg.309]

It is helpful in the discussion to describe silicate structures using the Q nomenclature, where Q represents [SiOJ tetrahedra and the superscript n the number of Q units in the second coordination sphere. Thus, isolated [SiO ] " are represented as Q and those fully connected to other Q units as Q. In general, minerals based on Q , Q and units are decomposed by acids. Such minerals are those containing isolated silicate ions, the orthosilicates, SiO (Q ) the pyrosilicates, Si O " (Q ) ring and chain silicates, (SiOg) (Q ). Certain sheet and three-dimensional silicates can also yield gels with acids if they contain sites vulnerable to acid attack. This occurs with aluminosilicates provided the Al/Si ratio is at least 2 3 when attack occurs at A1 sites, with scission of the network (Murata, 1943). [Pg.114]

Figure 11.1a [1] shows a schematic representation of a micropreparative thin-layer chromatogram obtained on a 0.5-mm Florisil (magnesium silicate) layer prewetted with benzene of a crude extract, i.e., containing coextracted plant oil obtained from Heracleum moelendorfi fruit. The initial band of extract was washed with benzene and then separated by continuous development with ethyl acetate in benzene [1]. As seen from the fraction analysis presented in Figure 11.1b, small quantities of pure bergapten and xanthotoxin can be isolated in this maimer. [Pg.253]

P. A. Alikin, N. N. Kasatkina, N. M. Makeev, and V. Yu. Vantsev. Plugging solution for deep wells—contains slag-sand cement, iron chloride, polyacrylamide, ethyl silicate and water, and has increased isolating efficiency. Patent SU 1776761-A, 1992. [Pg.347]

In the previous reviews,1 la,d f syntheses of many examples of transient silicon-oxygen double bond compounds such as MeHSi=0, Me2Si=0, H2Si=0 (2), (H0)HSi=0 (silanoic acid), and (H0)2Si=0 (silicic acid) have been described, and they are reportedly isolated as stable species in the low temperature matrices. However, the stabilization of this extremely reactive double bond species is very difficult, and no stable example of silanone (RR/Si=0) has been isolated until now even by the methods of thermodynamic or kinetic stabilization. [Pg.127]

The early period of the Earth s history, around 3.8 1 billion years ago, is completely shrouded in darkness possible witnesses from this archaic period might help to cast some light. So we are looking for possible remains of the first primitive life forms on our planet—fossils, or to be exact, microfossils, which refers to the remains of living cells. What have survived are mainly only cell walls, which can be isolated from sedimentary rocks when the silicate-, sulphide- or carbonate-rich minerals are chemically dissolved away. The microfossils are found in the remaining carbon-containing residue, transparently thin platelets of which are prepared for microscopic studies. [Pg.257]

In studies of amphiboles (44), isolated strips of triplechain silicates were discovered embedded in the double-chain parent structure. It was later realized that new types of silicate structures, composed of recurrent triple chains, existed in nature. The part that HREM played in the identification of this new family of triple-chain silicates, which constitute a further step in the progression pyroxene, amphibole,. .. mica, was crucial. [Pg.444]

Isolation of the active component is carried out chro-matographically. Roth et al.9 used a magnesol (magnesium silicate) column to absorb colored impurities, followed by a Darco G-60 activated carbon column to eliminate sodium formate and inorganics. Elution with an alcohol/ammonia solvent was followed by rechromatographing in magnesol. [Pg.329]


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See also in sourсe #XX -- [ Pg.315 ]




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