Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Silica porosity

Filter crucibles with a porous filter base are available in porcelain (porosity 4), in silica (porosities 1,2,3,4), and in alumina (coarse, medium and fine porosities) these have the advantage as compared with sintered crucibles, of being capable of being heated to much higher temperatures. Nevertheless, the heating must be gradual otherwise the crucible may crack at the join between porous base and glazed side. [Pg.103]

The capacitance values of the carbons from propylene, i.e. CPr in the three electrolytic media are lower than for the materials from sucrose CS (Table 4), and they decrease with the total surface area of the carbon materials, i.e. with the filling rate of carbon in the silica porosity [18], These results are not surprising since the carbon filling is quite uniform during the CVI process, and consequently, the fraction of micropores formed is much... [Pg.39]

TABLE 10. Variation of silica porosity depending on the experimental parameter of the chemical treatment... [Pg.627]

Surface energy and surface extension together characterize the activity of silica ( activity is the surface property of the adsorbent), and the size of the surface is reduced when covered with molecules such as water and glycol, which deactivate the surface of the sorbent. An increase in surface activity results in lower Rf values which, therefore, depend on silica porosity and humidity changes. The surface pore diameter can vary over a wide range TLC sorbents have pores of 40,60, 80, and 100 A. The specific surface area of sihca gel ranges from 200 to 800 m7g. [Pg.1636]

As in the manufacture of silica, porosity, pore size, and surface area of polymer packings can be adjusted over a wide range, and micro-, meso-, and macro- as well as non-porous beads are synthesized reproducibly. [Pg.82]

Dacquin et al. [51] used a method called in situ crystallization in a confined space to prepare a LaNiOs/SBAlO catalyst. As evidenced by TEM analysis, very small nanoparticles of perovskite were generated within the silica porosity with a size between 2 and 5 nm and an average closed to 3 nm. The reduction step performed at 700 °C gives Ni° particles well dispersed within the matrix porosity and their size remained close to the support pore size. The catalytic activity for syngas production was doubled compared to bulk LaNiOs precursor, it remains... [Pg.511]

The pores of a 2-mm-thick sintered silica (porosity 0.3) are filled with water at 25°C. At one side of the solid a potassium chloride solution (0.10 g mole/liter) is placed. Pure water flows past the other side. Experimental observation shows the potassium chloride flux to be 7.01 X 10 kg mole/sec. Based on this result, derive an appropriate equation to describe this system. (Hint Alter the diffusion equation to reflect the porous medium.)... [Pg.245]

Compressional wave velocities versus bulk density for the series of acid-catalyzed TEOS xerogels investigated by Murtagh el al. [31], The solid lines correspond to the relationship predicted from a fused silica-porosity composite assuming either spherical- or needle-shaped pores. Gel values fall beneath the predicted values, indicating that the skeletal phase is not as stiff as conventional fused silica [31]. [Pg.277]

In view of the widespread use of nitrogen and argon in surface area and porosity studies, data for the construction of the standard a,-curves for these adsorbates on hydroxylated silica, are given in Table 2.14 (p. 93) for nitrogen and in Table 2.15 for argon. From the arguments of Section 2.12, these should be adequate for other oxides such as alumina, if high accuracy is not called for. [Pg.99]

In Unger and Fischer s study of the effect of mercury intrusion on structure, three samples of porous silica were specially prepared from spherical particles 100-200 pm in diameter so as to provide a wide range of porosity (Table 3.16). The initial pore volume n (EtOH) was determined by ethanol titration (see next paragraph). The pore volume u (Hg, i) obtained from the first penetration of mercury agreed moderately well with u fEtOH),... [Pg.182]

Diatomaceous Silica Filter aids of diatomaceous silica have a dry bulk density of 128 to 320 kg/m (8 to 20 Ib/fU), contain paiiicies mostly smaller than 50 [Lm, and produce a cake with porosity in the range of 0.9 (volume of voids/total filter-cake volume). The high porosity (compared with a porosity of 0.38 for randomly packed uniform spheres and 0.2 to 0.3 for a typical filter cake) is indicative of its filter-aid ability Different methods of processing the crude diatomite result in a series of filter aids having a wide range of permeability. [Pg.1708]

We showed that these mesoporous silica materials, with variable pore sizes and susceptible surface areas for functionalization, can be utilized as good separation devices and immobilization for biomolecules, where the ones are sequestered and released depending on their size and charge, within the channels. Mesoporous silica with large-pore-size stmctures, are best suited for this purpose, since more molecules can be immobilized and the large porosity of the materials provide better access for the substrates to the immobilized molecules. The mechanism of bimolecular adsorption in the mesopore channels was suggested to be ionic interaction. On the first stage on the way of creation of chemical sensors on the basis of functionalized mesoporous silica materials for selective determination of herbicide in an environment was conducted research of sorption activity number of such materials in relation to 2,4-D. [Pg.311]

Commercially available pre-coated plates with a variety of adsorbents are generally very good for quantitative work because they are of a standard quality. Plates of a standardised silica gel 60 (as medium porosity silica gel with a mean porosity of 6mm) released by Merck have a specific surface of 500 m /g and a specific pore volume of 0.75 mL/g. They are so efficient that they have been called high performance thin layer chromatography (HPTLC) plates (Ropphahn and Halpap J Chromatogr 112 81 1975). In another variant of thin layer chromatography the... [Pg.18]

A mixture of powdered poly(vinyl chloride), cyclohexanone as solvent, silica, and water is extruded and rolled in a calender into a profiled separator material. The solvent is extracted by hot water, which is evaporated in an oven, and a semiflexible, microporous sheet of very high porosity ( 70 percent) is formed [19]. Further developments up to the 75 percent porosity have been reported [85,86], but these materials suffer increasingly from brittleness. The high porosity results in excellent values for acid displacement and electrical resistance. For profiles, the usual vertical or diagonal ribs on the positive side, and as an option low ribs on the negative side, are available [86],... [Pg.275]

As surface area and pore structure are properties of key importance for any catalyst or support material, we will first describe how these properties can be measured. First, it is useful to draw a clear borderline between roughness and porosity. If most features on a surface are deeper than they are wide, then we call the surface porous (Fig. 5.16). Although it is convenient to think about pores in terms of hollow cylinders, one should realize that pores may have all kinds of shapes. The pore system of zeolites consists of microporous channels and cages, whereas the pores of a silica gel support are formed by the interstices between spheres. Alumina and carbon black, on the other hand, have platelet structures, resulting in slit-shaped pores. All support materials may contain micro, meso and macropores (see text box for definitions). [Pg.182]

The interferometer assembly has been modified to provide acoustic isolation from both building vibrations and airborne noise (7). These improvements have greatly enhanced the signal to noise. The spectra presented here show a signal to noise ratio in excess of 500 for silica samples and in excess of 100 for the alumina samples the differences are due to different sample porosities. No smoothing of the spectra has been performed, and all spectra reported are direct reproductions of the plotter output from the spectrometer. [Pg.451]


See other pages where Silica porosity is mentioned: [Pg.199]    [Pg.306]    [Pg.398]    [Pg.418]    [Pg.2198]    [Pg.828]    [Pg.199]    [Pg.306]    [Pg.398]    [Pg.418]    [Pg.2198]    [Pg.828]    [Pg.535]    [Pg.1059]    [Pg.2064]    [Pg.2471]    [Pg.258]    [Pg.630]    [Pg.634]    [Pg.295]    [Pg.56]    [Pg.489]    [Pg.162]    [Pg.96]    [Pg.34]    [Pg.84]    [Pg.139]    [Pg.14]    [Pg.201]    [Pg.35]    [Pg.41]    [Pg.7]    [Pg.285]   
See also in sourсe #XX -- [ Pg.66 ]

See also in sourсe #XX -- [ Pg.1392 ]




SEARCH



© 2024 chempedia.info