Scaling number, dimensionless

Dimensionless Numbers. With impeller diameter D as length scale and mixer speed N as time scale, common dimensionless numbers encountered in mixing depend on several controlling phenomena (Table 2). These quantities are useful in characterizing hydrodynamics in mixing tanks and when scaling up mixing systems. 

Scaling by use of dimensionless numbers only is limited in two-phase flow to simple and isolated problems, where the physical phenomenon is a unique function of a few parameters. If there is a reaction between two or more physical occurrences, dimensionless scaling numbers can mainly serve for selecting the hydrodynamic and thermodynamic conditions of the modelling tests. In... 

The scale-up procedure, then, is simple express the process using a complete set of dimensionless numbers, and try to match them at different scales. This dimensionless space in which the measurements are presented or measured will make the process scale invariant. 

Dimensional analysis is a method for producing dimensionless numbers that completely characterize the process. The analysis can be applied even when the equations governing the process are not known. According to the theory of models, two processes may be considered completely similar if they take place in similar geometrical space and if all the dimensionless numbers necessary to describe the process have the same numerical value [2], The scale-up procedure, then, is simple express the process using a complete set of dimensionless numbers, and try to match them at different scales. This dimensionless space in which the measurements are presented or measured will make the process scale invariant. 

Reynold s number dimensionless number used in scaling fluid systems and in determining the transition point from laminar to turbulent flow. 

Unfortunately, donor numbers have been defined in the non-SI unit kcal mol b Marcus has presented a scale of dimensionless, normalized donor numbers DN, which are defined according to DN = DNl i%.% kcal mol ) [200]. The non-donor solvent 1,2-dichloroethane [DN = DN = 0.0) and the strong donor solvent hexamethyl-phosphoric triamide (EiMPT DN = 38.8 kcal mol DN = 1.0) have been used to define the scale. Although solvents with higher donicity than EiMPT are known [cf. Table 2-3), it is expedient to choose the solvent with the highest directly [i.e. calori-metrically) determined DN value so far as the second reference solvent [200] f The DN values are included in Table 2-3. 

FIGURE 8.9 Spinodal decomposition process modeled using the Cahn-Hilliard equation. Time and length scales are dimensionless. Number of time steps following the quench are (a) 10,000, (b) 40,000, (c) 160,000, and (d) 640,000. Courtesy of Dr. Nigel Clarke (University of Durham, U.K.). 

Schmidt number Sherwood number dimensionless time dimensionless fluid temperature initial dimensionless temperature distribution dimensionless soUd phase temperature dimensionless volume-averaged solid temperature scale for temperature change, K dimensionless external temperature rise dimensionless inlet temperature maximum dimensionless temperature in the solid maximum dimensionless internal temperature rise... 

Asymptotic Solution Rate equations for the various mass-transfer mechanisms are written in dimensionless form in Table 16-13 in terms of a number of transfer units, N = L/HTU, for particle-scale mass-transfer resistances, a number of reaction units for the reaction kinetics mechanism, and a number of dispersion units, Np, for axial dispersion. For pore and sohd diffusion, q = / // p is a dimensionless radial coordinate, where / p is the radius of the particle, if a particle is bidisperse, then / p can be replaced by the radius of a suoparticle. For prehminary calculations. Fig. 16-13 can be used to estimate N for use with the LDF approximation when more than one resistance is important. 

Damkdhler (1936) studied the above subjects with the help of dimensional analysis. He concluded from the differential equations, describing chemical reactions in a flow system, that four dimensionless numbers can be derived as criteria for similarity. These four and the Reynolds number are needed to characterize reacting flow systems. He realized that scale-up on this basis can only be achieved by giving up complete similarity. The recognition that these basic dimensionless numbers have general and wider applicability came only in the 1960s. The Damkdhler numbers will be used for the basis of discussion of the subject presented here as follows ... 

This chapter reviews the various types of impellers, die flow patterns generated by diese agitators, correlation of die dimensionless parameters (i.e., Reynolds number, Froude number, and Power number), scale-up of mixers, heat transfer coefficients of jacketed agitated vessels, and die time required for heating or cooling diese vessels. 

It is only po.ssible to obtain similar solutions in situations where the governing equations (Eqs. (12.40) to (12.44)) are identical in the full scale and in the model. This tequirement will be met in situations where the same dimensionless numbers are used in the full scale and in the model and when the constants P(i, p, fj.Q,.. . have only a small variation within the applied temperature and velocity level. A practical problem when water is used as fluid in the model is the variation of p, which is very different in air and in water see Fig. 12.27. Therefore, it is necessary to restrict the temperature differences used in model experiments based on water. 

Here r is the distance between the centers of two atoms in dimensionless units r = R/a, where R is the actual distance and a defines the effective range of the potential. Uq sets the energy scale of the pair-interaction. A number of crystal growth processes have been investigated by this type of potential, for example [28-31]. An alternative way of calculating solid-liquid interface structures on an atomic level is via classical density-functional methods [32,33]. 

Reduce the number of variables by combining the variables into a few dimensionless terms. These dimensionless terms can be used to assist in the design of a physical model that, in turn, can be used for experimentation (on an economic scale) that will yield insight into the prototype device or system. 

In 1953, Rushton proposed a dimensionless number that is used for scale-up calculation. The dimensionless group is proportional to NRe as shown by the following equation 2,3... 

Since the process is more complex, the proposed method may not be valid for scale-up calculation. The combination of power and Reynolds number was the next step for correlating power and fluid-flow dimensionless number, which was to define power number as a function of the Reynolds number. In fact, the study by Rushton summarised various geometries of impellers, as his findings were plotted as dimensionless power input versus impeller... 

Equations (3.11) and (3.12) show that the friction factor of a rectangular micro-channel is determined by two dimensionless groups (1) the Reynolds number that is defined by channel depth, and (2) the channel aspect ratio. It is essential that the introduction of a hydraulic diameter as the characteristic length scale does not allow for the reduction of the number of dimensionless groups to one. We obtain... 

A dimensionless dispersion number, based on the probable number of passes through the shear zone for an ingredient to be dispersed, was developed for scale-up of mixing of short fiber... 

In any circumstances, it can be expected that and (5x are algebraic functions of turbulence length scale and kinetic energy, as well as chemical and molecular quantities of the mixture. Of course, it is expedient to determine these in terms of relevant dimensionless quantities. The simplest possible formula, in the case of very fast chemistry, i.e., large Damkohler number Da = (Sl li)/ SiU ) and large Reynolds Re = ( Ij)/ (<5l Sl) and Peclet numbers, i.e., small Karlovitz number Ka = sjRej/Da will be Sj/Sl =f(u / Sl), but other ratios are also quite likely to play a role in the general case. 

In order to derive specific numbers for the temperature rise, a first-order reaction was considered and Eqs. (10) and (11) were solved numerically for a constant-density fluid. In Figure 1.17 the results are presented in dimensionless form as a function of k/tjjg. The y-axis represents the temperature rise normalized by the adiabatic temperature rise, which is the increase in temperature that would have been observed without any heat transfer to the channel walls. The curves are differentiated by the activation temperature, defined as = EJR. As expected, the temperature rise approaches the adiabatic one for very small reaction time-scales. In the opposite case, the temperature rise approaches zero. For a non-zero activation temperature, the actual reaction time-scale is shorter than the one defined in Eq. (13), due to the temperature dependence of the exponential factor in Eq. (12). For this reason, a larger temperature rise is foimd when the activation temperature increases. 

In Table 1.4, the characteristic time-scales for selected operations are listed. The rate constants for surface and volume reactions are denoted by and respectively. Furthermore, the Sherwood number Sh, a dimensionless mass-transfer coefficient and the analogue of the Nusselt number, appears in one of the expressions for the reaction time-scale. The last column highlights the dependence of z p on the channel diameter d. Apparently, the scale dependence of different operations varies from dy f to (d ). Owing to these different dependences, some op-... 

Dimensionless numbers (Reynolds number = udip/jj., Nusselt number = hd/K, Schmidt number = c, oA, etc.) are the measures of similarity. Many correlations between them (known also as scale-up correlations) have been established. The correlations are used for calculations of effective (mass- and heat-) transport coefficients, interfacial areas, power consumption, etc. 

An alternative to the measurement of the dimensions of the indentation by means of a microscope is the direct reading method, of which the Rockwell method is an example. The Rockwell hardness is based on indentation into the sample under the action of two consecutively applied loads - a minor load (initial) and a standardised major load (final). In order to eliminate zero error and possible surface effects due to roughness or scale, the initial or minor load is first applied and produce an initial indentation. The Rockwell hardness is based on the increment in the indentation depth produced by the major load over that produced by the minor load. Rockwell hardness scales are divided into a number of groups, each one of these corresponding to a specified penetrator and a specified value of the major load. The different combinations are designated by different subscripts used to express the Rockwell hardness number. Thus, when the test is performed with 150 kg load and a diamond cone indentor, the resulting hardness number is called the Rockwell C (Rc) hardness. If the applied load is 100 kg and the indentor used is a 1.58 mm diameter hardened steel ball, a Rockwell B (RB) hardness number is obtained. The facts that the dial has several scales and that different indentation tools can be filled, enable Rockwell machine to be used equally well for hard and soft materials and for small and thin specimens. Rockwell hardness number is dimensionless. The test is easy to carry out and rapidly accomplished. As a result it is used widely in industrial applications, particularly in quality situations. 

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