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Saturated alkenes

A two-dimensional supercritical fluid chromotography (SFC) system has been developed for the determination of saturates, alkenes, and mono-, di-, and tri-aromatics in diesel fuel. This technique results in a short analysis time (less than 8 minutes) and good relative standard deviations at low alkene content (Andersson et al. 1992). [Pg.156]

As noted in the introduction, in contrast to attack by nucleophiles, attack of electrophiles on saturated alkene-, polyene- or polyenyl-metal complexes creates special problems in that normally unstable 16-electron, unsaturated species are formed. To be isolated, these species must be stabilized by intramolecular coordination or via intermolecular addition of a ligand. Nevertheless, as illustrated in this chapter, reactions of significant synthetic utility can be developed with attention to these points. It is likely that this area will see considerable development in the future. In addition to refinement of electrophilic reactions of metal-diene complexes, synthetic applications may evolve from the coupling of carbon electrophiles with electron-rich transition metal complexes of alkenes, alkynes and polyenes, as well as allyl- and dienyl-metal complexes. Sequential addition of electrophiles followed by nucleophiles is also viable to rapidly assemble complex structures. [Pg.712]

Alkanes contain only single bonds. Alkanes have the maximum number of hydrogen atoms possible for their carbon backbone, so they are called saturated. Alkenes, alkynes, and aromatics are unsaturated because they have fewer hydrogen atoms.. [Pg.133]

Catalytic reduction in methanol using decaborane as the hydrogen source successfully saturates alkenes and alkynes and converts nitroarenes to arylamines. Concurrent A -alkylation to afford ArNHCHRR occurs when a carbonyl compound (RR C=0) is present. " ... [Pg.313]

Evidence of the importance of the technique was the method development work sponsored by the American Petroleum Institute (API) for the analysis of constituents in petroleum products for example, ASTM D-1319 [20] details the procedure for the determination of saturates, alkenes and aromatics using a fluorescent indicator on silica gel adsorbent with isopropanol as eluant. [Pg.6]

Alkane saturated, alkene unsaturated, alkyne unsaturated... [Pg.428]

Arosolvan process A process for the extraction of benzene and toluene from a mixture of aromatic and saturated hydrocarbons using a mixture of water and N-methylpyrrolidone. The process is used when naphtha is cracked to produce alkenes. To prevent extraction of alkenes these are saturated by hydrogenation prior to extraction. [Pg.41]

Alkylation combines lower-molecular-weight saturated and unsaturated hydrocarbons (alkanes and alkenes) to produce high-octane gasoline and other hydrocarbon products. Conventional paraffin-olefin (alkane-alkene) alkylation is an acid-catalyzed reaction, such as combining isobutylene and isobutane to isooctane. [Pg.102]

Migration of a hydride ligand from Pd to a coordinated alkene (insertion of alkene) to form an alkyl ligand (alkylpalladium complex) (12) is a typical example of the a, /(-insertion of alkenes. In addition, many other un.saturated bonds such as in conjugated dienes, alkynes, CO2, and carbonyl groups, undergo the q, /(-insertion to Pd-X cr-bonds. The insertion of an internal alkyne to the Pd—C bond to form 13 can be understood as the c -carbopa-lladation of the alkyne. The insertion of butadiene into a Ph—Pd bond leads to the rr-allylpalladium complex 14. The insertion is usually highly stereospecific. [Pg.7]

In the reaction of Q,/3-unsaturated ketones and esters, sometimes simple Michael-type addition (insertion and hydrogenolysis, or hydroarylation, and hydroalkenylation) of alkenes is observed[53,54]. For example, a simple addition product 56 to methyl vinyl ketone was obtained by the reaction of the heteroaromatic iodide 55[S5]. The corresponding bromide affords the usual insertion-elimination product. Saturated ketones are obtained cleanly by hydroarylation of o,/3l-unsaturated ketones with aryl halides in the presence of sodium formate, which hydrogenolyses the R—Pd—I intermediate to R— Pd—H[56]. Intramolecular hydroarylation is a useful reaction. The diiodide 57 reacts smoothly with sodium formate to give a model compound for the afla-toxin 58. (see Section 1.1.6)[57]. Use of triethylammonium formate and BU4NCI gives better results. [Pg.136]

Alkenes are commonly described as unsaturated hydrocarbons because they have the capacity to react with substances which add to them Alkanes on the other hand are said to be saturated hydrocarbons and are incapable of undergoing addition reactions... [Pg.230]

The condition defined by equation (8) is met by adjustment of (Qg(3)) nd (T(3)). The pressures at the second stripping flow inlet and that of the outlet for solute (C) must be made equal, or close to equal, to prevent cross-flow. Scott and Maggs [7] designed a three stage moving bed system, similar to that described above, to extract pure benzene from coal gas. Coal gas contains a range of saturated aliphatic hydrocarbons, alkenes, naphthenes and aromatics. In the above theory the saturated aliphatic hydrocarbons, alkenes and naphthenes are represented by solute (A). [Pg.437]

As in the alkanes, it is possible for carbon atoms to align themselves in different orders to form isomers. Not only is it possible for the carbon atoms to form branches which produce isomers, but it is also possible for the double bond to be situated between different carbon atoms in different compounds. This different position of the double bond also results in different structural formulas, which, of course, are isomers. Just as in the alkanes, isomers of the alkenes have different properties. The unsaturated hydrocarbons and their derivatives are more active chemically than the saturated hydrocarbons and their derivatives. [Pg.188]

The above discussions have concentrated on hydrocarbons, both saturated and unsaturated, with the unsaturated hydrocarbons containing only one multiple bond. The unsaturated hydrocarbons are the alkenes with one double bond and the alkynes... [Pg.191]

The first step in the reaction is adsorption of Pronto the catalyst surface. Complexation between catalyst and alkene then occurs as a vacant orbital on the metal interacts with the filled alkene tt orbital. In the final steps, hydrogen is inserted into the double bond and the saturated product diffuses away from the catalyst (Figure 7.7). The stereochemistry of hydrogenation is syn because both hydrogens add to the double bond from the same catalyst surface. [Pg.230]

Saturated (Section 3.2) A molecule that has only single bonds and thus can t undergo addition reactions.. Alkanes are saturated, but alkenes are unsaturated. [Pg.1250]


See other pages where Saturated alkenes is mentioned: [Pg.85]    [Pg.86]    [Pg.127]    [Pg.85]    [Pg.509]    [Pg.273]    [Pg.85]    [Pg.86]    [Pg.127]    [Pg.85]    [Pg.509]    [Pg.273]    [Pg.126]    [Pg.511]    [Pg.4]    [Pg.164]    [Pg.41]    [Pg.201]    [Pg.507]    [Pg.51]    [Pg.86]    [Pg.510]    [Pg.186]    [Pg.188]    [Pg.194]    [Pg.195]    [Pg.953]    [Pg.981]    [Pg.164]    [Pg.209]    [Pg.132]    [Pg.314]    [Pg.229]    [Pg.229]    [Pg.154]    [Pg.325]   


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