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Salts phenoxide

Pyridine-bound resins were also prepared and successfully employed as polymer-supported phase transfer catalysts in bromide displacement from 1-bromoalkanes by salt phenoxide or naphthoxide, even though the controlling factor (diffusivity or preferential sorption) for the observed substrate selectivity effects was difficult to determined.[133]... [Pg.188]

All esters are hydrolysed by sodium hydroxide to the alcohol (or sodium phenoxide) and the sodium salt of the acid from which they are derived. [Pg.355]

Treatment of phenyl esters, (See also p. 248.) The alkaline solu tion containing phenoxide and the sodium salt of the acid should now be worked up by the following method. [Pg.357]

B) If test in (A) ( ) is negative, an alcohol is absent and the residual solution must contain a Na phenoxide as well as the Na salt... [Pg.413]

Reaction with arenediazonium salts Adding a phe nol to a solution of a diazonium salt formed from a primary aromatic amine leads to formation of an azo compound The reaction is carried out at a pH such that a significant portion of the phenol is pres ent as its phenoxide ion The diazonium ion acts as an electrophile toward the strongly activated ring of the phenoxide ion... [Pg.1004]

After cleavage the reaction mass is a mixture of phenol, acetone, and a variety of other products such as cumylphenols, acetophenone, dimethyl-phenylcarbinol, a-methylstyrene, and hydroxyacetone. It may be neutralised with a sodium phenoxide solution (20) or other suitable base or ion-exchange resins. Process water may be added to facilitate removal of any inorganic salts. The product may then go through a separation and a wash stage, or go direcdy to a distillation tower. [Pg.96]

Solvent for Displacement Reactions. As the most polar of the common aprotic solvents, DMSO is a favored solvent for displacement reactions because of its high dielectric constant and because anions are less solvated in it (87). Rates for these reactions are sometimes a thousand times faster in DMSO than in alcohols. Suitable nucleophiles include acetyUde ion, alkoxide ion, hydroxide ion, azide ion, carbanions, carboxylate ions, cyanide ion, hahde ions, mercaptide ions, phenoxide ions, nitrite ions, and thiocyanate ions (31). Rates of displacement by amides or amines are also greater in DMSO than in alcohol or aqueous solutions. Dimethyl sulfoxide is used as the reaction solvent in the manufacture of high performance, polyaryl ether polymers by reaction of bis(4,4 -chlorophenyl) sulfone with the disodium salts of dihydroxyphenols, eg, bisphenol A or 4,4 -sulfonylbisphenol (88). These and related reactions are made more economical by efficient recycling of DMSO (89). Nucleophilic displacement of activated aromatic nitro groups with aryloxy anion in DMSO is a versatile and useful reaction for the synthesis of aromatic ethers and polyethers (90). [Pg.112]

Aromatic haUdes do not react easily with phenoxide ions to produce diaryl ethers unless the aromatic haUde is substituted with one or more electron-withdrawing groups, eg, nitro or carboxyl groups. The Ullmann reaction uses finely divided copper or copper salts to cataly2e the reaction of phenoxides with aromatic haUdes to give diaryl ethers. [Pg.426]

Cram has published several studies indicating that complexation of ammonium salts was greatly enhanced by using cyclic polyethers over the corresponding acyclic ones. These molecules were analogs of the binaphthyl systems under study and were generally prepared by phenoxide substitution on the appropriate tosylate. The approach is illustrated below in Eq. (7.9). ... [Pg.316]

Reduction of the sodium salt of equilenin 17-ethylene ketal with lithium, sodium or potassium in ammonia at —70° occurs predominantly in the B-ring, affording, after acid hydrolysis, equilin (29) in up to 76% yield (55% isolated). The preferential reduction of the B-ring reflects the relative, but not absolute, resistance to reduction conferred on the A-ring by the naphthoxide ion. Some A-ring reduction does compete kinetically with B-ring reduction, since the epimeric 3-hydroxyestra-5,7,9-trien-17-ones are the major reaction by-products. Simple phenoxide ions usually reduce slowly... [Pg.9]

Lithium metal in ammonia at high concentration (4 M), with an alcoholic proton donor, will reduce the benzene ring of a phenoxide ion. The lithium salt of estrone is reduced under such conditions in 95% yield to a mixture containing 77% of estr-5(10)-ene-3a,17i -diol and 23% of the derived 5(10)-dihydro derivative. [Pg.10]

Kinetic studies on 2-, 3-, and 4-chloro-l-methylpyridinium salts showed a 30 10 ratio of the reaction rates at 50° with 4-nitro-phenoxide ion in methanol. The activation energy for reaction at the 4-position is one kilocalorie lower ( 8-fold higher rate) than for reaction at the 2-position. The reversal in rates relative to the corresponding halopyridines is the result of a much higher entropy of activation for the 2-chloro compound. The 3-chloro compound has a favorable entropy of activation also, but the energy of activation is about 13 kcal higher than that of the isomers (cf. Table II and Section III, A, 2). [Pg.194]

A variant for the synthesis of diaryl ethers—e.g. diphenyl ether 9, where an aryl halide and a phenoxide are reacted in the presence of copper or a copper-(I) salt, is called the Ullmann ether synthesis. ... [Pg.293]

The product is almost exclusively sodium o-hydroxybenzoate (salicylate, 71) only traces of the p-isomer being obtained if, however, the reaction is carried out on potassium phenoxide the salt of the p-acid becomes the major product. It has been suggested that the preferential o-attack with sodium phenoxide may result from stabilisation of the T.S. (72) through chelation by NaP in the ion pair ... [Pg.291]

This is the most common route, the reagent being a metal compound/solvent combination. Typical conditions call for the metal salt (e.g., acetate) in a buffer system (e.g., NaOAc/AcOH) and a co-solvent such as chloroform. Generally the reaction mixture is refluxed until the metal complex spectrum (see Section 9.22.5.6 and Table 4) is fully developed. Metal acetylacetonates and metal phenoxides have also been employed. The topic has been reviewed in detail by Buchler,51 who has also summarized the history and classification of metal complexes of this series, and the mechanisms of metalation.52... [Pg.955]

Finally,- the alkali salts of phenol itself are more deeply coloured than is phenol. This fact cannot indeed be recognised subjectively, but investigation of the absorption of ultra-violet light demonstrates it. Thus it has been found that the absorption by sodium phenoxide much more nearly approaches the subjectively visible part of the spectrum than does that of the free phenol. The difference is so considerable that it provides also a satisfactory explanation of a subjectively perceptible deepening of colour from colourless to yellow. The colour of the salts of nitrophenols is therefore ascribed to the bathychromic (colour-deepening) efEect of salt-formation. [Pg.248]

Completely dry phenoxide is essential for the success of the experiment. It is convenient to ohoose a time for this such that the dried salt remains over night in the dish, in a vacuum desiooator over sulphuric acid and solid potassium hydroxide, before the synthesis is started next morning. [Pg.249]


See other pages where Salts phenoxide is mentioned: [Pg.997]    [Pg.283]    [Pg.359]    [Pg.426]    [Pg.794]    [Pg.505]    [Pg.4]    [Pg.206]    [Pg.267]    [Pg.729]    [Pg.1311]    [Pg.78]    [Pg.225]    [Pg.346]    [Pg.367]    [Pg.121]    [Pg.138]    [Pg.281]    [Pg.941]    [Pg.345]    [Pg.99]    [Pg.863]    [Pg.281]    [Pg.941]    [Pg.1052]    [Pg.185]    [Pg.307]    [Pg.1120]    [Pg.54]    [Pg.45]    [Pg.650]   
See also in sourсe #XX -- [ Pg.690 ]




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