Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Rotationally symmetrical component

Asymmetric Shear Forming Conventional shear forming is limited to production of rotationally symmetric components. To produce asymmetric components and therefore increase the range of shapes that can be produced by shear forming, four asymmetric configurations have been proposed. [Pg.1118]

A metal-forming process used for production of hollow, rotationally symmetric sheet metal components. To produce a component with a given shape and thickness distribution, the sheet is clamped to a rotating rigid mandrel and formed by a roller tracing the shape of the mandrel at a fixed distance. [Pg.1115]

Diamond machined optical components have conquered a huge market. They are needed for projection systems, displays, laser scanners, sensors, reflective tapes, scientific instruments, medical and defense equipment, laser beam guiding, and illumination systems exhibiting a multitude of different surfaces ranging from rotational symmetric aspheres to freeform and structured surfaces with Fresnel or prismatic elements (Table 3). Moreover, aspheric glass and plastic... [Pg.1283]

Fig. 6.7 Perspective drawing of a rotationally symmetric three-state ( triple ) conical intersection such as occurs, for example, at an accidental crossing of a doubly degenerate state with a nondegenerate state. The coordinates are the components of a doubly degenerate mode, causing a linear coupling between the electronic states... Fig. 6.7 Perspective drawing of a rotationally symmetric three-state ( triple ) conical intersection such as occurs, for example, at an accidental crossing of a doubly degenerate state with a nondegenerate state. The coordinates are the components of a doubly degenerate mode, causing a linear coupling between the electronic states...
The generally rotationally symmetrical mold, which gives the final component its shape, is called the mandrel. It is either directly or with the aid of special adapters fixed to the driving spindles of the winding system (three jaw chucks). Mandrels can be reusable (depending on the component geometry) or remain in the finished part as so-called lost cores . [Pg.264]

There are two contributions to the polarizability of a molecule the distortion of the electronic wave function and the distortion of the nuclear framework. The major contribution is from the electrons, and can be considered to be the sum of contributions from the individual electrons. The contributions of the inner-shell electrons are nearly independent of orientation and these contributions can be ignored. The polarizability of electrons in a bond parallel to the bond direction is different from the polarizability perpendicular to that bond. As a diatomic molecule or linear polyatomic molecule rotates, the components of the polarizability in fixed directions are modulated (fluctuate periodically) as the ellipsoid of polarizability rotates. The rotation of a diatomic or linear polyatomic molecule will be Raman active (produce a Raman spectram). In a nonlinear polyatomic molecule, the polarizabilities of the individual bonds add vectorially to make up the total polarizability. If the molecule is a symmetric top, the total polarizability is the same in all directions and the ellipsoid of polarizability is a sphere. A spherical top molecule has no rotational Raman spectmm. Symmetric tops and asymmetric tops have anisotropic polarizabilities and produce rotational Raman spectra. [Pg.987]

For an isotropic, poled polymer film of essentially one-dimensional NLO molecules, the orientational average is expressed in terms of the average angle between the ground-state dipole moments of the chromophores and the direction in the film they would be pointing if perfectly aligned (83). For a polymer film in which the nonlinear component or moiety is rotationally symmetric about the film normal (z-axis), the only two nonzero susceptibility components can be... [Pg.815]

For molecules that are non-linear and whose rotational wavefunctions are given in terms of the spherical or symmetric top functions D l,m,K, the dipole moment Pave can have components along any or all three of the molecule s internal coordinates (e.g., the three molecule-fixed coordinates that describe the orientation of the principal axes of the moment of inertia tensor). For a spherical top molecule, Pavel vanishes, so El transitions do not occur. [Pg.401]

Figure 5.5 The rotational angular momentum vector P for (a) a linear molecule and (b) the prolate symmetric rotor CH3I where is the component along the a axis... Figure 5.5 The rotational angular momentum vector P for (a) a linear molecule and (b) the prolate symmetric rotor CH3I where is the component along the a axis...
Figure 9.24 shows part of the laser Stark spectrum of the bent triatomic molecule FNO obtained with a CO infrared laser operating at 1837.430 cm All the transitions shown are Stark components of the rotational line of the Ig vibrational transition, where Vj is the N-F stretching vibration. The rotational symbolism is that for a symmetric rotor (to which FNO approximates) for which q implies that AA = 0, P implies that A/ = — 1 and the numbers indicate that K" = 7 and J" = 8 (see Section 6.2.4.2). In an electric field each J level is split into (J + 1) components (see Section 5.2.3), each specified by its value of Mj. The selection mle when the radiation is polarized perpendicular to the field (as here) is AMj = 1. Eight of the resulting Stark components are shown. [Pg.369]

Another generalization uses referential (material) symmetric Piola-Kirchhoff stress and Green strain tensors in place of the stress and strain tensors used in the small deformation theory. These tensors have components relative to a fixed reference configuration, and the theory of Section 5.2 carries over intact when small deformation quantities are replaced by their referential counterparts. The referential formulation has the advantage that tensor components do not change with relative rotation between the coordinate frame and the material, and it is relatively easy to construct specific constitutive functions for specific materials, even when they are anisotropic. [Pg.119]

To describe the velocity profile in laminar flow, let us consider a hemisphere of radius a, which is mounted on a cylindrical support as shown in Fig. 2 and is rotating in an otherwise undisturbed fluid about its symmetric axis. The fluid domain around the hemisphere may be specified by a set of spherical polar coordinates, r, 8, , where r is the radial distance from the center of the hemisphere, 0 is the meridional angle measured from the axis of rotation, and (j> is the azimuthal angle. The velocity components along the r, 8, and (j> directions, are designated by Vr, V9, and V. It is assumed that the fluid is incompressible with constant properties and the Reynolds number is sufficiently high to permit the application of boundary layer approximation [54], Under these conditions, the laminar boundary layer equations describing the steady-state axisymmetric fluid motion near the spherical surface may be written as ... [Pg.175]

Material like sapphire, which is a uniaxial crystal, does not show nonlinear fluorescence, and direct visualization of filaments is, consequently, not an option. However, the effect of rotation of plane polarization can also be probed in such materials by monitoring the spatial size of the white light disc, and of the spectrum of the super continuum that is produced. Figure 5.3 depicts some typical results obtained with 3 mm long sapphire crystals. The extent of the supercontinuum spectrum is seen to vary as a function of polarization angle. The supercontinuum spectrum has two components [39] symmetric broadening about the incident wavelength that is essentially ascribable to... [Pg.87]

Similar to the PIP, the Hamiltonian [Eq. (52a)] of a periodic pulse shows an infinite number of effective RF fields with both x and y components of the scaling factors X a and the phases 0na. The periodic pulse, however, acquires a different symmetry as that of the PIP. From Eq. (52c) and = ana, it follows that the scaling factor Xm, is symmetric in respect to the sideband number n, while the phase 6na is anti-symmetric according to Eq. (51c). These symmetries seem to be a coincidence arising from the mathematical derivations. As a matter of fact, they are the intrinsic natures of the periodic pulse. Considering the term f x i)Ix for instance, any Iy component created by the rotating field denoted by a> must be compensated at any time t by its counter-component oj n in order to reserve the amplitude modulated RF field. [Pg.24]

In addition, it is worth mentioning that, even in the case of a uniform distribution, the number of vectors oriented parallel to any given direction is small, so that pmax could be underestimated. Here we assumed that the rotational diffusion tensor is axially symmetric. The presence of a rhombic component could be identified by the shape of the distribution of the values of p (see e.g. Refs. [55, 57]). [Pg.297]


See other pages where Rotationally symmetrical component is mentioned: [Pg.264]    [Pg.264]    [Pg.264]    [Pg.264]    [Pg.98]    [Pg.42]    [Pg.303]    [Pg.84]    [Pg.38]    [Pg.7]    [Pg.394]    [Pg.107]    [Pg.165]    [Pg.114]    [Pg.471]    [Pg.615]    [Pg.1134]    [Pg.577]    [Pg.577]    [Pg.604]    [Pg.113]    [Pg.726]    [Pg.75]    [Pg.143]    [Pg.224]    [Pg.117]    [Pg.27]    [Pg.473]    [Pg.685]    [Pg.685]    [Pg.712]    [Pg.118]    [Pg.120]    [Pg.216]    [Pg.294]    [Pg.162]   
See also in sourсe #XX -- [ Pg.238 ]




SEARCH



Rotational components

© 2024 chempedia.info