Orientation relationships

Greenhalgh, L., Gilkey, R. (1993). The effect of relationship orientation on negotiators cognitions and tactics. Group Decision and Negotiation, 2, 167-183. 

Fiedler s contingency theory shows the relationship between the leader s orientation or style and group performance under different situational conditions. Fiedler found that task oriented leaders were more effective in low and moderate control situations and relationship oriented managers were more effective in moderate control situations (http //www.valuebasedmanagement.net/methods contingen-cy theory.html visited on 25 Sept 2010). 

These problems must be resolved as partners move forward together with a CPFR effort. The emphasis must be placed on putting aside the adversarial relationships oriented around getting the best price and terms, and focusing on best total costs in the network with the highest customer satisfaction ratings — not easy conditions for most companies and industries. 

Collaborative The norms, beliefs and underlying culture values with relationship orientation... 

Other person. It has also been called relationship-oriented, charismatic, or inspirational leadership. A transformational leader s role is to inspire others to go above and beyond their mere self-interest of the moment. 

There has been considerable elaboration of the simple Girifalco and Good relationship, Eq. XII-22. As noted in Sections IV-2A and X-6B, the surface ftee energies that appear under the square root sign may be supposed to be expressible as a sum of dispersion, polar, and so on, components. This type of approach has been developed by Dann [70] and Kaelble [71] as well as by Schonhom and co-workers (see Ref. 72). Good (see Ref. 73) has preferred to introduce polar interactions into a detailed analysis of the meaning of in Eq. IV-7. While there is no doubt that polar interactions are important, these are orientation dependent and hence structure sensitive. 

Dahmen U 1982 Orientation relationships in precipitation systems Acfa Metall. 30 63... 

Here the ijk coordinate system represents the laboratory reference frame the primed coordinate system i j k corresponds to coordinates in the molecular system. The quantities Tj, are the matrices describing the coordinate transfomiation between the molecular and laboratory systems. In this relationship, we have neglected local-field effects and expressed the in a fomi equivalent to simnning the molecular response over all the molecules in a unit surface area (with surface density N. (For simplicity, we have omitted any contribution to not attributable to the dipolar response of the molecules. In many cases, however, it is important to measure and account for the background nonlinear response not arising from the dipolar contributions from the molecules of interest.) In equation B 1.5.44, we allow for a distribution of molecular orientations and have denoted by () the corresponding ensemble average ... 

The susceptibility tensors give the correct relationship for the macroscopic material. For individual molecules, the polarizability a, hyperpolarizability P, and second hyperpolarizability y, can be defined they are also tensor quantities. The susceptibility tensors are weighted averages of the molecular values, where the weight accounts for molecular orientation. The obvious correspondence is correct, meaning that is a linear combination of a values, is a linear combination of P values, and so on. 

The most notable studies are those of Ingold, on the orienting and activating properties of substituents in the benzene nucleus, and of Dewar on the reactivities of an extensive series of polynuclear aromatic and related compounds ( 5.3.2). The former work was seminal in the foundation of the qualitative electronic theory of the relationship between structure and reactivity, and the latter is the most celebrated example of the more quantitative approaches to the same relationship ( 7.2.3). Both of the series of investigations employed the competitive method, and were not concerned with the kinetics of reaction. 

It is the purpose of this and the following chapter to report the quantitative data concerning the relationship of structure to orientation and reactivity in aromatic nitration. Where data obtained by modern analytical methods are available they are usually quoted in preference to the results of older work. Many of the papers containing the latter are, however, noted in the brief discussion which is given of interpretations of the results. 

Sometimes the orientation of two substituents m an aromatic compound precludes Its straightforward synthesis m Chloroethylbenzene for example has two ortho para directing groups m a meta relationship and so can t be prepared either from chloroben zene or ethylbenzene In cases such as this we couple electrophilic aromatic substitution with functional group manipulation to produce the desired compound... 

Some object-oriented systems also support the notion of subobjects. This faciUtates the representation of stmctural relationships. For example, the objects IMPELLER and LINING can be made subobjects of a REACTOR object, to represent the stmctural components of the reactor. 

An example of research in the micromechanics of shock compression of solids is the study of rate-dependent plasticity and its relationship to crystal structure, crystal orientation, and the fundamental unit of plasticity, the dislocation. The majority of data on high-rate plastic flow in shock-compressed solids is in the form of ... 

Biological membranes provide the essential barrier between cells and the organelles of which cells are composed. Cellular membranes are complicated extensive biomolecular sheetlike structures, mostly fonned by lipid molecules held together by cooperative nonco-valent interactions. A membrane is not a static structure, but rather a complex dynamical two-dimensional liquid crystalline fluid mosaic of oriented proteins and lipids. A number of experimental approaches can be used to investigate and characterize biological membranes. However, the complexity of membranes is such that experimental data remain very difficult to interpret at the microscopic level. In recent years, computational studies of membranes based on detailed atomic models, as summarized in Chapter 21, have greatly increased the ability to interpret experimental data, yielding a much-improved picture of the structure and dynamics of lipid bilayers and the relationship of those properties to membrane function [21]. 

In addition to the reciprocal relationship between the helix pitch and layer line spacing, Figure 18.14 illustrates the reciprocal relationship between the orientation of the arms of the cross and the angle of climb of the helix as the helix becomes steeper the arms of the cross become more horizontal. 

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