Reformulated gasolines evaporative emissions

Public concerns about air quality led to the passage of the Clean Air Act in 1970 to amendments to that act in 1977 and 1990. The 1990 amendments contained seven separate titles covering different regula-toiy programs and include requirements to install more advanced pollution control equipment and make other changes in industrial operations to reduce emissions of air pollutants. The 1990 amendments address sulfur dioxide emissions and acid rain deposition, nitrous oxide emissions, ground-level ozone, carbon monoxide emissions, particulate emissions, tail pipe emissions, evaporative emissions, reformulated gasoline, clean-fueled vehicles and fleets, hazardous air pollutants, solid waste incineration, and accidental chemical releases. 

Because CNG is primarily methane, it is expected to have relatively low reactivity, with the small amounts of reactive impurities such as small olefins and alkanes being responsible for most of its reactivity (see Table 16.14). Emissions of CO are smaller than from gasoline-powered vehicles, while the effect on NOx emissions is not clear (National Research Council, 1991). As seen in Tables 16.10 and 16.11, CNG shows the highest promise for low-reactivity exhaust emissions, and this appears to be the case for its use in real vehicles (Gabele, 1995). Figure 16.40, for example, shows the estimated ozone production per mile traveled for a vehicle fueled on CNG compared to vehicles fueled on reformulated gasoline (RFG) or the alcohol fuels M85 or E85 (vide infra). These measurements and estimates based on them include the contributions from both exhaust (including CO) and evaporative emissions (Black et al., 1998). Clearly, the reactivity of the CNG-powered vehicle emissions was substantially smaller than for the other vehicle-fuel combinations. 

In the United States, measures to control the levels of automobile emissions and therefore of photochemical smog have become sophisticated since the first federal Clean Air Act of 1967. Modifications to the ICE have been extensive and included various redesigns of the combustion chamber, variations in the air-to-fuel ratio, reformulations of the composition of gasoline, the addition of the positive crankcase ventilation (PCV) valve to recirculate exhaust and underoxidized fuel gases through the combustion chambers, and the addition of carbon canisters that temporarily collect and then recirculate evaporated fuel from the gas tank and the fuel system. Some of these modifications have not always worked out as well as envisioned. For example, the 1990 modification to the Clean Air Act called for the addition of oxygenated... 

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