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Recovery of structure

Remesh. Enables the recovery of structure value when the mesh has become thin... [Pg.607]

It is well known that polymer melts exhibit thixotropic behavior, i.e, reversible structural break down with flow. This means that an opportunity exists to take advantage of this reduction in resistance to flow to process polymers with less expenditure of energy. Current studies of the time dependence of recovery of structure from previous shearing indicate that rather long times, up to ten minutes, are available before complete recovery . Ap-... [Pg.147]

VRML has been found to be a very useful visualization format for chemistry. The only major disadvantage is that VRML files do not contain easily recognizable structures, only balls, cylinders, and triangle strips. The automatic recovery of structure data from these files suitable for further processing is difficult, but has been performed,An increasing number of computational chemistry programs add VRML output support in order to make their visualizations usable for WWW presentation, especially in the context of electronic publishing. More about this topic can be read in Internet-based Computational Chemistry Tools in this encyclopedia. [Pg.1421]

For those gels in which shear thinning occurs (ALSP 1-3%), the process can be reversed by either the removal or the reduction of the shem-strain rate. That is, the breakdown process is reversible. Each point on the non-linear zone of the flow curve corresponds to a state of dynamic equilibrium between processes of deformation and recovery of structure of the matrix. The situation can be represented by the following equation ... [Pg.195]

Protein tertiary structure is also influenced by the environment In water a globu lar protein usually adopts a shape that places its hydrophobic groups toward the interior with Its polar groups on the surface where they are solvated by water molecules About 65% of the mass of most cells is water and the proteins present m cells are said to be m their native state—the tertiary structure m which they express their biological activ ity When the tertiary structure of a protein is disrupted by adding substances that cause the protein chain to unfold the protein becomes denatured and loses most if not all of Its activity Evidence that supports the view that the tertiary structure is dictated by the primary structure includes experiments m which proteins are denatured and allowed to stand whereupon they are observed to spontaneously readopt their native state confer matron with full recovery of biological activity... [Pg.1146]

Many of the most important naturally occurring minerals and ores of the metallic elements are sulfides (p. 648), and the recovery of metals from these ores is of major importance. Other metal sulfides, though they do not occur in nature, can be synthesized by a variety of preparative methods, and many have important physical or chemical properties which have led to their industrial production. Again, the solubility relations of metal sulfides in aqueous solution form the basis of the most widely used scheme of elementary qualitative analysis. These various more general considerations will be briefly discussed before the systematic structural chemistry of metal sulfides is summarized. [Pg.676]

In this solvent the reaction is catalyzed by small amounts of trimethyl-amine and especially pyridine (cf. 9). The same effect occurs in the reaction of iV -methylaniline with 2-iV -methylanilino-4,6-dichloro-s-triazine. In benzene solution, the amine hydrochloride is so insoluble that the reaction could be followed by recovery. of the salt. However, this precluded study mider Bitter and Zollinger s conditions of catalysis by strong mineral acids in the sense of Banks (acid-base pre-equilibrium in solution). Instead, a new catalytic effect was revealed when the influence of organic acids was tested. This was assumed to depend on the bifunctional character of these catalysts, which act as both a proton donor and an acceptor in the transition state. In striking agreement with this conclusion, a-pyridone is very reactive and o-nitrophenol is not. Furthermore, since neither y-pyridone nor -nitrophenol are active, the structure of the catalyst must meet the conformational requirements for a cyclic transition state. Probably a concerted process involving structure 10 in the rate-determining step... [Pg.300]

In previous works [18-20,23,102] water-soluble polymers such as polyacrylamide (pAM), polysodium acrylate (pAA Na), poly(acrylamide-sodium acrylate) (pAM-AA Na), poly(acrylamide-diallyethylamine-hy-drochloride) (pAM-DAEA-HCl), and poly(acrylamide-sodium acrylate-diallyethylamine-hydrochloride) (pAM-AANa-DAEA-HCl) were used in the recovery of cations and some radioactive isotopes from aqueous solutions. It was found that the floe is formed between the added polymer and ions of the solution in the flocculation process with the formation of a crosslinked structure. The formed cross-linked structure is characterized by [103-105] ... [Pg.128]

OUTLINE OF STRUCTURAL METALLURGY RELEVANT TO CORROSION Annealing Recovery and Recrysta/ffsation... [Pg.1268]

Denaturation is accompanied by changes in both physical and biological properties. Solubility is drastically decreased, as occurs when egg white is cooked and the albumins unfold and coagulate. Most enzymes also lose all catalytic activity when denatured, since a precisely defined tertiary structure is required for their action. Although most denaturation is irreversible, some cases are known where spontaneous renaturation of an unfolded protein to its stable tertiary structure occurs. Renaturation is accompanied by a full recovery of biological activity. [Pg.1040]

From the foregoing it is clear that indentation anisotropy is a consequence of high molecular orientation within highly oriented fibrils and microfibrils coupled with a preferential local elastic recovery of these rigid structures. We wish to show next that the influence of crystal thickness on AMH is negligible. The latter quantity is independent on 1 and is only correlated to the number of tie molecules and inter-crystalline bridges of the oriented molecular network. [Pg.141]

Resilin and elastin, unlike other structural proteins, fulfill both definitions of an elastic material. Colloquially speaking, resilin and elastin are stretchy or flexible. They also fulfill the strict definition of an elastic material, i.e., the ability to deform in proportion to the magnitude of an applied stress without a loss of energy, and the recovery of the material to its original state when that stress is removed. Resilin and elastin are alone in the category of structural proteins (e.g., collagen, silk, etc.) in that they have the correct blend of physical properties that allow the proteins to fulfill both definitions of elasticity. Both proteins have high extensibility and combine that property with remarkable resilience [208]. [Pg.100]

The concept of minimum AE and maximum Emw is illustrated with the generalized sequence shown in Scheme 4.7 under stoichiometric conditions with complete recovery of reaction solvents, catalysts, and post-reaction materials. Markush structures are used to show both variable R groups and necessarily invariant atoms. This analysis is useful in studying combinatorial hbraries where a constant scaffold structure is selected and then is decorated with, in principle, an unlimited number of possible R groups. [Pg.90]

The basic aim of PEC applications in clinical chemistry, apart from the recovery of standards of endogenous substances, consists of structural identification of isolated (without further separation) substances of relatively high purity. Therefore, the majority of works devoted to this topic pertain to semipreparative separation. Obtaining low amounts of analytes, achieved by coupling TEC with modem... [Pg.198]

Solvent recovery is fast and complete, with minimal residue in product. Collapse of structure due to capillary forces is prevented during solvent removal. [Pg.14]


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See also in sourсe #XX -- [ Pg.151 ]




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Structural recovery

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