Radioactive emissions gamma rays

The fifth type of radioactive emission, gamma radiation, does not result in a change in the properties of the atoms. As a result, they are usually omitted from nuclear equations. Gamma emissions often accompany other alpha or beta reactions—any decay that has an excess of energy that is released. For example, when a positron collides with an electron, two gamma rays are emitted, a phenomenon usually referred to as annihilation radiation. 

This is the last chapter in Part I of the general chemistry review. In this chapter, we will discuss the different aspects of radioactivity. Radioactivity is a nuclear phenomenon. It results from natural nuclear instability or externally induced nuclear instability. We will limit our discussion of nuclear chemistry to the basic aspects of radioactivity involving radioactive emissions such as alpha emission, beta emission, gamma rays, positron emission, and electron capture. We will also review other ideas such as the half-lives of radioactive substances and the mass-energy equation. 

The most important types of radioactive particles are alpha particles, beta particles, gamma rays, and X-rays. An alpha particle, which is symbolized as a, is equivalent to a helium nucleus, fHe. Thus, emission of an alpha particle results in a new isotope whose atomic number and atomic mass number are, respectively, 2 and 4 less than that for the unstable parent isotope. 

Neutron Activation Analysis Few samples of interest are naturally radioactive. For many elements, however, radioactivity may be induced by irradiating the sample with neutrons in a process called neutron activation analysis (NAA). The radioactive element formed by neutron activation decays to a stable isotope by emitting gamma rays and, if necessary, other nuclear particles. The rate of gamma-ray emission is proportional to the analyte s initial concentration in the sample. For example, when a sample containing nonradioactive 13AI is placed in a nuclear reactor and irradiated with neutrons, the following nuclear reaction results. 

Gamma ray The shortest wavelength and highest energy type of all electromagnetic radiation. It originates in the nucleus of radioactive isotopes along with alpha particle, beta particle, or neutron emissions. 

Radioactive transformations are accomplished by several different mechanisms, most importantly alpha ptirticle, beta particle, tuid gamma ray emissions, Each of tliese mechanisms are sponuuieous nuclear transformations. The result of these transformations is tlie formation of different tuid more stable elements. 

Several different mechanisms, most importtuitly alplia particle, beta particle, and gamma ray emissions accomplish radioactive transformations. Each of these mechanisms is a spontaneous nuclear transformation. Tlie result of tliese transformations is the formation of different stable elements. Tlie kind of transformation that will ttike place for any given radioactive element is a function of the type of nuclear inslabilitv as well as the mass/energy relationship. The nuclear instability is dependent on the ratio of neutrons to... 

The nuclear reactor also must be shielded against the emission of radioactive material to the external environment. Suitable radiation controls include both thermal and biological shielding systems. Radiation from alpha particles (a rays) and beta particles ((3 rays) has little penetrating power, but gamma rays have deep penetration properties. Neutron radiation is, however, the primary area of risk. Typically, extremely thick concrete walls are used as a neutron absorber, but lead-lined concrete and special concretes are also used. 

The origin of the rays was initially a mystery, because the existence of the atomic nucleus was unknown at the time. However, in 1898, Ernest Rutherford took the first step to discover their origin when he identified three different types of radioactivity by observing the effect of electric fields on radioactive emissions (Fig. 17.4). Rutherford called the three types a (alpha), (3 (beta), and y (gamma) radiation. 

The numerical combination of protons and neutrons in most nuclides is such that the nucleus is quantum mechanically stable and the atom is said to be stable, i.e., not radioactive however, if there are too few or too many neutrons, the nucleus is unstable and the atom is said to be radioactive. Unstable nuclides undergo radioactive transformation, a process in which a neutron or proton converts into the other and a beta particle is emitted, or else an alpha particle is emitted. Each type of decay is typically accompanied by the emission of gamma rays. These unstable atoms are called radionuclides their emissions are called ionizing radiation and the whole property is called radioactivity. Transformation or decay results in the formation of new nuclides some of which may themselves be radionuclides, while others are stable nuclides. This series of transformations is called the decay chain of the radionuclide. The first radionuclide in the chain is called the parent the subsequent products of the transformation are called progeny, daughters, or decay products. 

Radioactive isotopes that decay by the emission of alpha or beta radiation undergo a change in the nature of their nuclei and are converted into isotopes of other elements. The emission of gamma rays, on the other hand, does not change the nature of the nuclei of the radioisotopes from which the rays are emitted. Gamma rays are a form of dissipation of nuclear energy. 

Some radioisotopes decay emitting only gamma rays, but many do so by the concurrent emission of beta and gamma radiation. The rate at which radiation is emitted from the nuclei of different radioisotopes varies considerably. Each radioisotope has a unique form of decay that is characterized by its half-life (tV2), the time it takes for the radioactivity of the radioisotope to decrease by one-half of its original value (see Textbox 14). 

The common type of radioactive emission that does not consist of matter is the gamma ray. 

RADIOACTIVE DECAY. Many atomic nuclei have unstable neutron-to-proton ratios and undergo spontaneous first-order decay through the emission of a, I3, or (3 particles or gamma rays. 

Man-made radioactive atoms are produced either as a by-product of fission of uranium atoms in a nuclear reactor or by bombarding stable atoms with particles, such as neutrons, directed at the stable atoms with high velocity. These artificially produced radioactive elements usually decay by emission of particles, such as positive or negative beta particles and one or more high energy photons (gamma rays). Unstable (radioactive) atoms of any element can be produced. 

Three main forms of radioactive decay involve the emission of alpha particles, beta particles, and gamma rays. An alpha particle is equivalent to the nucleus of a helium atom. Beta particles are nothing more than electrons. Gamma rays are a form of electromagnetic radiation. 

Although the nucleus is normally found in its lowest energy state, it may be produced as the result of a nuclear reaction, or tlirougli radioactivity in a number of excited states whose detailed properties may differ quite markedly from the lowest state, if formed in an excited state, it will decay, normally by the emission of electromagnetic radiation (gamma rays) lo the lowest state, or by the emission of particles to another nucleus. 

Decay. The diminution of a radioactive substance due to nuclear emission of alpha or beta particles, gamma rays or positrons. 

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