Quartz monitor

The samples have been prepared by e-beam evaporation of a dielectric layer followed by thermal evaporation of the silver fraction, which builds the island film, while the sandwich is completed by a further dielectric film. In every sample, intentionally the same amount of silver (corresponding to an average thickness of 4 nm, as recorded by quartz monitoring) has been embedded in a 6 nm thick dielectric film, formed from either Mgp2, LaFs, Si02, or AI2O3. The optical transmittance T and reflectance R of all films have been measured by a Perkin Elmer Lambda 19 spectrophotometer. To correlate the optical properties with the sample morphology, transmission electron microscopy (TEM) has been applied. 

J. Krim, C. Daly, Quartz Monitors and Microbalances, in D.A. Glocker, S.I. Shah (Eds.) Handbook of Thin Film Process Technology, vol. 1, Taylor Francis, 2002, Section D4.0. 

Acoustic Wave Sensors. Another emerging physical transduction technique involves the use of acoustic waves to detect the accumulation of species in or on a chemically sensitive film. This technique originated with the use of quartz resonators excited into thickness-shear resonance to monitor vacuum deposition of metals (11). The device is operated in an oscillator configuration. Changes in resonant frequency are simply related to the areal mass density accumulated on the crystal face. These sensors, often referred to as quartz crystal microbalances (QCMs), have been coated with chemically sensitive films to produce gas and vapor detectors (12), and have been operated in solution as Hquid-phase microbalances (13). A dual QCM that has one smooth surface and one textured surface can be used to measure both the density and viscosity of many Hquids in real time (14). 

Sample preparation is straightforward for a scattering process such as Raman spectroscopy. Sample containers can be of glass or quartz, which are weak Raman scatterers, and aqueous solutions pose no problems. Raman microprobes have a spatial resolution of - 1 //m, much better than the diffraction limit imposed on ir microscopes (213). Eiber-optic probes can be used in process monitoring (214). 

Experimental studies within the elastic range have been performed on monocrystalline AI2O3 (sapphire) and the nonpiezoelectric z-cut of quartz. Experiments are performed with a circuit devised by Ingram [68G05] in which a low-loss coaxial cable is used for both application of the potential and monitoring the current. As shown in Fig. 4.7, at an applied potential difference of a few kilovolts, a current of about 1 mA is produced at a compression of several percent. 

Fig. 11. Photograph of the four-electrode, vacuum flange and dual, quartz crystal, microbalance assembly, (A) side view, and (B) front view, used for mixed Cr atom. Mo atom matrix depositions with simultaneous monitoring of the individual metal flows. (The resolution of the microbalance is 10 g) (113).

Light Stability of Chlorinated Dibenzo-l -dioxins. A known concentration of chlorinated dibenzo-p-dioxin was placed in a quartz 1-cm path length cell. A General Electric R.S. sunlamp was placed either 0.5 or 1.0 meters from the face of the cell. The stability of the chlorinated dibenzo-p-dioxin was monitored using ultraviolet spectroscopy. 

The aim of the study was to check this possibility. A quartz nanobalance was chosen as a sensitive tool (Sauerbrey 1964). The device allows monitoring of the mass attached to the surface of quartz oscillators (Facci et al. 1993). The method is simple, cheap, and sensitive (as it should be for practical applications) and allows one to make parallel measurements in different media, also permitting a differential scheme of measurements. 

The catalysts were tested for their CO oxidation activity in an automated microreactor apparatus. The catalysts were tested at space velocities of 7,000 -60,000 hr . A small quantity of catalyst (typically 0.1 - 0.5 g.) was supported on a frit in a quartz microreactor. The composition of the gases to the inlet of the reactor was controlled by mass flow controllers and was CO = 50 ppm, CO2 = 0, or 7,000 ppm, HjO = 40% relative humidity (at 25°C), balance air. These conditions are typical of conditions found in spacecraft cabin atmospheres. The temperature of the catalyst bed was measured with a thermocouple placed half way into the catalyst bed, and controlled using a temperature controller. The inlet and outlet CO/CO2 concentrations were measured by non-dispersive infrared (NDIR) monitors. 

In the case of Ni(OH)2 and conductive polymer electrodes, solvent and anions intercalate into the electrode at anodic potentials. Electrochemical quartz crystal microbalance (EQCM) is a useful technique for monitoring the ingress and egress of solvent and anions in these materials. 

The most common filter pack material is quartz (silica). Quartz is relatively inert, readily available, and workable therefore, it is preferred to replace formation materials removed from the borehole. The grain size of the filter material (i.e., sand or gravel) should be chosen based on the characteristics of the formation to be monitored and the slot size of the screen. Sand and gravel are available in various uniform sizes to accommodate different monitoring environments. 

We used polycrystalline films of ZnO and Sn02 as adsorbents. The films were deposited from the water suspension of respective oxides on quartz substrates. These substrates contained initially sintered contacts made of platinum paste. The gap between contacts was of about lO" cm. All samples were initially heated in air during one hour at T 500 C. We used purified molecular oxygen an acceptor particle gas. H and Zn atoms as well as molecules of CO were used as donor particles. We monitored both the kinetics of the change of ohmic electric conductivity and the tangent of inclination angle of pre-relaxation VAC caused by adsorption of above gases and the dependence of stationary values of characteristics in question as functions of concentrations of active particles. 

Photolysis Procedure. The solvent-cleaned Kevlar-29 fabric swatch (2.5 cm x 18 cm) was placed around the outside quartz tube inside the photolysis chamber, which was subsequently evacuated, before - - 02 (99%) was introduced to 0.2 atm. The photolysis chamber was preheated to the specified photooxidation temperature, before the Hg-Xe lamp was turned on. The temperature, which was held constant in the chamber by adjusting the air flow around the lamp, was monitored by a thermocouple placed next to the fabric sample inside the chamber. After the photooxidation had continued for the specified... 

In the measurement technique, which has been used on D3 for many years, the ratio of the time spent counting with the cryoflipper in (+) or (-) mode is controlled by a quartz crystal controlled oscillator with a highly stable output frequency / of 1 MHz. There are two scalers to count the detector pulses (+ and - states), a single monitor scaler and a single time scaler used to end the measurement when the total time is reached (precision of 1 ms). 

Experiments were carried out in a U-type quartz reactor. The sample (0.025-0.2 g) was held between plugs of quartz wool and the temperature was monitored through a WET 4000 or Eurotherm 2408 temperature controllers. Reactant gases were fed from mass flow controllers (Brooks 5850TR). 

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