Propellant military

Nitrocellulose high performance gun propellant [military grade gunpowder double based)... 

Constituents. The military use a range of chemicals as explosives and propellants, which are sometimes termed "energetic molecules". 

Many compounds explode when triggered by a suitable stimulus however, most are either too sensitive or fail to meet cost and production-scale standards, requirements for safety in transportation, and storage stability. Propellants and explosives in large-scale use are based mosdy on a relatively small number of well-proven iagredients. Propellants and explosives for military systems are manufactured ia the United States primarily ia government owned plants where they are also loaded iato munitions. Composite propellants for large rockets are produced mainly by private iadustry, as are small arms propellants for sporting weapons. 

Military. The single-component explosives most commonly used for military compositions are TNT, RDX or HMX, nitrocellulose, and nitroglycerin. The last two are used almost exclusively to make propellants. The production volume of TNT far exceeds that of any other explosive. It is used as manufactured, as a base of biaary slurries with other high melting explosives, or ia ternary systems generally containing a biaary mix and aluminum. 

B. C. Pol and M. B. Ryan, Database Assessment of Pollution Control in the Military Explosives and Propellant Production Industry final report ORNL-22, Oak Ridge National Lab., Term., Feb. 1986. 

Black Powder. Black powder is mainly used as an igniter for nitrocellulose gun propellant, and to some extent in safety blasting fuse, delay fuses, and in firecrackers. Potassium nitrate black powder (74 wt %, 15.6 wt % carbon, 10.4 wt % sulfur) is used for military appHcations. The slower-burning, less cosdy, and more hygroscopic sodium nitrate black powder (71.0 wt %, 16.5 wt % carbon, 12.5 wt % sulfur) is used industrially. The reaction products of black powder are complex (Table 12) and change with the conditions of initia tion, confinement, and density. The reported thermochemical and performance characteristics vary greatly and depend on the source of material, its physical form, and the method of determination. Typical values are Hsted in Table 13. 

Propellants and Explosives. Hydrazine fuels include anhydrous hydrazine (AH), monomethyUiydrazine (MMH), and unsymmetrical dimethyUiydrazine (UDMH) for military and space programs. These compounds are used mainly as bipropeUant fuels, ie, with oxidizers, in rockets such as the Titan, MX missile, and the Ariane (UDA4H7X30. Using oxygen or fluorine as the oxidizer, hydrazine is exceeded only by hydrogen in specific impulse, ie, kilograms of thmst developed for each kilogram of fuel consumed per second (196). 

Explosives. Mercury, in the form of organic complexes, eg, mercury fulminate [628-86-4] has had long usage in explosives (see Explosives and propellants). In the United States all mercury for use in explosives is diverted to military uses. An explosive based on mercuric 5-nitrotetra2ole [60345-95-1] has been developed, but its use is on a small scale and in research and development only (3). 

Oxidizing Properties. Nitric acid is a powerful oxidizing agent (electron acceptor) that reacts violentiy with many organic materials (eg, turpentine, charcoal, and charred sawdust) (19,20). The concentrated acid may react explosively with ethanol (qv). Such oxidizing properties have had military appHcation nitric acid is used with certain organics, eg, furfuryl alcohol and aniline, as rocket propellant (see Explosives AND PROPELLANTS). 

Pyrotechnics have been used for military purposes for many centuries as propellants, explosive charges, time fuses, and for illumination. There are still many uses of pyrotechnic devices in military appHcations, where they provide portability, storage stability, simplicity of operation, safety, and the reUability required for military scenarios. The devices must be capable of surviving rough handling, weather extremes, and extended storage, yet reUably perform when called on to function. 

This low viscosity resin permits cure at low (70°C) temperatures and rapidly develops excellent elevated temperature properties. Used to increase heat resistance and cure speed of bisphenol A epoxy resins, it has utihty in such diverse appHcations as adhesives, tooling compounds, and laminating systems. A moleculady distilled version is used as a binder for soHd propellants (see Explosives and propellants) and for military flares (see Pyrotechnics). Its chief uses depend on properties of low viscosity and low temperature reactivity, particularly with carboxy-terminated mbbers. 

The advent of advanced fiber-reinforced composite materials has been called the biggest technical revolution since the jet engine [1-4], This claim is very striking because the tremendous impact of the jet engine on military aircraft performance is readily apparent. The impact on commercial aviation is even more striking because the airlines stwitched from propeller-driven planes to all-jet fleets within the span of just a few years because of superior performance and lower maintenance costs. 

See also Electric Power, Generation of Environmental Problems and Energy Use Explosives and Propellants Meitner, Lise Military Energy Use, Historical Aspects of Molecular Energy Nuclear Energy Nuclear Energy, Historical Evolution of the Use of Nuclear Fission Fuel Nuclear Fusion Nuclear Waste. 

Used tor modern solid propellant engines in military missiles, space launch vehicles and spacecraft. Pollutes environment by toxic exhaust. 

See also-. Aviation Fuel Batteries Engines Fuel Cells Fuel Cell Vehicles Military Energy Use, Historical Aspects of Rocket Propellants Storage Technology. 

Military Pyrotechnics Series, Part Three-Properties of Materials Used in Pyrotechnic Compositions , AMCP 706-187 (1963), 247 7) Anon, EngrDesHndbk, Solid Propellants,... 

Nobel s 704. See under British Military Explosives and Propellants in Vol 2, B301-R... 

Ontos. Designated as the M-50, this US Marine Corps system is a full-track self-propelled direct-fire and antitank weapon. It is aimed with six 106mm recoilless rifles, one. 30cal machine gun, and four. SOcal spotting rifles. It has a top speed of 40mph and a crew of three Ref J. Quick, Dictionary of Weapons and Military Terms , McGraw-Hill, NY (1973), 334... 

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