Processing, thermosets resin flow

Reinforced Thermoplastic Sheet. This process uses precombined sheets of thermoplastic resin and glass fiber reinforcement, cut into blanks to fit the weight and size requirements of the part to be molded. The blanks, preheated to a specified temperature, are loaded into the metal mold and the material flows under mol ding pressure to fiU the mold. The mold is kept closed under pressure until the temperature of the part has been reduced, the resin solidified, and demolding is possible. Cycle time, as with thermosetting resins, depends on the thickness of the part and the heat distortion temperature of the resin. Mol ding pressures are similar to SMC, 10—21 MPa (1500—3000 psi), depending on the size and complexity of the part. 

The cure of thermoset resins involves the transformation of a liquid resin, first with an increase in viscosity to a gel state (rubber consistency), and finally to a hard solid. In chemical terms, the liquid is a mixture of molecules that reacts and successively forms a solid network polymer. In practice the resin is catalyzed and mixed before it is injected into the mold thus, the curing process will be initialized at this point. The resin cure must therefore proceed in such a way that the curing reaction is slow or inhibited in a time period that is dictated by the mold fill time plus a safety factor otherwise, the increase in viscosity will reduce the resin flow rate and prevent a successful mold fill. On completion of the mold filling the rate of cure should ideally accelerate and reach a complete cure in a short time period. There are limitations, however, on how fast the curing can proceed set by the resin itself, and by heat transfer rates to and from the composite part. 

The fabrication of composite laminates having a thermosetting resin matrix is a complex process. It involves simultaneous heal, mass, and momentum transfer along with chemical reaction in a multiphase system with time-dependent material properties and boundary conditions. Two critical problems, which arise during production of thick structural laminates, are the occurrence of severely detrimental voids and gradients in resin concentration. In order to efficiently manufacture quality parts, on-line control and process optimization are necessary, which in turn require a realistic model of the entire process. In this article we review current progress toward developing accurate void and resin flow portions of this overall process model. 

Optimization of the cure cycle is inextricably linked to the design of processes for specific applications. Typically, this involves a clear understanding of the influence of temperature and time used to cure the thermosets. This is key to predicting resin flow and the degree of cure. Consequently, much attention has been placed on the curing process/morphology/ structure relationship of thermosets. " ... 

Hydrodynamics of "rheokinetic liquids is a theoretical basis for many production processes, namely, RIM-process, processing of items from thermosetting resins, molding of elastomers, plastisols, etc. It is important to note that different physicochemical processes are superimposed [1-3], first of all heat exchange and flow [4], because rheokinetic phenomena are always accompanied by heat output and occur under nonisothermal conditions. Then, it is necessary to allow for the possibility of crystallization of the product taking place [5, 6], etc. 

Rheology is the science of deformation and flow of matter. Essentially, all thermoplastic resins (and many thermosetting resins) are required to undergo flow in the molten state during the course of product manufacture. Important fabrication processes such as injection, extrusion, and calendering all involve the flow of molten polymers. In plastics fabrication, it is important to understand the effect, on melt viscosity, of such factors as temperature, pressure, rate of shear, molecular weight, and structure. It is also equally important to have reliable means of measuring viscous properties of materials. 

Thermoset based composite laminates are generally produced bj Autoclave/Vacuum Degassing Lamination Process (38, 39). The characteristics of this inocess are shown in Fig. IS. In this process, pr eg plies of desired shape are laid up in a prescribed orientation to form a laminate. The laminate is covered with successive layers of an absorbent material (glass bleeder fabric), a fluminated film to prevent sticking, and, finally, with a vacuum bag. The mitire system is placed upon a smooth metal tool surface into an autoclave, vacuum is a Ued to the bag and the temperature is increased at a constant rate in order to promote the resin flow and polymerization. The autoclave process will be used along this section as a case study to describe the influence of the matrix characteristics on the processing behavior of hi performance conqmsites. 

---