Processing chemical reactivity

Passive controls, process controls, 97-98 Paterson, New Jersey incident, 160-161 Peroxide formers, screening methods, 46-48 Physical processing chemical reactivity hazard, 8-10,11 screening methods, 36, 41—42 worked examples, 128,129 Polymerizing compounds, screening methods, 55... 

Adhesives and sealants are manufactured from a variety of polymers. Their selection and their combinations used impact solvent selection. Most solvent systems are designed to optimize the solubility of the primary polymer. Adhesives can be divided into ones which bond by chemical reaction and ones which bond due to physical processes. Chemically reactive adhesives are further divided into three more categories for those that bond through polymerization, polyaddition, or polycondensation. Physically bonding adhesives include pressure sensitive and contact adhesives, melt, or solution adhesives, and plastisols. Polymerization adhesives are composed of cyanoacrylates (no solvents), anaerobic adhesives (do not contain solvents but require primers for plastics and some metals which are solutions of copper naphthenate), UV-curable adhesives (solvent-free compositions of polyurethanes and epoxy), rubber modified adhesives (variety solvents discussed below). 

Because of the differences existing between the quality of different distillation cuts and those resulting from their downstream processing, it is useful to group them according to a major characteristic. That is, they are grouped into the three principal chemical families which constitute them paraffins, naphthenes and aromatics. From a molecular point of view, their chemical reactivities follow this order ... 

To an experienced operator trained in the handling of industrial chemicals, the dimers present Httle cause for concern in handling or storage. The finished polymer coating presents even less of a health problem contact with the reactive monomer is unlikely. In the ancillary operations, such as cleaning or adhesion promotion, the operator must observe suitable precautions. Before using the process chemicals, operators must read and understand the current Material Safety Data Sheets, which are available from the manufacturers. 

Pre-Production Handling. Salt-cured catde hides, when received at the tannery, are individually bundled to prevent excessive moisture loss. The bundles are tied with ropes that are later cut and removed the hides may be sorted for different weight or quaUty classification at this point. It is best to have hides of similar size and thickness in a given production batch to assure an even reactivity of the processing chemicals and to avoid frequent adjustments in the machinery to compensate for size and thickness variations. In the modem large tannery, the size/quaUty classification is not necessary because the hides arrive in carload quantities under specifications as to size, type, and month of slaughter. 

Chemical Reactivity Evaluation and Application to Process Design Preventing Human Error in Process Safety... 

Chlorendic anhydride is the common name of the Diels-Alder adduct of maleic anhydride and hexachlorocyclopentadiene, 3,4,5,6,7,7-hexachloroendomethylene-l,2,3,6-tetrahydrophthahc anhydride (HET). The resultant resins from HET contribute to the flame retardancy of the alkyd coatings. HET gives a greater reaction rate than phthaUc anhydride, to the extent that at 204—210°C the reaction rate approximates that of phthaUc anhydride at a temperature of 238°C (8). However, the resins tend to develop darker color, particularly at high processing temperature. Tetrachlorophthahc anhydride [117-08-8] made by conventional chlorination of phthaUc anhydride, would also impart flame retardancy to its alkyds. However, it is appreciably less soluble in the usual processing solvents than is phthaUc anhydride, and is reported to be of appreciably lower chemical reactivity (8). 

Behavior. Diffusion, Brownian motion, electrophoresis, osmosis, rheology, mechanics, and optical and electrical properties are among the general physical properties and phenomena that are primarily important in coUoidal systems (21,24—27). Of course, chemical reactivity and adsorption often play important, if not dominant, roles. Any physical and chemical feature may ultimately govern a specific industrial process and determine final product characteristics. 

Use reactor calorimetry testing to determine thermodynamics and kinetics of process. See Appendix 2A (Chemical reactivity hazards screening). 

Table A.4, taken from the CCPS Guidelines for Chemical Reactivity Evaluation and Application to Process Design, shows the questions which need to be asked regarding the safety of the proposed reaction, the data required to answer those questions and some selected methods of investigation. The experimental analysis is extremely specialized, and companies should consider outsourcing the tests if they do not have specialists in this area.

CCPS G-13. Guidelines for Chemical Reactivity Evaluation and Applications to Process Design. American Institute of Chemical Engineers, Center for Chemical Process Safety, New York. 

The rate at which an absorbed chemical species is removed from the ASL determines whether reenirainment occurs during a breaching cycle,Slow removal rates relative to the breathing cycle allow the concentrations in the ASL to be higher than in the expiratory airstream. Figure 5.26 shows processes that diminish the ASL concentration of absorbed chemical species. Metabolic processes or interactions with ions and other chemically reactive substances found... 

Many biological processes involve an "association" between two species in a step prior to some subsequent transformation. This association can take many forms. It can be a weak association of the attractive van der Waals type, or a stronger interaction such as a hydrogen bond. It can be an electrostatic attraction between a positively charged atom of one molecule and a negatively charged atom of another. Covalent bond formation between two species of complementary chemical reactivity represents an extreme kind of association. It often occurs in biological processes in which aldehydes or ketones react with amines via imine intermediates. 

As we saw in Chapter 19, chlorine represents the other extreme in chemical reactivity. Its most obvious chemical characteristic is its ability to acquire electrons to form negative chloride ions, and, in the process, to oxidize some other substance. Since the tendency to lose or gain electrons is a result of the details of the electronic structure of the atom, let us try to explain the chemistry of the third-row elements on this basis. 

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