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Process control, correlation function

However, Waite s approach has several shortcomings (first discussed by Kotomin and Kuzovkov [14, 15]). First of all, it contradicts a universal principle of statistical description itself the particle distribution functions (in particular, many-particle densities) have to be defined independently of the kinetic process, but it is only the physical process which determines the actual form of kinetic equations which are aimed to describe the system s time development. This means that when considering the diffusion-controlled particle recombination (there is no source), the actual mechanism of how particles were created - whether or not correlated in geminate pairs - is not important these are concentrations and joint densities which uniquely determine the decay kinetics. Moreover, even the knowledge of the coordinates of all the particles involved in the reaction (which permits us to find an infinite hierarchy of correlation functions = 2,...,oo, and thus is... [Pg.180]

Lotka-Volterra model reveals different kind of autowave processes with the non-monotonous behaviour of the correlation functions accompanied by their great spatial gradients and rapid change in time. Due to this fact the space increment Ar time increment At was variable to ensure that the relative change of any variable in the kinetic equations does not exceed a given small value. The difference schemes described above were absolutely stable and a choice of coordinate and time mesh was controlled by additional calculations with reduced mesh. [Pg.482]

Process parameters are the type of unit operations (e.g. precipitation), their interaction in the process, process conditions under which the unit operations are operated (e.g. temperature, pressure, flow rates, etc.) and the materials processed. The structure-property as well as the process-structure correlations must be known in order to run a process successfully and achieve the desired goal, i.e. to produce well-defined product properties. In this paper, we show how the property function, i.e. the state of aggregation can be controlled by surface forces of the particles. [Pg.245]

The persistence implies that long time intervals in which the process does not jump between states on and off, control the asymptotic behavior of the correlation function. The factor P+, which is controlled by the amplitude ratio A+/A-, determines the expected short and long time t behaviors of the correlation function, namely C(oo, 0) = lim oo (7(f)/(f + 0)) = P+ and C(oo,oc) = lim oo(7(f)/(f + oo)) = (P+)2. In slightly more detail the two limiting behaviors are... [Pg.342]

Alternatively, one may calculates S(t) itself systematically using controlled approximations. Calculating a correlation function for large systems has a long history in chemical physics [25], including recent applications to VER processes in liquid [26,27]. The vibrational self-consistent field (VSCF) method [28] will also be useful in this respect. [Pg.186]

If a system is uniformly hyperbolic, every point in phase space has both stable and unstable directions, and the maximum Lyapunov exponent with respect the maximum entropy measure is positive. The system has the mixing property and is therefore ergodic. The correlation function of observables also shows exponential decay. Uniformly hyperbolicity, which is sometimes rephrased as strong chaos in physical literature, is a well-established class of systems and is controllable by means of many mathematical tools [15]. In hyperbolic systems, there are no sources to make the relaxation process slow. [Pg.379]

Up to the present time it has not been possible to demonstrate the ultimate reliability of characterizations based on random disturbances. However, the use of random disturbances offers great potential advantage in studying existing process control systems where upsets like step disturbances cannot be tolerated. Because of the extensive calculation required to reduce the random operating records to statistical-correlation functions, high speed digital computation is essential in this treatment. [Pg.51]


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See also in sourсe #XX -- [ Pg.307 ]




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