Power feasibility

Zumsteg ZS, Kemere C, O DriscoU S, Santhanam G, Ahmed RE, Shenoy KV, et al. (2005) Power feasibility of implantable digital spike sorting circuits for neural prosthetic systems. IEEE Trans Neural Syst Rehabil Eng 13(3) 272-279, Sep. 2005. 

Amines are powerful nucleophiles which react under neutral or slightly basic conditions with several electron-accepting carbon reagents. The reaction of alkyl halides with amines is useful for the preparation of tertiary amines or quaternary ammonium salts. The conversion of primary amines into secondary amines is usually not feasible since the secondary amine tends towards further alkylation. 

Combinatorial. Combinatorial methods express the synthesis problem as a traditional optimization problem which can only be solved using powerful techniques that have been known for some time. These may use total network cost direcdy as an objective function but do not exploit the special characteristics of heat-exchange networks in obtaining a solution. Much of the early work in heat-exchange network synthesis was based on exhaustive search or combinatorial development of networks. This work has not proven useful because for only a typical ten-process-stream example problem the alternative sets of feasible matches are cal.55 x 10 without stream spHtting. 

The remaining class depicted in Figure 2 is that of soHd-state devices, ie, transistors, various types of semiconductor diode amplifiers, etc. At frequencies below 1 GHz, generation of hundreds or even at the lower frequencies, kilowatts, is feasible by soHd state. Above 1 GHz power capabiHty of soHd-state sources drops. Development of efficient (- 50%) sources at about the 50 W level at S-band (2 GHz) has been demonstrated. It is reasonable to expect soHd-state sources to replace tubes for low frequency and low (<100 W) power appHcations (52). For high power or high frequency, however, tube sources should continue to prevail. 

The physical form of the thermocouples varies significantly according to appHcations. Most spacecraft power suppHes utilize separate thermocouples that can be checked for performance at successive stages of manufacturing and be replaced if necessary. This approach fits in very well with the extremely high rehabihty requirements imposed on such systems. In terrestrial systems where such individualized attention is not economically feasible, modular assembhes are generally used, which can contain tens to hundreds of couples in a single unit. 

Basic to establishing whether power recovery is even feasible, let alone economical, are considerations of the flowing-fluid capacity available, the differential pressure available for the power recovery, and corrosive or erosive properties of the fluid stream. A further important consideration in feasibihty and economics is the probable physical location, with respect to each other, of fluid source, power-production point, and final fluid destination. In general, the tendency has been to locate the power-recoveiy driver and its driven unit where dictated by the driven-unit requirement and pipe the power-recoveiy fluid to and away from the driver. While early installations were in noncorrosive, nonerosive services such as rich-hydrocarbon absorption oil, the trend has been to put units into mildly severe seiwices such as amine plants, hot-carbonate units, and hydrocracker letdown. 

Much attention is also being given to solar energy. It does not appear that direct solar heat is economically feasible as a large power plant energy source however, this resource has great potential for a number of process and heating applications. 

Turbine startup feasible for power recovery strings... 

Not only the buildings themselves, but an allowance for equipment and stocks within the buildings must be included in the cost estimates, such as maintenance shop power equipment, control laboratory analytical equipment and reagents and, largest of all, the thousands of warehouse equipment spares, fittings, and supplies. For feasibility cost estimates, such items are factored from experience. 

In recent years there has been some substitution of TDI by MDI derivatives. One-shot polyether processes became feasible with the advent of sufficiently powerful catalysts. For many years tertiary amines had been used with both polyesters and the newer polyethers. Examples included alkyl morpholines and triethylamine. Catalysts such as triethylenediamine ( Dabco ) and 4-dimethyla-minopyridine were rather more powerful but not satisfactory on their own. In the late 1950s organo-tin catalysts such as dibutyl tin dilaurate and stannous octoate were found to be powerful catalysts for the chain extension reactions. It was found that by use of varying combinations of a tin catayst with a tertiary amine... 

Since power is a substantial component of the fixed operating cost of a unit, the operating cost would run approximately seven times more on a scrubber installation. The installation costs of a hot-rolled steel precipitator to handle 100,000 cfm would be between 3.50 and 4.50/cfm as opposed to 1.40 to 1.80/cfm for a venturi scrubbing system. Although the initial capital expenditure is high for the precipitator, if the total operating and capital costs are amortized over an acceptable period of time, 8 to 10 years, the precipitator will prove to be the. lore economically feasible choice because of its low operating and maintenance costs. 

Enantioselective processes involving chiral catalysts or reagents can provide sufficient spatial bias and transition state organization to obviate the need for control by substrate stereochemistry. Since such reactions do not require substrate spatial control, the corresponding transforms are easier to apply antithetically. The stereochemical information in the retron is used to determine which of the enantiomeric catalysts or reagents are appropriate and the transform is finally evaluated for chemical feasibility. Of course, such transforms are powerful because of their predictability and effectiveness in removing stereocenters from a target. 

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