Poly diallyldimethylammonium

Poly(diallyldimethylammonium) chloride [26062-79-3], Ppted from water in acetone, and dried in vacuum for 24h. [Hardy and Shriner J Am Chem Soc 107 3822 1985.]... 

We have studied stoichiometry of complex formation between DNA and PLL and found that the complexes formed in low-salt-buffer solutions are of a 1 1 charge ratio [92]. The same 1 1 stoichiometry was found experimentally for DNA complexed with other synthetic polycations of different nature in low-salt aqueous solutions [such as poly (diallyldimethylammonium chloride), poly(dimethyhmino)ethylene(dimethylimino)ethy-lene-l,4-dimethylphenylmethyl ene dichloride, andpoly(4-vinyl-A-methylpyridinium bromide)] [93]. 

Chrambach, A Rodbard, D, Polyacrylamide Gel Electrophoresis, Science 172, 440, 1971. Chu, B Yeh, F Sokolov, EL Starodoubtsev, SG Khokhlov, AR, Interaction of Slightly Cross-linked Gels of Poly(diallyldimethylammonium chloride) with Surfactants, Macromolecules 28, 8447, 1995. 

The encapsulation process used was the LbL method, employing alternately charged polymers, namely PDA [poly(diallyldimethylammonium chloride)] and PSS... 

Negatively charged species such as carboxylic acid group in acid-treated CNTs can attract positively charged enzymes from solution as long as the pH value of the enzyme solution is controlled to be lower than the iso-electric point of the enzyme thus, multilayer films of the enzyme can be formed by the layer-by-layer technique. For example, five layers of GOx can be immobilized on the electrode surface by alternatively dipping a poly(diallyldimethylammonium chloride (PDDA))-functionalized GC into a CNT solution and a GOx solution (pH 3.8). Figure 15.15 illustrates the preparation process for the formation of a multilayer film of GOx on the electrode. 

P.L. He, N.F. Hu, and G. Zhou, Assembly of electroactive layer-by-layer films of haemoglobin and poly-cationic poly(diallyldimethylammonium). Biomacromolecules 3, 139-146 (2002). 

Figure 10. Proton conductivity diffusion coefficient (mobility) and self-diffusion coefficient of phosphorus for poly-(diallyldimethylammonium-dihydrogenphosphate)—phosphoric acid ((PAMA+H2P04 ) nH3P04), as a function of the phosphoric acid content. Note that the ratio DJDp remains almost constant (see text).

Fabrication of organic thin films based on sponfaneous molecular assembly has been considered as one of fhe powerful approaches to create novel supramolecular systems. In this context, multilayer films were fabricated by layer-by-layer electrostatic deposition techniques based on the electrostatic interaction between dsDNA and the positively charged polymer poly(diallyldimethylammonium chloride) (PDDA) on GC surfaces. A uniform assembly of PDDA/DNA multilayer films was achieved, based on the adsorption of the negatively charged DNA molecules on the positively charged substrate [55]. 

Fig. 16. Poly[diallyldimethylammonium chloride. Reproduced with permission from Wolfson et al.

Work with supported ionic liquids was extended to a cationic polymer, poly (diallyldimethylammonium chloride), which has quaternary ammonium functional groups (Fig. 16) 268). The extra-structural counter anion is Cl . The polymer was applied to simultaneously incorporate an ionic liquid and a transition-metal catalyst via a simple mixing of the components. Wilkinson s catalyst and [BMIM]PF6 were... 

PDADMA = poly(diallyldimethylammonium chloride) a positively, PSS = poly(styrenesulfonic acid), PAMPS = poly(2-acrylamido-2-methyl-l-propane sulfonic acid), and PFPVP = 4-vinyl-trideca-fluoro-octyl pyridinium iodide-co-4-vinyl pyridine. 

AA BAA CMC CPB CTAB DM SO IPC MVPQ PAA PDADMAB PEG PIPAA SDS SMA TEMED acrylamide methylene bisacrylamide critical micelle concentration cetylpyridinium bromide cetyltrimethylammonium bromide dimethylsulfoxide interpolymer complex methylvinylpiridine units quaternized by dimethyl sulfate poly(acrylamide) poly(diallyldimethylammonium bromide) polyethylene glycol) poly(isopropylacrylamide) sodium dodecyl sulfate sodium methacrylate tetramethylethylenediamine... 

A detailed study of the structure of the aggregates of the ionic surfactants in polyelectrolyte networks was presented in Refs. [66,68]. The dynamics of the changes in the microenvironment of the fluorescent probe, pyrene, in slightly crosslinked networks of poly(diallyldimethylammonium bromide) (PDADMAB) during diffusion of sodium dodecyl sulfate (SDS) in the gel phase has been investigated by means of fluorescence spectroscopy. In Ref. [66], an analogous investigation was reported for complexes formal by the sodium salt of PMAA with cetyltrimethylammonium bromide (CTAB). 

Ionic charges of the polymers were determined by photometric colloid titrations in some instances. A known amount of poly(diallyldimethylammonium chloride) was added to the polymer solution at a pH of 2.5. The excess poly(diallyldimethylammonium chloride) was titrated by poly(vinylsulfate) using the adsorption indicator methylene blue. The end point was detected by the photometric detector as the color of the solution changes from blue to violet. For anionic copolymers the colloid titration was conducted at pH values of 2.5 and 10.0 to determine the extent of modification. 

Polymer beads have also been tagged by treating them after each new diversity-introducing reaction with dye-containing, colloidal silica particles, which can be irreversibly adsorbed on the surface of the beads with the aid of polyelectrolytes such as poly(diallyldimethylammonium chloride) and poly(acrylic acid) [42,43]. Larger portions of support can also be linked to a chip that enables electronic tagging with a radio emitter [44-46]. 

The theoretical bases for interaction with counterions have been discussed in Sect. 5.1. However, these theories do not take into account the special nature of the ions and only the valency was considered [102-108,114-117]. The solubility caused by the variation in the counterions cannot, for example, be predicted. According to [35] the solubility of poly(diallyldimethylammonium halides) decreases in the order Cl" >Br" >1". The homopolymer precipitates in the iodide form. This is in contrast to ammonium halides where the iodide has the highest solubility [153]. Comparing the effects of Cl", S042", and P043" a very similar in-... 

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