Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Actual state

Fig. 4. Schematic of the JKR treatment of contact mechanics calculations. The point (, a, P) corresponds to the actual state under the action of interfacial forces and applied load P. P is the equivalent Hertzian load corresponding to contact radius a between the two surfaces, ( o, P) and (S], a, P ) are the Hertzian contact points. The net stored elastic energy and displacement S are calculated as the difference of steps 1 and 2. Fig. 4. Schematic of the JKR treatment of contact mechanics calculations. The point (, a, P) corresponds to the actual state under the action of interfacial forces and applied load P. P is the equivalent Hertzian load corresponding to contact radius a between the two surfaces, ( o, P) and (S], a, P ) are the Hertzian contact points. The net stored elastic energy and displacement S are calculated as the difference of steps 1 and 2.
As a result of simultaneous introduction of elastic, viscous and plastic properties of a material, a description of the actual state functions involves the history of the local configuration expressed as a function of the time and of the path. The restrictions, which impose the second law of thermodynamics and the principle of material objectivity, have been analyzed. Among others, a viscoplastic material of the rate type and a strain-rate sensitive material have been examined. [Pg.645]

The actual state, and absolute amount, of intrinsic energy existing in a body, or system of bodies, are things which lie quite outside the range of pure thermodynamics. This indefiniteness has, however, not the slightest influence on the stringency of the definition, since we can proceed as in the definition of electrostatic potential, and choose any convenient standard state of the body, and use the term intrinsic energy with reference to this standard state. [Pg.34]

This integral may therefore be regarded as measuring the change of some magnitude which depends, like the intrinsic energy, entirely on the actual state of a material system, and is independent of the previous history of the system. If SA, SB... [Pg.74]

A value close to 4.8 V has been obtained in four different laboratories using quite different approaches (solid metal/solution Ay, 44 emersed electrodes,40,47 work function changes48), and is apparently supported by indirect estimates of electronic energy levels. The consistency of results around 4.8 V suggests that the value of 4.44 V is probably due to the value of 0 not reflecting the actual state of an Hg jet or pool. According to some authors,44 the actual value of 0 for Hg in the stream should be 4.8 V in that the metal surface would be oxidized. [Pg.14]

Both the ionic and the covalent structure of sphalerite, for instance, are singlet structures, with no unpaired electrons, so that either extreme or any intermediate is possible, and in such a case evidence from various properties of the particular substance must be considered to decide which extreme is more closely approached. On the other hand, in a crystal such as (NH FeFg or (7V774)3Z e(GW)s the lowest ionic state of the [FeXft] complex does not combine with the lowest covalent state, so that the transition from one extreme to the other is discontinuous. The actual state of the complex in the crystal can be determined from the multiplicity. With an ionic state, Fe+++ and -For ( C Nthe F or... [Pg.159]

The purpose of this section is to describe recent achievements in time-resolved X-ray diffraction from liquids. Keeping the scope of the present chapter in mind, neither X-ray diffraction from solids nor X-ray absorption will be discussed. The majority of experiments realized up to now were performed using optical excitation, although some recent attempts using infrared excitation were also reported. The main topics that have been studied are (1) visualization of atomic motions during a chemical reaction, (2) structure of reaction intermediates in a complex reaction sequence, (3) heat propagation in impulsively heated liquids, and (4) chemical hydrodynamics of nanoparticle suspensions. We hope that the actual state-of-the-art will be illustrated in this way. [Pg.274]

This review has been restricted mainly to clarification ofthe fundamentals and to presenting a coherent view ofthe actual state of research on voltaic cells, as well as their applications. Voltaic cells are, or may be, used in various branches of electrochemistry and surface chemistry, both in basic and applied research. They particularly enable interpretations of the potentials of various interphase and electrode boundaries, including those that are employed in galvanic and electroanalytical cells. [Pg.48]

Thus, the activity coefficient can be calculated if AGE is known this is the difference between the work of the reversible transition of the real system at constant temperature and pressure from the standard to the actual state and the work in the same process in the ideal system ... [Pg.40]

The limitation of transfer function representation becomes plain obvious as we tackle more complex problems. For complex systems with multiple inputs and outputs, transfer function matrices can become very clumsy. In the so-called modem control, the method of choice is state space or state variables in time domain—essentially a matrix representation of the model equations. The formulation allows us to make use of theories in linear algebra and differential equations. It is always a mistake to tackle modem control without a firm background in these mathematical topics. For this reason, we will not overreach by doing both the mathematical background and the control together. Without a formal mathematical framework, we will put the explanation in examples as much as possible. The actual state space control has to be delayed until after tackling classical transfer function feedback systems. [Pg.64]

Research activities in the area of fast pyrolysis of biomass started toward the end of the 1970s of past century. A thorough overview of the basic principles and actual state of the art is given by Meier,96 Bridgwater and Peacocke,97 and Mohan et al.98... [Pg.210]

Sostoa A, Lobon-Cervia J (1989) Fish and fisheries of the river Ebro actual state and recent history. In Petts GE, Moller H, Roux AL (eds) Historical change of large alluvial rivers Western Europe. Wiley, New York, pp 233-247... [Pg.138]

Choosing the basis in this manner sometimes leads to some initial confusion, because we select species present in the system to serve as components. There is a risk of confusing the amount of a component, which describes bulk composition but not the actual state of the system, with the amount of a species or mineral that exists in reality. [Pg.38]

There are a number of approaches to measuring risks depending on assessment and measurement endpoints selected. At ecosystem level, one can propose a percentage of the affected area with CLs exceeded as an acceptable quantitative parameter for ecosystem risk magnitude. In pristine areas, actual state of the environment may be taken as a reference point for risk characterization. [Pg.20]

The next stage in the Rhine treatment, the GAC filtration, does not result in a measurable decrease of SPC [23]. As already discussed for the waterworks Llobregat, in this instance the actual state of the GAC, in terms of the extent of loading and breakthrough behaviour, might be a decisive factor in its ability to adsorb the polar sulfonates. [Pg.805]

We are here picturing the production of real states [mesomeric forms] from unreal states [i.e., the ordinary structural formulas] and not the deformation of real states by some external disturbance, as is the case in most of the physical problems to which perturbation theory is commonly applied.. . . There can be no physical separation. . . between resonance vibrations and other electronic vibrations it follows that the unperturbed structures. .. are only of the nature of intellectual scaffolding, and that the actual state is the mesomeric state. Chemical evidence in support of these ideas is extensive.43... [Pg.224]

In quantum mechanics, as we have already seen, one can approximately describe the hydrogen molecular ion as consisting of Ha+ and Hb, or Hb+ and Ha. Some combination of wave functions representing these two configurations is needed as an approximation of the actual state of affairs. The state of H2+ can then be thought of as a resonance hybrid of the two. [Pg.262]

Data at the actual state (P,T-area of interest) are available from the literature. [Pg.422]

Weiner, M. and Osek, J. (2007). Shiga toxin producing E. coli-the actual state of knowledge. [Pg.207]


See other pages where Actual state is mentioned: [Pg.492]    [Pg.518]    [Pg.60]    [Pg.427]    [Pg.427]    [Pg.398]    [Pg.307]    [Pg.103]    [Pg.327]    [Pg.681]    [Pg.77]    [Pg.6]    [Pg.104]    [Pg.460]    [Pg.16]    [Pg.18]    [Pg.18]    [Pg.20]    [Pg.22]    [Pg.39]    [Pg.37]    [Pg.538]    [Pg.20]    [Pg.268]    [Pg.513]    [Pg.238]    [Pg.391]    [Pg.5]    [Pg.80]    [Pg.189]    [Pg.89]   
See also in sourсe #XX -- [ Pg.258 ]




SEARCH



Actual

Actuality

© 2024 chempedia.info