Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Physical convection

Transport. The mechanisms responsible for transport are considered to be both physical (convection or mass flow) and chemical (diffusion). When considered simultaneously, these processes have been summarized in the convective-dispersive, or miscible displacement, equation. For a non-interacting solute (such as chloride) under steady state water flow conditions in a homogeneous soil, this equation can be written as (10) ... [Pg.333]

These should be con describe the same reaction, s but at the limit of fine Physically the interesting f appearance of the pressure p ablej with the consequence describe the system at the at the limit of fine pores, true that the pressure wit ni sense that percentage variat of the pressure variations i permeability, so convective permeability and pressure gr the origin of the two terms... [Pg.168]

In the earlier versions of the streamline upwinding scheme the modified weight function was only applied to the convection tenns (i.e. first-order derivatives in the hyperbolic equations) while all other terms were weighted in the usual manner. This is called selective or inconsistent upwinding. Selective upwinding can be interpreted as the introduction of an artificial diffusion in addition to the physical diffusion to the weighted residual statement of the differential equation. This improves the stability of the scheme but the accuracy of the solution declines. [Pg.54]

Effect of Uncertainties in Thermal Design Parameters. The parameters that are used ia the basic siting calculations of a heat exchanger iaclude heat-transfer coefficients tube dimensions, eg, tube diameter and wall thickness and physical properties, eg, thermal conductivity, density, viscosity, and specific heat. Nominal or mean values of these parameters are used ia the basic siting calculations. In reaUty, there are uncertainties ia these nominal values. For example, heat-transfer correlations from which one computes convective heat-transfer coefficients have data spreads around the mean values. Because heat-transfer tubes caimot be produced ia precise dimensions, tube wall thickness varies over a range of the mean value. In addition, the thermal conductivity of tube wall material cannot be measured exactiy, a dding to the uncertainty ia the design and performance calculations. [Pg.489]

Likewise, the microscopic heat-transfer term takes accepted empirical correlations for pure-component pool boiling and adds corrections for mass-transfer and convection effects on the driving forces present in pool boiling. In addition to dependence on the usual physical properties, the extent of superheat, the saturation pressure change related to the superheat, and a suppression factor relating mixture behavior to equivalent pure-component heat-transfer coefficients are correlating functions. [Pg.96]

Influence of Chemical Reactions on Uq and When a chemical reaction occurs, the transfer rate may be influenced by the chemical reac tion as well as by the purely physical processes of diffusion and convection within the two phases. Since this situation is common in gas absorption, gas absorption will be the focus of this discussion. One must consider the impacts of chemical equilibrium and reac tion kinetics on the absorption rate in addition to accounting for the effec ts of gas solubility, diffusivity, and system hydrodynamics. [Pg.615]

Zddovich, Y. B. 1937. Fundamental principle.s for free convective plume.s. Journal of Experimental and Technical Physics, vol. 7, no. 12. [Pg.541]

As their name suggests, these models are based on the physical principles of diffusion and convection, which govern the mixing process. According to the flow pattern, the reactor is divided into different zones with different flow characteristics. [Pg.51]

Loop Tests Loop test installations vary widely in size and complexity, but they may be divided into two major categories (c) thermal-convection loops and (b) forced-convection loops. In both types, the liquid medium flows through a continuous loop or harp mounted vertically, one leg being heated whilst the other is cooled to maintain a constant temperature across the system. In the former type, flow is induced by thermal convection, and the flow rate is dependent on the relative heights of the heated and cooled sections, on the temperature gradient and on the physical properties of the liquid. The principle of the thermal convective loop is illustrated in Fig. 19.26. This method was used by De Van and Sessions to study mass transfer of niobium-based alloys in flowing lithium, and by De Van and Jansen to determine the transport rates of nitrogen and carbon between vanadium alloys and stainless steels in liquid sodium. [Pg.1062]

Renal replacement by an artificial device providing continuous filtration of plasma based on the physical principle of convection. [Pg.582]

Convection—transport to the electrode by a gross physical movement such fluid tiow occurs with stirring or tiow of the solution and with rotation or vibration of the electrode (i.e., forced convection) or due to density gradients (i.e., natural convection) ... [Pg.4]

Determination of the wet-bulb temperature. Equation 13.8 gives the humidity of a gas in terms of its temperature, its wet-bulb temperature, and various physical properties of the gas and vapour. The wet-bulb temperature is normally determined as the temperature attained by the bulb of a thermometer which is covered with a piece of material which is maintained saturated with the liquid. The gas should be passed over the surface of the wet bulb at a high enough velocity (>5 m/s) (a) for the condition of the gas stream not to be affected appreciably by the evaporation of liquid, (b) for the heat transfer by convection to be large compared with that by radiation and conduction from the surroundings, and... [Pg.756]

As shown in Fig. 21, in this case, the entire system is composed of an open vessel with a flat bottom, containing a thin layer of liquid. Steady heat conduction from the flat bottom to the upper hquid/air interface is maintained by heating the bottom constantly. Then as the temperature of the heat plate is increased, after the critical temperature is passed, the liquid suddenly starts to move to form steady convection cells. Therefore in this case, the critical temperature is assumed to be a bifurcation point. The important point is the existence of the standard state defined by the nonzero heat flux without any fluctuations. Below the critical temperature, even though some disturbances cause the liquid to fluctuate, the fluctuations receive only small energy from the heat flux, so that they cannot develop, and continuously decay to zero. Above the critical temperature, on the other hand, the energy received by the fluctuations increases steeply, so that they grow with time this is the origin of the convection cell. From this example, it can be said that the pattern formation requires both a certain nonzero flux and complementary fluctuations of physical quantities. [Pg.248]

New questions have arisen in micro-scale flow and heat transfer. The review by Gad-el-Hak (1999) focused on the physical aspect of the breakdown of the Navier-Stokes equations. Mehendale et al. (1999) concluded that since the heat transfer coefficients were based on the inlet and/or outlet fluid temperatures, rather than on the bulk temperatures in almost all studies, comparison of conventional correlations is problematic. Palm (2001) also suggested several possible explanations for the deviations of micro-scale single-phase heat transfer from convectional theory, including surface roughness and entrance effects. [Pg.37]

In our analysis, we discuss experimental results of heat transfer obtained by previous investigators and related to incompressible fluid flow in micro-channels of different geometry. The basic characteristics of experimental conditions are given in Table 4.1. The studies considered herein were selected to reveal the physical basis of scale effect on convective heat transfer and are confined mainly to consideration of laminar flows that are important for comparison with conventional theory. [Pg.147]

The flow in a heated capillary depends on a number of parameters including the channel geometry, physical properties of the liquid and the heat flux. An immediate consequence of the liquid heating and evaporation is convective motion of both phases. The latter leads to a velocity and temperature field fransformation and a change in fhe meniscus shape. [Pg.350]

Another widely used concept is that of a planetary boundary layer (PBL) in contact with the surface of the Earth above which lies the "free atmosphere." This PBL is to some degree a physically mixed layer due to the effects of shear-induced turbulence and convective overturning near the Earth s surface. [Pg.135]

The second term on the left-hand side of Eq (1) expresses the convection of gas molecules across the face of dr in physical space by the molecular velocity c. The third term on the left-hand side of Eq (1) represents the convection of... [Pg.97]

The large viscosity increases that accompany increased polymer concentrations have a strong effect on reactor performance. This phenomenon is illustrated through a simplified yet realistic example (also used in Reference 1 to study the effects of radial convection). In this case the polymerization rate is first order in monomer concentration and the physical properties are constant, except for viscosity, which is given by the following expression ... [Pg.340]

The effect of natural convection can be illustrated by considering the following simplified model. The reaction rates and physical parameters are constant except for the density which is given as ... [Pg.343]


See other pages where Physical convection is mentioned: [Pg.177]    [Pg.177]    [Pg.163]    [Pg.512]    [Pg.308]    [Pg.94]    [Pg.560]    [Pg.764]    [Pg.1190]    [Pg.2007]    [Pg.230]    [Pg.300]    [Pg.52]    [Pg.463]    [Pg.1227]    [Pg.397]    [Pg.590]    [Pg.209]    [Pg.213]    [Pg.250]    [Pg.694]    [Pg.142]    [Pg.171]    [Pg.464]    [Pg.318]    [Pg.352]    [Pg.133]    [Pg.172]    [Pg.241]   
See also in sourсe #XX -- [ Pg.176 ]




SEARCH



Convection heat transfer physical mechanism

Convection physical mechanism

Convective mixing physical processes

Natural convection physical mechanism

© 2024 chempedia.info