Phthalic acid methyl ester

Synonyms AI3-00262 Avolin 1,2-Benzenedicarboxylic acid, dimethyl ester BRN 1911460 C-11233 Caswell No. 380 CCRIS 2674 Dimethyl-1,2-benzenedicarboxylate Dimethylbenzene-o-dicarboxylate DMP EINECS 205-011-6 ENT 262 EPA pesticide chemical code 028002 Fermine Methyl phthalate Mipax NSC 15398 NTM Palatinol M Phthalic acid, dimethyl ester o-Phthalic acid, dimethyl ester Phthalic acid methyl ester o Phthalic acid, dimethyl ester RCRA waste number U102 Solvanom Solvarone. 

Phthalic acid, methyl ester, see Dimethyl phthalate... 

PHTHALIC ACID, DIPENTYL ESTER see AON300 PHTHALIC ACID, DIPROPYL ESTER see DW 500 PHTHALIC ACID METHYL ESTER see DTR200 PHTHALIC ANHYDRIDE see PHW750 o-PHTHAUC INODE see PHXOOO PHTHAUDE 3,3,-BIS(p-HYDROXYPHENYL)- see PDO750... 

Avolin 1,2-benzenedicarboxylate benzenedicarboxylic acid dimethyl ester dimethyl 1,2-benzenedicarboxylate dimethyl benzene-o-dicarboxylate dimethyl benzeneorthodicarboxy-late dimethyl o-phthalate o-dimethyl phthalate DMP Fer-mine Kodaflex DMP methyl benzene-1,2-dicarboxylate Mipax Palatinol M phthalic acid dimethyl ester phthalic acid methyl ester Repeftal Solvanom Solvarone Unimoll DM. 

SYNONYMS DMP avolin 1,2-benzenedicarboxylic acid, methyl phthalate, phthalic acid methyl ester, solvarone, dimethyl bezeneorthodicarboxylate. 

SYNONYMS Avolin, 1,2-Benzenedicarboxylic acid. Dimethyl ester, Dimethyl-1,2-benzenedi carboxyl ate. Dimethyl benzeneorthodicarboxylate, DMP, ENT 262, Fermine, Methyl phthalate, Mipax, NTM, Palatinol M, Phthalic acid methyl ester, Phthalsaeuredimethylester (german), Solvanom, Solvarone... 

Synonyms cas isi-ii-s avolin dmp methyl phthalate phthalic acid methyl ester Dimethylpolysiloxane... 

Synonyms Avolin 1,2-Benzenedicarboxylic acid dimethyl ester Dimethyl-1,2-ben-zenedicarboxylate Dimethylbenzeneorthodicarboxylate DMP ENT 262 Pennine Methyl phthalate Mipax NTM Palatinol M Phthalic acid dimethyl ester Phthalic acid methyl ester RCRA waste number U102 Solvanom Solvarone. 

Figure 12.12 THM GC/MS curves of a Winsor Newton lemon alkyd paint (a) and of an alkyd sample taken from Fontana s work Concetto spaziale (1961) (b). Peak assignments 1, 1,3 dimethoxy 2 propanol 2, 1,2,3 trimethoxy propane 3, 3 methoxy 1,2 propandiol 4, 4 chloro benzenamine 5, 3 methoxy 2,2 bis(methoxymethyl) 1 propanol 6, 3 chloro N methyl benzenamine 7, 3 methoxy 2 methoxymethyl 1 propanol 8, 4 chloro N methyl benzenamine 9, phthalic anhydride 10, 3 chloro 4 methoxy benzenamine 11, suberic acid dimethyl ester 12, dimethyl phthalate 13, azelaic acid dimethyl ester 14, sebacic acid dimethyl ester 15, palmitic acid methyl ester 16, oleic acid methyl ester 17, stearic acid methyl ester 18, 12 hydroxy stearic acid methyl ester 19, 12 methoxy stearic acid methyl ester 20, styrene 21, 2 (2 methoxyethoxy) ethanol 22, 1,1 oxybis(2 methoxy ethane) 23, benzoic acid methyl ester 24, adipic acid dimethyl ester 25, hexadecenoic acid methyl ester 26, dihydroisopimaric acid methyl ester 27, dehydroabietic acid methyl ester 28, 4 epidehydroabietol...

Indenopyrene, see Indeno[l,2,3-crf pyrene l//-Indole, see Indole Indolene, see Indoline Inexit, see Lindane Inhibisol, see 1,1,1-Trichloroethane Insecticide 497, see Dieldrin Insecticide 4049, see Malathion Insectophene, see a-Endosulfan, p-Endosulfan Intox 8, see Chlordane Inverton 245, see 2,4,5-T lodomethane, see Methyl iodide IP, see Indeno[l,2,3-crf pyrene IP3, see Isoamyl alcohol Ipaner, see 2,4-D IPE, see Isopropyl ether IPH, see Phenol Ipersan, see Trifluralin Iphanon, see Camphor Isceon 11, see Trichlorofluoromethane Isceon 122, see Dichlorodifluoromethane Iscobrome, see Methyl bromide Iscobrome D, see Ethylene dibromide Isoacetophorone, see Isophorone a-Isoamylene, see 3-Methyl-l-butene Isoamyl ethanoate, see Isoamyl acetate Isoamylhydride, see 2-Methylbutane Isoamylol, see Isoamyl alcohol Isobac, see 2,4-Dichlorophenol Isobenzofuran-l,3-dione, see Phthalic anhydride 1,3-Isobenzofurandione, see Phthalic anhydride IsoBuAc, see Isobutyl acetate IsoBuBz, see Isobutylbenzene Isobutane, see 2-Methylpropane Isobutanol, see Isobutyl alcohol Isobutene, see 2-Methylpropene Isobutenyl methyl ketone, see Mesityl oxide Isobutyl carbinol, see Isoamyl alcohol Isobutylene, see 2-Methylpropene Isobutylethylene, see 4-Methyl-l-pentene Isobutyl ketone, see Diisobutyl ketone Isobutyl methyl ketone, see 4-Methyl-2-pentanone Isobutyltrimethylmethane, see 2,2,4-Trimethylpentane Isocumene, see Propylbenzene Isocyanatomethane, see Methyl isocyanate Isocyanic acid, methyl ester, see Methyl isocyanate Isocyanic acid, methylphenylene ester, see 2,4-Toluene-diisocyanate... 

Synonyms 1,2-benzenedicarboxylic acid dimethyl ester phthalic acid dimethyl ester methyl phthalate... 

The phthalimlde group is typically introduced by reaction of a primary amine with phthalic anhydride in chloroform at 70 °C for 4 h (85-93% yield)1 or phthaloyl chloride in the presence of triethylamine [Scheme 8.10].20 2-Ch oro-carbonylbenzoic acid methyl ester in the presence of base [Scheme 8.11JT21-22 or N-ethoxycarbonylphthalimide23 have also been used with the latter reagent being especially useful for the -protection of a-amino acids [Scheme 8 12] m. 24... 

Dimethyl Phthalate. 1,2-Benienedicarboxylic acid dimethyl ester phthalic acid dimethyl ester methyl phthalate dimethyl 1,2-benzenedicarboxylate DMP Palatinol M Fer-mine Avolin Mipax. C 0H.0O4 mol wt 194.19. C 61.85%, H 5,19%, O 32.96%. Prepd industrially from phthalic anhydride and methanol Faith, Keyes St, Clarks Industrial... 

Alternative Name/Abbreviation Methyl phthalate, phthalic acid dimethyi ester, 1,2-benzenedicarboxyiic acid dimethyi ester, DMPh... 

CAS 131-11-3 EINECS/ELINCS 205-011-6 Synonyms 1,2-Benzenedicarboxylic acid dimethyl ester Dimethyl 1,2-benzenedicarboxylate Dimethyl benzeneotthodicarbo) lale DMP Methyl phthalate Phthalic acid, dimethyl ester Definition Diester of methyl alcohol and phthalic acid Enpirical C,oH 0,... 

Synonyms Ethyl 0-(o-(methoxycarbonyl) benzoyl) glycolate Ethyl o-(methoxycarbonyl) benzoyloxyacetate Glycolic acid, ethyl ester, methyl phthalate Phthalic acid, monomethyl ester, ester with ethyl glycolate Empirical C13H14O6... 

C13H14O6 phthalic acid ethoxycarbonylmethyl ester methyl ester 85-71-2 ... 

Methyl, ethyl, n-propyl, isopropyl, n-hutyl, benzyl, cyclohexyl esters of formic, acetic, oxalic, succinic, tartaric, citric, benzoic, salicylic (and other substituted benzoic acids), phthalic and cinnamic acids phenyl esters of acetic, benzoic and salicylic acids. 

Reactions of the Methyl Groups. These reactions include oxidation, polycondensation, and ammoxidation. PX can be oxidized to both terephthahc acid and dimethyl terephthalate, which ate then condensed with ethylene glycol to form polyesters. Oxidation of OX yields phthaUc anhydride, which is used in the production of esters. These ate used as plasticizers for synthetic polymers. MX is oxidized to isophthaUc acid, which is also converted to esters and eventually used in plasticizers and resins (see Phthalic acids and otherbenzenepolycarboxylic acids). 

Other large-volume esters are vinyl acetate [108-05-4] (VAM, 1.15 x 10 t/yr), methyl methacrylate [80-62-6] (MMA, 0.54 x 10 t/yr), and dioctyl phthalate [117-81-7] (DOP, 0.14 x 10 t/yr). VAM (see Vinyl polymers) is produced for the most part by the vapor-phase oxidative acetoxylation of ethylene. MMA (see Methacrylic polymers) and DOP (see Phthalic acids) are produced by direct esterification techniques involving methacryHc acid and phthaHc anhydride, respectively. 

Chemical/Physical. An aqueous solution containing chlorine dioxide in the dark for 3.5 d oxidized naphthalene to chloronaphthalene, 1,4-dichloronaphthalene, and methyl esters of phthalic acid (Taymaz et ah, 1979). In the presence of bromide ions and a chlorinating agent (sodium hypochlorite), major products identified at various reaction times and pHs include 1-bromonaphthalene, dibromonaphthalene, and 2-bromo-l,4-naphthoquinone. Minor products identified include chloronaphthalene, dibromonaphthalene, bromochloronaphthalene, bromo-naphthol, dibromonaphthol, 2-bromonaphthoquinone, dichloronaphthalene, and chlorodibromo-naphthalene (Lin et ah, 1984). 

Chloroform, Chloropicrin, 1,1-Dichloroethylene, Endrin, Hexachlorocyclopentadiene, Methyl chloride. Methylene chloride, Tetrachloroethylene, 1,1,1 -Trichloroethane, Trichloroethylene Phosphine, see Pentachlorobenzene, Phorate Phosphoric acid, see Dichlorvos, Ethephon. Glvphosate. Malathion, Mevinphos, Parathion, Sulfotepp, Tributyl phosphate, Trichlorfon Phosphoric acid, dimethyl ester, see Mevinphos, Oxvdemeton-methvl Phosphorothioic acid, see Parathion Photoaldrin, see Aldrin Photoaldrin chlorohydrin, see Dieldrin Photodieldrin, see Aldrin, Dieldrin Photoheptachlor, see Heptachlor Photoketoaldrin, see Aldrin Phthalaldehyde, see Naphthalene Phthalaldehydes, see Tolnene Phthalic acid, see Anthracene, Benzo[a]anthracene, Benzyl bntyl phthalate, Dichlone. Diethyl phthalate, Dimethyl phthalate, Naphthalene, Naptalam. I ene... 

Carboxy carbons of methyl benzoates are shielded by electron-withdrawing substituents in the oposition of the benzene ring [320] (Table 4.38). Carbonyl shifts of phthalic acid diesters and phthalimide are larger than those of phthalic anhydride [321]. fi effects of the O-alkyl group in the esters and hydrogen bonding of the imide are the obvious reasons. 

Several polymers were found to fit all or most of the above criteria and were used to prepare the carrier films. Many polymers have been used for this purpose, viz., ethyl cellulose, poly(y-benzyl glutamate), poly(vinyl acetate), cellulose acetate phthalate, and the copolymer of methyl vinyl ether with maleic anhydride. In addition to the base polymers, plasticizers were often needed to impart a suitable degree of flexibility. Plasticizers, which are found to be compatible with polymeric materials include, acetylated monoglycerides, esters of phthalic acid such as dibutyl tartarate, etc. An excipient was usually incorporated into the matrix of the carrier films. The excipients used were water-soluble materials, which are capable of creating channels in the polymer matrix and facilitate diffusion of the drug. PEGs of different molecular weights were used for this purpose. 

On treatment with acids or bases, both the monomethoxy and the dimethoxy six-membered ring peroxide are converted into the methyl ester of o-phthalaldehydic acid or into o-phthalaldehydic acid, depending on the reaction conditions. Oxidation with hydrogen peroxide yields o-phthalic acid.87 The hydrogenation of 135 in the presence of a Lindlar catalyst leads to o-phthaldialdehyde (yield =... 

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