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Phthalate plasticizers hydrolysis

Aromatic esters are more resistant. Resistance to microbial attack among phthalate plasticizers follows resistance to hydrolysis—that is, essentially to heat stability. Aliphatic phosphate plasticizers are similar in microbial resistance to phthalates aromatic and halogenated phosphates and chlorinated paraffin appear to be inedible. Usually, plasticizer choice is dictated by other factors, thus requiring use of biocides. [Pg.131]

Plasticizer. The polymer tubing extractor contains the plasticizer l,2-bis(ethylhexyl) phthalate. Longer exposures to 0.1 M NaOH indicated that electroactive hydrolysis products of plasticizer, probably ethyl and hexyl alcohols, were produced, as suggested by the following peak currents given in nanoamperes (the times of the peak currents are given in parentheses) 30 (2 min), 7 (1 min), 5 (30 s), and 2 (15 s). The analytical procedure presented here uses back extraction times of less... [Pg.348]

Hydrolysis revealed numerous anthropogenic compounds that can be attributed to different technical applications or widespread domestic usages. Within the group of plasticizers the phthalates, which are well-known and ubiquiteous pollutants, were most abundant. Also the plasticizers tributylphosphate and 2,4,4-trimcthylpcntane-l,3-dioldi-/.vo-butyrate occurred in minor concentrations mainly in sample Tl. Due to their molecular structures a non-covalent association of these compounds to the geopolymers has to be assumed. [Pg.252]

Composition B contains 1 percent wax. Depending on the nature of the wax, some long-chain fatty acids may be present, which act as surfactants. Hydrolysis of the plasticizers in M28 propellant may also release phthalate salts, which can aid in the emulsification of TNT when M28 and Composition B are processed together. [Pg.37]

Production of benzyl butyl phthalate is complicated by the need to use two different substituents. Studies show that many side reactions may take place, that change proportions of three potential phthalates (dibutyl, dibenzyl, benzyl butyl). The proportion of the three components determines properties of the plasticizer. The secondary reactions of hydrolysis leading to formation of unwanted components (dibutyl and dibenzyl) were found to be at a minimum when pH of reaction medium was slightly basic. ... [Pg.65]

The disappearance of a plasticizer from water can be the result of a number of abiotic and biotic processes that can transform or degrade the compound into daughter compounds that have different physicochemical properties from the parent compound. Hydrolysis is a family of chemical reactions where a plasticizer reacts with water. Phthalate esters may hydrolyze to form monoesters and then dicarboxylic acid. It has been predicted that di-(2-ethylhexyl) sebacate will form 2-ethylhexanol and decanedioic acid. Wolfe et al experimentally measured second-order alkaline hydrolysis rate constants for dimethyl, diethyl, di-n-butyl, and di-(2-ethylhexyl) phthalates, and it appears that hydrolysis may be too slow to have a major impact on the fate of most dissolved plasticizers. The estimated hydrolysis half-lives at pH 7 for 20 plasticizers were longer than 100 days. No information was located for diallyl, ditridecyl and diundecyl phthalates. Under alkaline conditions, hydrolysis may be important for tricresyl phosphate and tri-(2-ethylhexyl) trimellitate at pH 8 their predicted half-lives are 3.2 and 12 days respectively. [Pg.601]

Some polymerizable esters can be used as a copolymerizable internal plasticizer in technical applications. The best known of the group is diallyl phthalate (DAP), which is used to replace styrene, divinyl benzene, or methyl methacrylate in unsaturated polyester resins. It has a very low vapour pressure (300°C boiling point), leading to significant reduction in loss through evaporation. It considerably improves properties such as hardness, chemical resistance, hydrolysis resistance, electrical properties, and product life. It is particularly used in electrical applications, can be employed (after suitable preparation) in cold-cure systems, and shows high affinity to glass fibre. DAP can also be used as a reactive plasticizer with PVC resins. [Pg.172]

PlaStiSOlS. Plastisols, commonly called pastes, are dispersions of PVC powders in plasticizers. A wide range of plasticizers are used in plastisol formulations, but the most widely used are C4-C12 esters such as phthalates, adipates, azelates, sebacates, trimellitates, and phosphates. Chlorinated paraffins are used as secondary plasticizers. A good plasticizer should have low volatility, low color value, neutral reaction, resistance to hydrolysis, insolubility in water, flame resistance, and nontoxicity. As no plasticizer can satisfy all these properties, several plasticizers are mixed to achieve the desired properties of the final prodnct. Table 8 shows the influence of plasticizers on plastisol properties Table 9, the inflnence of plasticizers on final product properties and Table 10, the inflnence of resin characteristics on plastisol and final prodnct properties. [Pg.8951]

Allyl alcohol, CH2=CH-CH20H, is obtained from allyl chloride by alkaline hydrolysis. Oxydation of allyl alcohol gives acrolein, glycerol, formic acid, diallyl phthalate, acrylic acid. Allyl halogenids, allyl esters, allyl amines, allyl Grignard reagent can be obtained. End products are plastics, resins, plasticizers, varnish ingredients, pharmaceuticals, perfumes, flavors. [Pg.199]


See other pages where Phthalate plasticizers hydrolysis is mentioned: [Pg.165]    [Pg.181]    [Pg.145]    [Pg.186]    [Pg.286]    [Pg.117]    [Pg.111]    [Pg.569]    [Pg.397]    [Pg.645]    [Pg.42]    [Pg.317]    [Pg.82]    [Pg.161]    [Pg.112]    [Pg.691]    [Pg.145]    [Pg.48]    [Pg.292]    [Pg.5]    [Pg.611]    [Pg.396]    [Pg.65]    [Pg.118]    [Pg.61]    [Pg.90]    [Pg.367]   
See also in sourсe #XX -- [ Pg.186 ]




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